Geochemical characteristics of rare earth elements (REEs) in soils developed on different parent materials, in the Baoshan area, Yunnan Province, Southwest China

2021 ◽  
pp. geochem2019-082
Author(s):  
Li Zhang ◽  
Wei Han ◽  
Min Peng ◽  
Fei Liu ◽  
Yuntao Song ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Alkali Metals ◽  
Yunnan Province ◽  
Southwest China ◽  
Regional Scale ◽  
Ionic Radii ◽  
Content Type ◽  
Parent Materials ◽  
Supplementary Material

The geochemistry of rare earth elements (REEs) was studied in rock samples from host formations, ore samples from two mineral deposits (the Hetaoping Cu-Pb-Zn mine: HTP and the Heiyanao Fe-Cu-Pb-Zn mine: HYA) and the overlying or nearby soils to better understand REE concentrations, distributions and behaviour during weathering from different parent materials at the regional scale, Baoshan area, Yunnan Province, Southwest China. The mudstone and sandstone formations have highest total REE (ΣREE) contents. Chondrite-normalized diagrams for rocks and ores show significant light REEs (LREEs) enrichments and Eu depletion (except for ores in HYA). Cerium displays an obvious negative anomaly in carbonate rocks (Є-3-R, C-R, D-R, T-1-R, and T-2-R). Soils overlying carbonate rock formations (T-1-S, C-S, and Є-3-S) have the highest ΣREE contents, while soils overlying basalts have the lowest ΣREE contents. Soils show enrichments in LREEs with negative Eu anomalies and slight Ce anomalies in the studied soils. Soils with high ∑LREE/∑heavy REE (HREE) values may result from the preferential absorption of LREEs by organic matter. Negative Eu anomalies in soils occur for parent materials in the study area lacking feldspar, especially soils developed from carbonates. Compared to the parent materials, most soils show REE enrichment because alkali metals are removed and REEs are concentrated by low mobility in surficial processes and positive Ce anomalies because of weathering dissolution of other trivalent REEs with ionic radii similar to that of Ca2+.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5303140

Geochemistry and environmental effects of rare earth elements in laterites from Yunnan province, southwest China

2021 ◽  
pp. geochem2021-039
Author(s):  
Bin Liang ◽  
Guilin Han ◽  
Jie Zeng ◽  
Rui Qu ◽  
Man Liu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Environmental Effects ◽  
Inductively Coupled Plasma ◽  
Anthropogenic Activities ◽  
Distribution Patterns ◽  
Content Type ◽  
Tropical Regions ◽  
Supplementary Material ◽  
And Migration

Rare earth elements (REEs) in soils are influenced by pedogenic processes and anthropogenic activities. To interpret the fractionation and migration of REEs during weathering in (sub-) tropical regions, the distribution, fractionation patterns, and environmental effects of REEs in laterites were investigated in this study. Soil samples from two laterite profiles (labeled with S1 and S2) were collected and the concentration of REEs were measured with an inductively coupled plasma mass spectrometer (ICP-MS). The results suggested that the ΣREEs of S2 (119 ± 10 mg/kg to 209 ± 10 mg/kg) has a higher concentration and a wider variation than that of S1 (114 ± 5 mg/kg to 154 ± 8 mg/kg). The REEs in both laterite profiles are enriched with the order of HREEs > LREEs > MREEs. The distribution patterns of laterite profiles show evidence of inheritance from parent granites. The laterites preferentially incorporated HREEs, and besides, secondary Fe2O3 and clay minerals were likely to affect the fractionation of REEs in laterites. The enrichment factor of REEs varies from 11.1 to 18.9 for S1 and 10.0 to 27.6 for S1, indicating potential pollution by REEs. The accumulation of REEs in laterites by mining activities should be a concern of environmental agencies of governments.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5609234

scholarly journals The PedS2/PedR2 Two-Component System Is Crucial for the Rare Earth Element Switch inPseudomonas putidaKT2440

mSphere ◽  
2018 ◽  
Vol 3 (4) ◽  
Author(s):  
Matthias Wehrmann ◽  
Charlotte Berthelot ◽  
Patrick Billard ◽  
Janosch Klebensberger
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Response Regulator ◽  
Regulatory Function ◽  
Methylotrophic Bacteria ◽  
Two Component System ◽  
Component System ◽  
Content Type ◽  
Two Component ◽  
Type Response

