COBALT(II)/NICKEL(II) COMPLEXES OF DITHIOACETYLACETONE [M(SacSac)2](M = Co, Ni) AS SINGLE SOURCE PRECURSORS FOR COBALT/NICKEL SULFIDE NANOSTRUCTURES

Cobalt(II)/Nickel(II) complexes of 4-thiopent-3-ene-2-thione (SacSac), [ M(SacSac) 2]( M = Co, Ni ) have been used as single source precursors (SSPs) for the preparation of cobalt/nickel sulfide thin films by aerosol-assisted chemical vapor deposition (AACVD). Cobalt or nickel sulfide nanoparticles were grown by thermal decomposition of the precursor in hot trioctylphosphine oxide (TOPO) or hexadecylamine (HDA). XRD analysis showed that all samples of cobalt or nickel sulfide are of the sulfur deficient phases ( Ni9S8, Co9S8, Ni7S6 , or Ni3S2 ). SEM and TEM analysis showed that nickel sulfide formed nanowires, nanorods and spheres; cobalt sulfide formed plate like structures and spheres. The chemical compositions of the nanoparticles can be controlled by varying temperature or the capping agents.

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Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

Chemistry of Materials ◽

10.1021/cm801330v ◽

2008 ◽

Vol 20 (19) ◽

pp. 6157-6162 ◽

Cited By ~ 73

Author(s):

Naveed Alam ◽

Michael S. Hill ◽

Gabriele Kociok-Köhn ◽

Matthias Zeller ◽

Muhammad Mazhar ◽

...

Keyword(s):

Chemical Vapor Deposition ◽

Vapor Deposition ◽

Nickel Sulfide ◽

Chemical Vapor ◽

Single Source ◽

Single Source Precursors

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Nickel(II) complexes of N-(dialkylcarbamothioyl)-4-nitrobenzamide as single-source precursors for the deposition of nanostructured nickel sulfide thin films by chemical vapor deposition

Journal of Coordination Chemistry ◽

10.1080/00958972.2013.807921 ◽

2013 ◽

Vol 66 (16) ◽

pp. 2788-2801 ◽

Cited By ~ 13

Author(s):

Sohail Saeed ◽

Naghmana Rashid ◽

Mohammad Azad Malik ◽

Paul O’Brien ◽

Wing-Tak Wong

Keyword(s):

Thin Films ◽

Chemical Vapor Deposition ◽

Vapor Deposition ◽

Nickel Sulfide ◽

Chemical Vapor ◽

Single Source ◽

Single Source Precursors

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Group III Metal Sulfide Thin Films From Single-Source Precursors by Chemical Vapor Deposition (CVD) Techniques

MRS Proceedings ◽

10.1557/proc-606-127 ◽

1999 ◽

Vol 606 ◽

Author(s):

Mike R. Lazell ◽

Paul O'brien ◽

David J. Otway ◽

Jin-Ho Park

Keyword(s):

Thin Films ◽

Vapor Deposition ◽

Vapour Deposition ◽

Chemical Vapour ◽

Metal Sulfide ◽

Chemical Vapor ◽

Single Source ◽

Group 13 ◽

Single Source Precursors ◽

Group Iii

AbstractSeveral single-source precursors including In(SOCNiBu2)3, In(S2CNMeHex)3 and Ga(S2CNMeR)3, (R = Et, Bu, Hex) have been prepared and used for the deposition of Group 13 metal sulfide thin films. The α and β-In2S3thin films on borosilicate glass and oc-Ga 2S3thin films on GaAs(111) single crystal substrates were prepared from the precursors by various chemical vapour deposition (CVD) techniques. These semicondcuting materials have been characterized by XRD, SEM, XPS and EDAX.

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Aerosol-Assisted Chemical Vapor Deposition of ZnS from Thioureide Single Source Precursors

Inorganic Chemistry ◽

10.1021/acs.inorgchem.8b03363 ◽

2019 ◽

Vol 58 (4) ◽

pp. 2784-2797 ◽

Cited By ~ 3

Author(s):

Hannah S. I. Sullivan ◽

James D. Parish ◽

Prem Thongchai ◽

Gabriele Kociok-Köhn ◽

Michael S. Hill ◽

...

