Magnetic and electrical transport properties of Sr2Ti1−xCoxO4 ceramics by sol–gel

2017 ◽  
Vol 31 (17) ◽  
pp. 1750195
Author(s):  
Li Zhang ◽  
Yibao Li ◽  
Zhen Tang ◽  
Yan Deng ◽  
Hui Yuan ◽  
...  

Microstructures, electrical transport and magnetic properties of Sr[Formula: see text]Ti[Formula: see text]Co[Formula: see text]O[Formula: see text] ceramics are investigated. With Co doping, the Sr[Formula: see text]Ti[Formula: see text]Co[Formula: see text]O[Formula: see text] ceramics remain tetragonal structure while the grain size is decreased with doping. Magnetic moment is enhanced with Co doping and ferromagnetism is observed at low temperatures for Co-doped Sr[Formula: see text]TiO[Formula: see text]. The Sr[Formula: see text]Ti[Formula: see text]Co[Formula: see text]O[Formula: see text] and Sr[Formula: see text]Ti[Formula: see text]Co[Formula: see text]O[Formula: see text] show semiconductor-like transport properties, which can be well fitted by Mott variable range hopping model. The results will provide an effective route to synthesize Sr[Formula: see text]Ti[Formula: see text]Co[Formula: see text]O[Formula: see text] ceramics as well as to investigate the physical properties.

2011 ◽  
Vol 25 (21) ◽  
pp. 1787-1794 ◽  
Author(s):  
ABIDA BASHIR ◽  
MOHD IKRAM ◽  
RAVI KUMAR

We present here the electrical transport properties of RFe 1-x Ni x O 3 (x ≤ 0.5) where R = Nd , Sm and Gd and the correlation between these systems. The resistivity increases as the rare ion is changed from Nd to Sm . The resistivity increases from the magnitude of the order of 103 to 106 Ωcm at lower temperatures and from 10 to 105 Ωcm as the temperature is increased. Also, the resistivity decreases as the concentration of Ni is increased within the ensemble showing a semiconducting behavior. The resistivity data is fitted with the Greaves Variable Range Hopping model which fits in the intermediate range of temperatures. There is decrease in gap parameter, increase in conductivity and increase in the density of states at Fermi level which clarify that the correlation length in the conducting network increases with the increase in Ni substitution. The Debye temperature decreases as the Ni concentration increases and follows the same trend as the rare earth ion is replaced.


2017 ◽  
Vol 46 (12) ◽  
pp. 6804-6810 ◽  
Author(s):  
Shuping Deng ◽  
Yu Tang ◽  
Decong Li ◽  
Hongxia Liu ◽  
Zhong Chen ◽  
...  

2015 ◽  
Vol 1107 ◽  
pp. 272-277 ◽  
Author(s):  
Siau Wei Ng ◽  
Kean Pah Lim ◽  
S.A. Halim ◽  
Hassan Jumiah ◽  
Albert H.M. Gan ◽  
...  

We have investigated the structural, microstructure and electrical transport properties of nanosized Pr0.85Na0.15MnO3 (PNMO) synthesized by sol-gel technique and sinter from 600°C to 1000°C. The grain size increases from 67 nm (S600) up to 284 nm (S1000) due to the grain growth during heat treatment. XRD showed that single phase orthorhombic crystal structure of PNMO is fully forms started at 600°C. The resistivity decreased with the increased of grain size and crystallite size due to the reduction of grain boundary effect (dead magnetic layer) which improved their grain conductivity.All samples showed semiconductor behavior where their metal insulator transition temperatures (TMIT) were estimated to be lower than 80K.


2020 ◽  
Vol 8 (7) ◽  
pp. 3978-3987 ◽  
Author(s):  
Raza Moshwan ◽  
Wei-Di Liu ◽  
Xiao-Lei Shi ◽  
Qiang Sun ◽  
Han Gao ◽  
...  

In eco-friendly SnTe thermoelectrics, In and Ag co-doping induces the synergistic effect of resonance energy levels and valence band convergence to enhance its electrical transport properties, while defects ameliorates its thermal transport.


2018 ◽  
Vol 236-237 ◽  
pp. 179-188
Author(s):  
F.M. Pontes ◽  
D.S.L. Pontes ◽  
A.J. Chiquito ◽  
Y.N. Colmenares ◽  
V.R. Mastelaro ◽  
...  

2020 ◽  
Author(s):  
Pradipta Chakraborty ◽  
Dhiraj Kumar Rana ◽  
Shovan Kumar Kundu ◽  
Soumen Basu

2011 ◽  
Vol 31 (1) ◽  
pp. 64-67 ◽  
Author(s):  
Takahiro Matsuoka ◽  
Naohisa Hirao ◽  
Yasuo Ohishi ◽  
Katsuya Shimizu ◽  
Akihiko Machida ◽  
...  

2001 ◽  
Vol 16 (3) ◽  
pp. 774-777 ◽  
Author(s):  
Yong-Chae Chung ◽  
Han-Ill Yoo

Electrical transport properties, electrical conductivity, and thermoelectric power of a single-crystalline Mn0.45Zn0.43Fe2.12O4 were measured as functions of temperature in the range of 25 to 1000 °C. According to the small polaron hopping model, the values of the activation energy for small polaron hopping (EH) were obtained from the conductivity data in three different temperature regions: 0.032 eV for T < TC, 0.12 eV for TC < T < 600 °C, and 0.25 eV for 600 °C < T < 1000 °C. The behavior of conductivity and thermoelectric power data above TC is discussed in connection with cation redistribution.


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