ORGANIC CuPc COATING INDUCED IMPROVED PHOTOLUMINESCENCE AND PHOTOCONDUCTIVITY OF ZnO NANOWIRES ARRAY
In this work, we investigated the effect of organic CuPc coating on the surface of the ZnO NWs for possible improvement in the photoluminescence, photoconductivity and photoresponse. As a result of surface covering, the UV emission is enhanced by a factor of 7–8 while the green emission is reduced to half. Despite an increase in dark current after the CuPc covering, we obtained a significant improvement in the photocurrent and photoresponse rate. The photocurrent-to-dark current ratio is nearly doubled and the photoresponse process becomes faster for the ZnO/CuPc heterostructure. Improvements in the photoluminescence and photoconductivity for the ZnO/CuPc heterostructure are explained on the basis of modification of surface defects and interfacial charge transfer process.