Keyword(s):

Chemical Vapor Deposition ◽

Vapor Deposition ◽

Chemical Vapor ◽

Single Source ◽

Single Source Precursors

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Synthesis and characterization of Ni(II) complexes with functionalized dithiocarbamates: New single source precursors for nickel sulfide and nickel-iron sulfide nanoparticles

Inorganica Chimica Acta ◽

10.1016/j.ica.2019.119162 ◽

2019 ◽

Vol 498 ◽

pp. 119162 ◽

Cited By ~ 3

Author(s):

E. Sathiyaraj ◽

S Thirumaran ◽

Samuele Ciattini ◽

S. Selvanayagam

Keyword(s):

Nickel Sulfide ◽

Iron Sulfide ◽

Synthesis And Characterization ◽

Single Source ◽

Single Source Precursors ◽

Nickel Iron

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CuInS2 films deposited by aerosol-assisted chemical vapor deposition using ternary single-source precursors

Materials Science and Engineering B ◽

10.1016/j.mseb.2004.05.043 ◽

2005 ◽

Vol 116 (3) ◽

pp. 395-401 ◽

Cited By ~ 13

Author(s):

Michael H.-C. Jin ◽

Kulbinder K. Banger ◽

Jerry D. Harris ◽

Aloysius F. Hepp

Keyword(s):

Chemical Vapor Deposition ◽

Vapor Deposition ◽

Chemical Vapor ◽

Single Source ◽

Single Source Precursors

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Deposition of Bismuth Chalcogenide Thin Films Using Novel Single-Source Precursors by Metal-Organic Chemical Vapor Deposition.

ChemInform ◽

10.1002/chin.200443025 ◽

2004 ◽

Vol 35 (43) ◽

Author(s):

John Waters ◽

David Crouch ◽

James Raftery ◽

Paul O'Brien

Keyword(s):

Thin Films ◽

Chemical Vapor Deposition ◽

Vapor Deposition ◽

Chemical Vapor ◽

Organic Chemical ◽

Single Source ◽

Single Source Precursors ◽

Metal Organic ◽

Chalcogenide Thin Films ◽

Organic Chemical Vapor Deposition

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Structural, morphological and optical properties of iron sulfide, cobalt sulfide, copper sulfide, zinc sulfide and copper-iron sulfide nanoparticles synthesized from single source precursors

Chemical Physics Letters ◽

10.1016/j.cplett.2019.136972 ◽

2020 ◽

Vol 739 ◽

pp. 136972 ◽

Cited By ~ 6

Author(s):

E. Sathiyaraj ◽

S. Thirumaran

Keyword(s):

Optical Properties ◽

Zinc Sulfide ◽

Copper Sulfide ◽

Iron Sulfide ◽

Cobalt Sulfide ◽

Single Source ◽

Single Source Precursors

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Solvothermal Synthesis of Weakly Crystalline Cobalt-Nickel Sulfide to Obtain High Pseudocapacitance

10.21203/rs.3.rs-184247/v1 ◽

2021 ◽

Author(s):

Nao Zhang ◽

Ya-bo Zhu ◽

Tingting Xie ◽

Chao Shi ◽

Qian Xu ◽

...

Keyword(s):

Nickel Sulfide ◽

Retention Rate ◽

Solvent System ◽

Transmission Efficiency ◽

Cobalt Sulfide ◽

Synthesis Time ◽

Electrochemical Tests ◽

Cobalt Nickel ◽

Nickel Cobalt ◽

A Current

Abstract In this paper, a dual solvent system of glycerol and ethylene glycerol was used to prepare nickel cobalt sulfide with different crystallinity. It was found that the crystallinity and morphology of the product had an important effect on its electrochemical performance. Therefore, the synthesis time was chosen between 1 and 18 h to control the crystallinity. The best sample (GENCS-3) was prepared within 3hour, and had flower-like structures. Its electrochemical tests showed that it had good ion transmission efficiency and excellent specific capacitance (1816F/g at 1A/g, 1620F/g at 10 A/g). Especially, its retention rate could arrive at 89.5% after 1000 cycles under a current density of 5A/g. The weak crystalline nickel-cobalt sulfide is easy to form porous structure, which can significantly increase capacitance, also maintaining good rate performance.

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