SURFACE-ACTIVE AND PERFORMANCE PROPERTIES OF CATIONIC IMIDAZOLINIUM SURFACTANTS BASED ON DIFFERENT FATTY ACIDS

2008 ◽  
Vol 15 (04) ◽  
pp. 361-367 ◽  
Author(s):  
DIVYA BAJPAI ◽  
V. K. TYAGI

Imidazoline surfactants belong to the category of cationic surfactants. Cationic surfactants are often quaternary nitrogen salts and are widely used both in nonaqueous systems and in applications such as textile softeners, dispersants, and emulsifiers. This study describes the surface-active properties of cationic imidazolinium surfactants synthesized from different fatty acids. Their laundry performance in combination with nonionic surfactants like detergency, foaming property, softening property, rewettability etc., is also emphasized.

2007 ◽  
Vol 14 (06) ◽  
pp. 1129-1133 ◽  
Author(s):  
SHILPI MISHRA ◽  
V. K. TYAGI

In this study, an attempt has been made to synthesize esteramide quat by esterification of palm fatty acids with 1(2-hydroxyethyl piperazine) followed by quaternization with dimethyl sulphate (DMS). The optimum reaction conditions for esterification of palm fatty acids and 1(2-hydroxyethyl piperazine) were found to be 170°C reaction temperature and 150 mmHg pressure. The obtained esteramide was subjected to quaternization with different molar ratios of DMS. The consequences revealed that esteramide to DMS ratio of 1 : 0.95 and duration of quaternization for 2 h yielded esteramide quat of maximum cationic content, i.e., 64.9%. The instrumental analysis, viz. FT-IR, 1 H NMR, 13 C NMR verified the esterification and subsequent quaternization of the obtained esteramide quat. Furthermore, the surface-active and performance properties of synthesized esteramide quat were also evaluated.


1984 ◽  
Vol 18 (11) ◽  
pp. 784-787 ◽  
Author(s):  
M. A. Chernyavskaya ◽  
V. V. Stefanovich ◽  
I. A. Sergeeva ◽  
A. S. Belova

2013 ◽  
Vol 16 (6) ◽  
pp. 857-863 ◽  
Author(s):  
Nabel A. Negm ◽  
Abdou Saad El-Tabl ◽  
Ismail A. Aiad ◽  
Khalid Zakareya ◽  
Ahmed H. Moustafa

2016 ◽  
Vol 61 (No. 3) ◽  
pp. 111-115 ◽  
Author(s):  
Y.I. Prokof ev ◽  
T.N. Poyarkova ◽  
A.R. Bykov ◽  
A.S. Shestakov ◽  
V.A. Kuznetsov ◽  
...  

From soapstock, which is a waste product of sunflower oil production, the fatty component was isolated using isopropyl alcohol, toluene, fusel oil and a mixture of common salt and nonionic surfactants. With the help of the Langmuir film balance the molecular areas of isolated fats were found and the degree of hydrophobization in comparison with the original soapstock was evaluated. It was found that the strongest compression of the monolayer is observed when using fusel oil. The surface active properties of emulsifiers, synthesized by alkaline hydrolysis method on the basis of the obtained fat extracts and original soapstock, were studied. These results are consistent with measurements on the Langmuir balance.


Sign in / Sign up

Export Citation Format

Share Document