ABSTRACTInPseudomonas putidaKT2440, two pyrroloquinoline quinone-dependent ethanol dehydrogenases (PQQ-EDHs) are responsible for the periplasmic oxidation of a broad variety of volatile organic compounds (VOCs). Depending on the availability of rare earth elements (REEs) of the lanthanide series (Ln3+), we have recently reported that the transcription of the genes encoding the Ca2+-utilizing enzyme PedE and the Ln3+-utilizing enzyme PedH are inversely regulated. With adaptive evolution experiments, site-specific mutations, transcriptional reporter fusions, and complementation approaches, we now demonstrate that the PedS2/PedR2 (PP_2671/PP_2672) two-component system (TCS) plays a central role in the observed REE-mediated switch of PQQ-EDHs inP. putida. We provide evidence that in the absence of lanthanum (La3+), the sensor histidine kinase PedS2 phosphorylates its cognate LuxR-type response regulator PedR2, which in turn not only activatespedEgene transcription but is also involved in repression ofpedH. Our data further suggest that the presence of La3+lowers kinase activity of PedS2, either by the direct binding of the metal ions to the periplasmic region of PedS2 or by an uncharacterized indirect interaction, leading to reduced levels of phosphorylated PedR2. Consequently, the decreasingpedEexpression and concomitant alleviation ofpedHrepression causes—in conjunction with the transcriptional activation of thepedHgene by a yet unknown regulatory module—the Ln3+-dependent transition from PedE- to PedH-catalyzed oxidation of alcoholic VOCs.IMPORTANCEThe function of lanthanides for methanotrophic and methylotrophic bacteria is gaining increasing attention, while knowledge about the role of rare earth elements (REEs) in nonmethylotrophic bacteria is still limited. The present study investigates the recently described differential expression of the two PQQ-EDHs ofP. putidain response to lanthanides. We demonstrate that a specific TCS is crucial for their inverse regulation and provide evidence for a dual regulatory function of the LuxR-type response regulator involved. Thus, our study represents the first detailed characterization of the molecular mechanism underlying the REE switch of PQQ-EDHs in a nonmethylotrophic bacterium and stimulates subsequent investigations for the identification of additional genes or phenotypic traits that might be coregulated during REE-dependent niche adaptation.

scholarly journals Geological, Geochronological, and Geochemical Insights into the Formation of the Giant Pulang Porphyry Cu (–Mo–Au) Deposit in Northwestern Yunnan Province, SW China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 191 ◽  
Author(s):  
Qun Yang ◽  
Yun-Sheng Ren ◽  
Sheng-Bo Chen ◽  
Guo-Liang Zhang ◽  
Qing-Hong Zeng ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Yunnan Province ◽  
Oceanic Lithosphere ◽  
Late Triassic ◽  
Porphyry Cu ◽  
Icp Ms ◽  
Heavy Rare Earth Elements ◽  
Granodiorite Porphyry ◽  
Northwestern Yunnan

The giant Pulang porphyry Cu (–Mo–Au) deposit in Northwestern Yunnan Province, China, is located in the southern part of the Triassic Yidun Arc. The Cu orebodies are mainly hosted in quartz monzonite porphyry (QMP) intruding quartz diorite porphyry (QDP) and cut by granodiorite porphyry (GP). New LA-ICP-MS zircon U–Pb ages indicate that QDP (227 ± 2 Ma), QMP (218 ± 1 Ma, 219 ± 1 Ma), and GP (209 ± 1 Ma) are significantly different in age; however, the molybdenite Re–Os isochron age (218 ± 2 Ma) indicates a close temporal and genetic relationship between Cu mineralization and QMP. Pulang porphyry intrusions are enriched in light rare-earth elements (LREEs) and large ion lithophile elements (LILEs), and depleted in heavy rare-earth elements (HREEs) and high field-strength elements (HFSEs), with moderately negative Eu anomalies. They are high in SiO2, Al2O3, Sr, Na2O/K2O, Mg#, and Sr/Y, but low in Y, and Yb, suggesting a geochemical affinity to high-silica (HSA) adakitic rocks. These features are used to infer that the Pulang HSA porphyry intrusions were derived from the partial melting of a basaltic oceanic-slab. These magmas reacted with peridotite during their ascent through the mantle wedge. This is interpreted to indicate that the Pulang Cu deposit and associated magmatism can be linked to the synchronous westward subduction of the Ganzi–Litang oceanic lithosphere, which has been established as Late Triassic.

Differentiation of rare earth elements and yttrium in different size and density fractions of the Reshuihe coal, Yunnan Province, China

2019 ◽  
Vol 207 ◽  
pp. 1-11 ◽  
Author(s):  
Piaopiao Duan ◽  
Wenfeng Wang ◽  
Xiaohua Liu ◽  
Shuxun Sang ◽  
Mengya Ma ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Yunnan Province ◽  
Density Fractions

Removal of Fission Products in the Spent Electrolyte Using Iron Phosphate Glass as a Sorbent

2010 ◽  
Author(s):  
Ippei Amamoto ◽  
Naoki Mitamura ◽  
Tatsuya Tsuzuki ◽  
Yasushi Takasaki ◽  
Atsushi Shibayama ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Phosphate Glass ◽  
Alkali Metals ◽  
Fission Products ◽  
Iron Phosphate ◽  
Experimental Result ◽  
Filtration Method ◽  
High Level ◽  
Filtration Experiment

