nanostructured polymer
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Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3313
Author(s):  
Jun Lan ◽  
Yong Yang ◽  
Song Hu

The application of moth-eye nanostructured polymer film on the flexible polyethylene terephthalate (PET) substrate is an effective way to improve its antireflection (AR) performance. However, many factors affect the AR properties of the moth-eye structure in the actual manufacturing process. Moreover, the antireflection research based on PET substrate has been relatively lacking compared with the silicon substrate. In this paper, we simulate and analyze the AR performance of the moth-eye nanostructured polymer film on PET substrate by using the finite-difference time-domain method within the wavelength range of 400–1100 nm. Simulation results show that the parabola-shaped moth-eye structure (PSMS) can suppress the Fresnel reflection significantly. Moreover, the height and filling ratios are the dominant factors that affect the AR performance of PSMS. Additionally, the base diameter, residual layer thickness, and the refractive index of PSMS polymer film also affect the reflectivity of PET slightly. As a result, an optimal PSMS with base diameter of 400 nm, height of 300 nm, and the hexagonal close-packed arrangement is appropriate, and the solar-weighted reflectivity of PET can be suppressed to 0.21%, which shows a prominent advantage over the bare PET (≈6%). Therefore, this research has promising potential for improving the optical performance of optoelectronic devices by using nanostructured polymer materials.


2021 ◽  
Author(s):  
Karthikeyan Krishnamoorthy ◽  
Sang-Jae Kim

This chapter describes the use of Raman spectroscopy and mapping analysis for the characterization of low dimensional nanostructures, including 2D sheets (graphene oxide, graphene sheets, MoS2, siloxene), and one-dimensional carbyne chains. The Raman mapping analysis and their application towards understanding the molecular level interactions in these low dimensional materials, nanostructured polymer composites, and nanopaints are also discussed. The stoichiometric composition and structure of these low dimensional materials were correlated with the Raman spectral and mapping analysis. Further, Raman spectroscopy for understanding or probing the mechanism of mechanical to electrical energy harvesting properties of carbyne films via the structural transformation from cumulene to polynne networks of carbyne is demonstrated.


2021 ◽  
Vol 29 (8) ◽  
pp. 509-518
Author(s):  
Jeong Hoon Yoon ◽  
Won-Jang Cho ◽  
Tae Hui Kang ◽  
Minjae Lee ◽  
Gi-Ra Yi

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