STEREODYNAMICS AND ISOTOPE EFFECTS FOR THE REACTION N + NH → N2 + H
Quasi-Classical Trajectory (QCT) calculations have been carried out to study the stereodynamics of the reactions N + NH → N 2 + H and isotopic effects on the product polarization at collision energies of 10.0 kcal/mol and 25.0 kcal/mol which proceed on the Double-Many-Body-Expansion (DMBE) potential energy surface. The distribution of dihedral angle P(ϕr), and the distribution of angle between k and j′, P(θr) are discussed in detail. Furthermore, four generalized polarization dependent differential cross sections (PDDCSs) (2π/σ)(dσ00/dω), (2π/σ)(dσ20/dω), (2π/;σ)(dσ22+/dω), and (2π/σ)(dσ21 -∕dω) are presented. The results reveal that isotope effect plays an important role for P(ϕr) and P(θr) distribution, and the PDDCSs exhibit similar collision energy dependency relationship at low and high collision energies.