This study is carried out to make the pyroprocessing hold a competitive advantage from the viewpoint of environmental load reduction and economical improvement. As one of the measures to reduce the volume of the high-level radioactive waste (HLW), the phosphate conversion method is applied for removal of fission products (FP) from the melt, referring to the spent electrolyte in this paper. Among the removing target chlorides in the spent electrolyte i.e., alkali metals, alkaline earth metals and rare earth elements, only the rare earth elements and lithium form the precipitates as insoluble phosphates by reaction with Li3PO4. The sand filtration method was applied to separate FP precipitates from the spent electrolyte. The iron phosphate glass (IPG) powder, which is a compatible material for the immobilization of FP, was used as a filter medium. After filtration experiment, it was proven that insoluble FP could almost be completely removed from the spent electrolyte. Subsequently, we attempted to separate the dissolved FP from the spent electrolyte. The IPG was being used once again but this time as a sorbent instead. This is possible because the IPG has some unique characteristics, e.g., changing the valence of iron, which is one of its network modifiers due to its manufacturing temperature. Therefore, it would be likely to sorb some FP when the chemical condition of IPG is unstable. We produced three kinds of IPG under different manufacturing temperature and confirmed that those glasses could sorb FP as anticipated. According to the experimental result, its sorption efficiency of metal cations was attained at around 20–40%.

Green chemistry and sustainable development: approaches to chemical footprint analysis

2018 ◽  
Vol 90 (1) ◽  
pp. 143-155 ◽  
Author(s):  
Natalia P. Tarasova ◽  
Anna S. Makarova ◽  
Stanislav F. Vinokurov ◽  
Vladimir A. Kuznetsov ◽  
Pavel I. Shlyakhov
Keyword(s):  
Heavy Metals ◽  
Sustainable Development ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Regional Scale ◽  
Small Water ◽  
Federal Districts ◽  
Footprint Analysis ◽  
Development Goals ◽  
The Impact

AbstractThe methods to monitor the distribution of chemicals in the biosphere and to estimate the impact of chemicals on the biosphere are necessary to reach Sustainable Development Goals (SDGs). The paper presents the examples of methods to measure the concentration of heavy metals (including rare earth elements) and to rank them by the level of hazard to human health on different scales. The megacity scale presents the investigation of the impact of heavy metals on the small water bodies using water contamination index (WCI); and the investigation of snow contamination to estimate the level of short-term seasonal emission of heavy metals and rare earth elements. The 2nd part of the paper presents approaches to mitigate the exposure to mercury on the regional scale: the estimation of the current concentrations of mercury in atmospheric air, natural soils, and fresh waters using UNEP/SETAC USEtox model, as well as the estimations of the variations in the concentrations of mercury for the year 2045 in the federal districts of the Russian Federation, based on representative concentration pathways (RCPs) scenario and Minamata Convention scenario.

scholarly journals New microfossil and strontium isotope chronology used to identify the controls of Miocene reefs and related facies in NW Cyprus

2020 ◽  
pp. jgs2020-081
Author(s):  
Torin Cannings ◽  
Elizabeth M. Balmer ◽  
Giovanni Coletti ◽  
Ryan B. Ickert ◽  
Dick Kroon ◽  
...  
Keyword(s):  
Late Miocene ◽  
Regional Scale ◽  
Early Miocene ◽  
Late Oligocene ◽  
Sr Isotope ◽  
Two Phase ◽  
Planktic Foraminifera ◽  
Content Type ◽  
Supplementary Material ◽  
Global Sea Level

The existing chronostratigraphic framework in NW Cyprus of two-phase, Early and Late Miocene reef and associated facies development is tested and improved using a combination of calcareous nannofossil, benthic and planktic foraminiferal, and also Sr isotope dating. Following localised Late Oligocene neritic carbonate deposition (e.g. benthic foraminiferal shoals), reefs and related facies (Terra Member) began to develop c. 24 Ma (Aquitanian) and terminated c. 16 Ma (end-Burdigalian). Early Miocene reef and marginal facies were then extensively redeposited as multiple debris-flow deposits until c. 13.7 Ma, influenced by a combination of global sea-level fall (related to growth of the East Antarctic Ice Sheet) and local- to regional-scale tectonics. Reef growth and related deposition resumed (Koronia Member) c. 9.1 Ma (Tortonian), then terminated by c. 6.1 Ma (mid-Messinian), followed by the Messinian salinity crisis. Neritic accumulation in NW Cyprus began earlier (Late Oligocene), than in southern Cyprus (Early Miocene). The Early Miocene reefs developed on a c. N-S-trending structural high in the west (Akamas Peninsula area) whereas the Late Miocene reefs developed on both flanks of the neotectonic Polis graben. The two-phase reef development is mirrored in SE Cyprus and in some other Mediterranean areas; e.g. S Turkey, Israel, Italy, S Spain.Supplementary material: GPS Locations of dated samples, the Sr isotope method and the samples examined for planktic foraminifera biostratigraphy are available at https://doi.org/10.6084/m9.figshare.c.5205315.

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