DIFFUSIVE EFFECTS ON A CATALYTIC SURFACE REACTION: AN INITIAL BOUNDARY VALUE PROBLEM IN REACTION-DIFFUSION-CONVECTION EQUATIONS

1993 ◽  
Vol 03 (01) ◽  
pp. 79-95 ◽  
Author(s):  
WEN ZHANG

A bimolecular catalytic surface reaction is extended to include diffusion which yields mobilized coverage on the surface. We consider the reaction occurring in a tubular reactor with a convection flow where the reactants also diffuse. An initial boundary value problem in one-dimensional reaction-diffusion-convection equations is used in describing the model. We combine singular perturbation analysis with numerical simulations in studying the solution behavior in parameter space. We track the reaction front and the cause of period-2 oscillations. Compared with the case of having no surface diffusion, we observe regular oscillations instead of irregular oscillations. Compared with the nondiffusive nonconvective model, we obtain rich spatiotemporal patterns including stationary, oscillatory reaction fronts and multiple steady states.

We examine the effects of a concentration dependent diffusivity on a reaction-diffusion process which has applications in chemical kinetics. The diffusivity is taken as a continuous monotone, a decreasing function of concentration that has compact support, of the form that arises in polymerization processes. We consider piecewise-classical solutions to an initial-boundary value problem. The existence of a family of permanent form travelling wave solutions is established, and the development of the solution of the initial-boundary value problem to the travelling wave of minimum propagation speed is considered. It is shown that an interface will always form in finite time, with its initial propagation speed being unbounded. The interface represents the surface of the expanding polymer matrix.


In this paper we examine the effects of concentration dependent diffusivity on a reaction-diffusion process which has applications in chemical kinetics and ecology. We consider piecewise classical solutions to an initial boundary-value problem. The existence of a family of permanent form travelling wave solutions is established and the development of the solution of the initial boundary-value problem to the travelling wave of minimum propagation speed is considered. For certain types of initial data, ‘waiting time’ phenomena are encountered.


2013 ◽  
Vol 54 (3) ◽  
pp. 153-170 ◽  
Author(s):  
RUNZHANG XU ◽  
YANBING YANG ◽  
SHAOHUA CHEN ◽  
JIA SU ◽  
JIHONG SHEN ◽  
...  

AbstractThis paper is concerned with the initial boundary value problem of a class of nonlinear wave equations and reaction–diffusion equations with several nonlinear source terms of different signs. For the initial boundary value problem of the nonlinear wave equations, we derive a blow up result for certain initial data with arbitrary positive initial energy. For the initial boundary value problem of the nonlinear reaction–diffusion equations, we discuss some probabilities of the existence and nonexistence of global solutions and give some sufficient conditions for the global and nonglobal existence of solutions at high initial energy level by employing the comparison principle and variational methods.


In this paper we examine the evolution that occurs when a localized input of an autocatalyst B is introduced into an expanse of a reactant A. The reaction is autocatalytic of order p,so A -> B at rate k [A] [B] p with rate constant k . We examine the case when 0 < p < 1, with p>/ 1 having been examined by Needham & Merkin (Phil. Trans. R. Soc. Lond. A 337, 261—274 (1991)). In particular, we show that the fully reacted state is not achieved (as t-> oo) via the propagation of a travelling wavefront (as for p>/ 1) but is approached uniformly in space as t-00.


Author(s):  
А.М. Слиденко ◽  
В.М. Слиденко

Приводится анализ механических колебаний элементов ударного устройства с помощью модели стержневого типа. Ударник и инструмент связаны упругими и диссипативными элементами, которые имитируют их взаимодействие. Аналогично моделируется взаимодействие инструмента с рабочей средой. Сформулирована начально-краевая задача для системы двух волновых уравнений с учетом переменных поперечных сечений стержней. Площади поперечных сечений определяются параметрическими формулами при сохранении объемов стержней. Параметрические формулы позволяют получать различного вида зависимости площади поперечного сечения стержня от его длины. Начальные условия отражают физическую картину взаимодействия инструмента с ударником и рабочей средой. Краевые условия описывают контактные взаимодействия ударника с инструментом и последнего с рабочей средой. В качестве модельной задачи рассматривается соударение ударника и инструмента через элемент большой жесткости. Начально-краевая задача исследуется разностным методом. Проводится сравнение решений задачи, полученных с помощью двухслойной и трехслойной разностных схем. Такие схемы реализованы в общей компьютерной программе в системе Mathcad. Показано, что при вычислениях распределения нормальных напряжений по длине стержня лучшими свойствами относительно устойчивости обладает двухслойная схема The article gives the analysis of mechanical vibrations of the impact device elements using the model of the rod type. The hammer and the tool are connected by elastic and dissipative elements that simulate their interaction. The interaction of the tool with the processing medium is simulated in a similar way. An initial boundary-value problem is formulated for a system of two wave equations taking into account the variable cross sections of the rods. Cross-sectional areas are determined by parametric formulas maintaining the volume of the rods. Parametric formulas allow one to obtain various dependence types of the cross-sectional area of the rod on its length. The initial and boundary conditions reflect the physical phenomenon of the tool interaction with the processing medium, and also describe the contact interactions of the hammer with the tool. The impacting of the hammer and the tool through an element of high rigidity is considered as a model problem. To control the limiting values, the solution of the model problem by the Fourier method is used. The initial-boundary-value problem is investigated by the difference method. A comparison of solutions obtained for the two-layer and three-layer difference schemes is given. Such schemes are realized in a common computer program in the Mathcad. It is shown that the two-layer scheme has the best properties in relation to stability while calculating the distribution of normal voltage along the length of the rod


2021 ◽  
Vol 2021 (1) ◽  
Author(s):  
Liming Xiao ◽  
Mingkun Li

AbstractIn this paper, we study the initial boundary value problem for a class of higher-order n-dimensional nonlinear pseudo-parabolic equations which do not have positive energy and come from the soil mechanics, the heat conduction, and the nonlinear optics. By the mountain pass theorem we first prove the existence of nonzero weak solution to the static problem, which is the important basis of evolution problem, then based on the method of potential well we prove the existence of global weak solution to the evolution problem.


Open Physics ◽  
2020 ◽  
Vol 18 (1) ◽  
pp. 1161-1167
Author(s):  
Marin Marin ◽  
Praveen Ailawalia ◽  
Ioan Tuns

Abstract In this paper, we obtain a generalization of the Gronwall’s inequality to cover the study of porous elastic media considering their internal state variables. Based on some estimations obtained in three auxiliary results, we use this form of the Gronwall’s inequality to prove the uniqueness of solution for the mixed initial-boundary value problem considered in this context. Thus, we can conclude that even if we take into account the internal variables, this fact does not affect the uniqueness result regarding the solution of the mixed initial-boundary value problem in this context.


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