Self-templating synthesis of single crystalline LiNi0.5Mn1.5O4 nanotubes with improved electrochemical performance

2014 ◽  
Vol 07 (02) ◽  
pp. 1450009 ◽  
Author(s):  
Guoqing Wang ◽  
Jian Xie ◽  
Tiejun Zhu ◽  
Gaoshao Cao ◽  
Xinbing Zhao ◽  
...  

Single crystalline lithium nickel manganese oxide ( LiNi 0.5 Mn 1.5 O 4) nanotubes have been prepared by a facile self-templating method from β- MnO 2 nanotubes. The wall thickness and hollow part of the nanotubes are around 250 nm and 200 nm, respectively. The tubular LiNi 0.5 Mn 1.5 O 4 exhibits good rate capability and high-rate cycling stability. At 10 C, it can yield a high discharge capacity of 99 mAh g-1. After 550 cycles at 5 C, a discharge capacity of 85 mAh g-1 can be kept, indicating a promising application in high-power Li -ion batteries.

RSC Advances ◽  
2015 ◽  
Vol 5 (95) ◽  
pp. 78209-78214 ◽  
Author(s):  
Feifan Guo ◽  
Xiaoxin Zou ◽  
Kai-Xue Wang ◽  
Yipu Liu ◽  
Feng Zhang ◽  
...  

The porous N-doped carbon stabilized Li3V2(PO4)3 particles are obtained by using a modified sol–gel method, and the composite exhibits a high discharge capacity of 114.7 mA h g−1 at 1 C in the voltage range of 3–4.3 V after 600 cycles.


2013 ◽  
Vol 739 ◽  
pp. 21-25 ◽  
Author(s):  
Xiang Yin Mo ◽  
Xiao San Feng ◽  
Yi Ding ◽  
Cai Rong Kang

Carbon-coated, bismuth-doped, lithium iron phosphates, LiFe1xBixPO4(0x0.05), have been synthesized by a solid-state reaction method. From the optimization, the carbon-coated LiFe0.95Bi0.05PO4phase showed superior performances in terms of phase purity and high discharge capacity. The structural, morphological, and electrochemical properties were studied and compared to carbon-coated, LiFePO4. The Li/LiFe0.95Bi0.05PO4with carbon coating cell delivered an initial discharge capacity of 145 mAh/g and was 30 mAh/g higher than the Li/LiFePO4with carbon coating cell. Cyclic voltammetry revealed excellent reversibility of the LiFe0.95Bi0.05PO4with carbon coating material. High rate capability studies were also performed and showed a capacity retention over 93% during the cycling. It was concluded that substituted Bi ion play an important role in enhancing battery performance of the LiFePO4material through improving the kinetics of the lithium insertion/extraction reaction on the electrode.


2020 ◽  
Vol 4 (12) ◽  
pp. 6105-6111
Author(s):  
Jiaojiao Ren ◽  
Xuanxuan Yang ◽  
Jianfei Yu ◽  
Xizhang Wang ◽  
Yongbing Lou ◽  
...  

A multi-dimensional structured gaseous cathode: Co-NC@CNTs with interconnected 3D conductive carbon networks for a Li–O2 battery achieve high discharge capacity, rate capability and long cycling life.


RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92522-92525 ◽  
Author(s):  
Wei Guo ◽  
Lin Mei ◽  
Xiu Li ◽  
Minglei Mao ◽  
Jianmin Ma

In this communication, we have successfully obtained electrospun indium@carbon nanofibers. When applied as the Li-ion battery anode, the indium@carbon nanofibers could exhibit a high discharge capacity of 500 mA h g−1 after 200 cycles at 100 mA g−1.


RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 39710-39717 ◽  
Author(s):  
M. Viji ◽  
Pravati Swain ◽  
Pavana S. V. Mocherla ◽  
C. Sudakar

Bamboo-like vertically standing LFP nanotube bundles enable a better accessibility for Li-ion movement along 1D-channels in b-axis of olivine structure.


2018 ◽  
Vol 5 (1) ◽  
pp. 225-232 ◽  
Author(s):  
Hailiang Chu ◽  
Chunfeng Shao ◽  
Shujun Qiu ◽  
Yongjin Zou ◽  
Cuili Xiang ◽  
...  

Nitrogen-rich sandwich-like carbon nanosheets used as anodes for LIBs exhibited high discharge capacity and remarkable rate capability.


2018 ◽  
Vol 6 (41) ◽  
pp. 20056-20068 ◽  
Author(s):  
Ganesh Kumar Veerasubramani ◽  
Yuvaraj Subramanian ◽  
Myung-Soo Park ◽  
Goli Nagaraju ◽  
Baskar Senthilkumar ◽  
...  

The yolk–shell structured Fe1−xS encapsulated by N-doped carbon exhibited high discharge capacity, good cycling stability and excellent rate capability.


RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14495-14503
Author(s):  
Christopher N. Chervin ◽  
Ryan H. DeBlock ◽  
Joseph F. Parker ◽  
Bethany M. Hudak ◽  
Nathaniel L. Skeele ◽  
...  

Substituting electroinactive Al3+ into vanadium ferrite aerogels boosts capacity to battery-relevant levels but in a material that expresses pseudocapacitive character and high-rate performance.


2021 ◽  
Author(s):  
Jinkwang Hwang ◽  
Rika Hagiwara ◽  
Hiroshi Shinokubo ◽  
Ji-Young Shin

Dual-ion sodium-organic secondary batteries were provided with antiaromatic porphyrinoid, NiNc as an active electrode material, which implemented inherent charge-discharge behaviors with high discharge capacity, high stability, high Coulombic efficiency with...


2021 ◽  
Vol 9 (11) ◽  
pp. 7018-7024
Author(s):  
Takahiro Yoshinari ◽  
Datong Zhang ◽  
Kentaro Yamamoto ◽  
Yuya Kitaguchi ◽  
Aika Ochi ◽  
...  

A Cu–Au cathode material for all-solid-state fluoride-ion batteries with high rate-capability was designed as new concepts for electrochemical energy storage to handle the physicochemical energy density limit that Li-ion batteries are approaching.


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