A MOF derived Co-NC@CNT composite with a 3D interconnected conductive carbon network as a highly efficient cathode catalyst for Li–O2 batteries

2020 ◽  
Vol 4 (12) ◽  
pp. 6105-6111
Author(s):  
Jiaojiao Ren ◽  
Xuanxuan Yang ◽  
Jianfei Yu ◽  
Xizhang Wang ◽  
Yongbing Lou ◽  
...  

A multi-dimensional structured gaseous cathode: Co-NC@CNTs with interconnected 3D conductive carbon networks for a Li–O2 battery achieve high discharge capacity, rate capability and long cycling life.

2014 ◽  
Vol 07 (02) ◽  
pp. 1450009 ◽  
Author(s):  
Guoqing Wang ◽  
Jian Xie ◽  
Tiejun Zhu ◽  
Gaoshao Cao ◽  
Xinbing Zhao ◽  
...  

Single crystalline lithium nickel manganese oxide ( LiNi 0.5 Mn 1.5 O 4) nanotubes have been prepared by a facile self-templating method from β- MnO 2 nanotubes. The wall thickness and hollow part of the nanotubes are around 250 nm and 200 nm, respectively. The tubular LiNi 0.5 Mn 1.5 O 4 exhibits good rate capability and high-rate cycling stability. At 10 C, it can yield a high discharge capacity of 99 mAh g-1. After 550 cycles at 5 C, a discharge capacity of 85 mAh g-1 can be kept, indicating a promising application in high-power Li -ion batteries.


2018 ◽  
Vol 5 (1) ◽  
pp. 225-232 ◽  
Author(s):  
Hailiang Chu ◽  
Chunfeng Shao ◽  
Shujun Qiu ◽  
Yongjin Zou ◽  
Cuili Xiang ◽  
...  

Nitrogen-rich sandwich-like carbon nanosheets used as anodes for LIBs exhibited high discharge capacity and remarkable rate capability.


2018 ◽  
Vol 6 (41) ◽  
pp. 20056-20068 ◽  
Author(s):  
Ganesh Kumar Veerasubramani ◽  
Yuvaraj Subramanian ◽  
Myung-Soo Park ◽  
Goli Nagaraju ◽  
Baskar Senthilkumar ◽  
...  

The yolk–shell structured Fe1−xS encapsulated by N-doped carbon exhibited high discharge capacity, good cycling stability and excellent rate capability.


2021 ◽  
Author(s):  
Jinkwang Hwang ◽  
Rika Hagiwara ◽  
Hiroshi Shinokubo ◽  
Ji-Young Shin

Dual-ion sodium-organic secondary batteries were provided with antiaromatic porphyrinoid, NiNc as an active electrode material, which implemented inherent charge-discharge behaviors with high discharge capacity, high stability, high Coulombic efficiency with...


Nanoscale ◽  
2018 ◽  
Vol 10 (46) ◽  
pp. 21671-21680 ◽  
Author(s):  
Wenbin Li ◽  
Jianfeng Huang ◽  
Liangliang Feng ◽  
Liyun Cao ◽  
Shuwei He

The decreasing crystallinity of VS4 microspheres greatly increases the surface active sites, and then promotes the pseudocapacitive behavior, and finally leads to the high capacity, long cycling life and high rate capability.


2020 ◽  
Vol 4 (4) ◽  
pp. 1704-1711
Author(s):  
Zige Tai ◽  
Ming Shi ◽  
Wei Zhu ◽  
Xin Dai ◽  
Yanfei Xin ◽  
...  

We prepared carbon-coated β-MnO2 for the cathode of a lithium-ion battery with high discharge capacity.


2013 ◽  
Vol 739 ◽  
pp. 21-25 ◽  
Author(s):  
Xiang Yin Mo ◽  
Xiao San Feng ◽  
Yi Ding ◽  
Cai Rong Kang

Carbon-coated, bismuth-doped, lithium iron phosphates, LiFe1xBixPO4(0x0.05), have been synthesized by a solid-state reaction method. From the optimization, the carbon-coated LiFe0.95Bi0.05PO4phase showed superior performances in terms of phase purity and high discharge capacity. The structural, morphological, and electrochemical properties were studied and compared to carbon-coated, LiFePO4. The Li/LiFe0.95Bi0.05PO4with carbon coating cell delivered an initial discharge capacity of 145 mAh/g and was 30 mAh/g higher than the Li/LiFePO4with carbon coating cell. Cyclic voltammetry revealed excellent reversibility of the LiFe0.95Bi0.05PO4with carbon coating material. High rate capability studies were also performed and showed a capacity retention over 93% during the cycling. It was concluded that substituted Bi ion play an important role in enhancing battery performance of the LiFePO4material through improving the kinetics of the lithium insertion/extraction reaction on the electrode.


2016 ◽  
Vol 4 (19) ◽  
pp. 7289-7296 ◽  
Author(s):  
T. Kimijima ◽  
N. Zettsu ◽  
K. Yubuta ◽  
K. Hirata ◽  
K. Kami ◽  
...  

Highly dispersed primary Li(Ni1/3Co1/3Mn1/3)O2 crystals, which showed high discharge capacity at a high C-rate, were grown from a Li2MoO4 flux.


2007 ◽  
Vol 280-283 ◽  
pp. 671-676 ◽  
Author(s):  
Hong Wei Chan ◽  
Jenq Gong Duh ◽  
Shyang Roeng Sheen

Surface modification on the electrode has a vital impact on lithium-ion batteries, and it is essential to probe the mechanism of the modified film on the surface of the electrode. In this study, a Li2O-2B2O3 film was coated on the surface of the cathode material by solution method. The cathode powders derived from co-precipitation method were calcined with various weight percent of the surface modified glass to form fine powder of single spinel phase with different particle size, size distribution and morphology. The thermogravimetry/differential thermal analysis was used to evaluate the appropriate heat treatment temperature. The structure was confirmed by the X-ray diffractometer along with the composition measured by the electron probe microanalyzer. From the field emission scanning electron microscope image and Laser Scattering measurements, the average particle size was in the range of 7-8µm. The electrochemical behavior of the cathode powder was examined by using two-electrode test cells consisted of a cathode, metallic lithium anode, and an electrolyte of 1M LiPF6. Cyclic charge/discharge testing of the coin cells, fabricated by both coated and un-coated cathode material, provided high discharge capacity. Furthermore, the coated cathode powder showed better cyclability than the un-coated one after the cyclic test. The introduction of the glass-coated cathode material revealed high discharge capacity and appreciably decreased the decay rate after cyclic test.


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