Managing personal desktop computing at Argonne National laboratory

Author(s):  
Debbie W. Coultis ◽  
Marc A. Gallo
Author(s):  
Charles W. Allen ◽  
Robert C. Birtcher

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.


Author(s):  
H. K. Birnbaum ◽  
I. M. Robertson

Studies of the effects of hydrogen environments on the deformation and fracture of fcc, bcc and hep metals and alloys have been carried out in a TEM environmental cell. The initial experiments were performed in the environmental cell of the HVEM facility at Argonne National Laboratory. More recently, a dedicated environmental cell facility has been constructed at the University of Illinois using a JEOL 4000EX and has been used for these studies. In the present paper we will describe the general design features of the JEOL environmental cell and some of the observations we have made on hydrogen effects on deformation and fracture.The JEOL environmental cell is designed to operate at 400 keV and below; in part because of the available accelerating voltage of the microscope and in part because the damage threshold of most materials is below 400 keV. The gas pressure at which chromatic aberration due to electron scattering from the gas molecules becomes excessive does not increase rapidly with with accelerating voltage making 400 keV a good choice from that point of view as well. A series of apertures were placed above and below the cell to control the pressures in various parts of the column.


2011 ◽  
Vol 20 (02) ◽  
pp. 474-481 ◽  
Author(s):  
A.B. HAYES ◽  
D. CLINE ◽  
C. Y. WU ◽  
A.M. HURST ◽  
M.P. CARPENTER ◽  
...  

A 985 MeV 178 Hf beam was Coulomb excited by a 208 Pb target at the ATLAS accelerator of Argonne National Laboratory. Gammasphere and the CHICO particle detector recorded particle-γ coincidence data. The aim was to populate and determine the mechanism of previously observed Coulomb excitation of the Kπ = 6+ (t1/2 = 77 ns ), 8- (4 s ) and 16+ (31 y ) isomer bands. New rotational bands were identified including an aligned band which appears to mix with the ground-state band (GSB) and the γ-vibrational band above ~ 12 ħ of angular momentum. Newly observed γ-decay transitions into the three isomer bands may elucidate the K-mixing which allows Coulomb excitation of these isomer bands, but direct decays from the GSB into the 16+ isomer band have not yet been confirmed.


2006 ◽  
Vol 985 ◽  
Author(s):  
Dawn E. Janney

AbstractArgonne National Laboratory has developed an electrometallurgical process for conditioning spent sodium-bonded metallic reactor fuel from the Experimental Breeder Reactor II (EBR-II). One waste stream from this process consists of a metal waste form (MWF) whose baseline composition is stainless steel alloyed with 15 wt% Zr (SS-15Zr) and whose microstructure is a eutectic intergrowth of iron solid solutions and Fe-Zr-Cr-Ni intermetallics. This paper reports scanning electron microscope (SEM) observations of corrosion products formed during static immersion tests in which coupons of surrogate MWF containing 10 wt% U (SS-15Zr-10U) were immersed in solutions with nominal pH values of 3 and 4 and 1000 ppm added chloride for 70 days at 50 °C. Although the majority of the surface areas of the coupons appear unchanged, linear areas with localized corrosion products apparently consisting of porous materials overlying corrosion-product-filled channels formed on both coupons, cross-cutting phase boundaries in the original eutectic microstructures. Many of the linear areas intersected the sample edge at notches present before the tests or followed linear flaws visible in pre-test images. Compositions of corrosion products differed significantly from the bulk composition, and the maximum observed concentration of U exceeded that reported in actinide-bearing phases in uncorroded surrogate MWF samples with comparable concentrations of U.


2012 ◽  
Vol 27 (4) ◽  
pp. 256-262 ◽  
Author(s):  
W. Wong-Ng ◽  
J. A. Kaduk ◽  
H. Wu ◽  
M. Suchomel

M2(dhtp)·nH2O (M = Mn, Co, Ni, Zn; dhtp = 2,5-dihydroxyterephthalate), known as MOF74, is a family of excellent sorbent materials for CO2 that contains coordinatively unsaturated metal sites and a honeycomb-like structure featuring a broad one-dimensional channel. This paper describes the structural feature and provides reference X-ray powder diffraction patterns of these four isostructural compounds. The structures were determined using synchrotron diffraction data obtained at beam line 11-BM at the Advanced Photon Source (APS) in the Argonne National Laboratory. The samples were confirmed to be hexagonal R 3 (No. 148). From M = Mn, Co, Ni, to Zn, the lattice parameter a of MOF74 ranges from 26.131 73(4) Å to 26.5738(2) Å, c from 6.651 97(5) to 6.808 83(8) Å, and V ranges from 3948.08 Å3 to 4163.99 Å3, respectively. The four reference X-ray powder diffraction patterns have been submitted for inclusion in the Powder Diffraction File (PDF).


1997 ◽  
Vol 32 (1-4) ◽  
pp. 303-326 ◽  
Author(s):  
David B. Chamberlain ◽  
Cliff Conner ◽  
Joseph C. Hutter ◽  
Ralph A. Leonard ◽  
David G. Wygmans ◽  
...  

Author(s):  
Kun Chen ◽  
Hanchung Tsai ◽  
Bud Fabian ◽  
Yung Liu ◽  
James Shuler

A temperature-monitoring system based on radiofrequency identification (RFID) has been developed for extending the maintenance period of the nuclear material packaging for storage and transportation. The system consists of tags, readers, and application software. The tag, equipped with a temperature sensor, is attached to the exterior of a package. The application software enables remote reading, via radio waves, of the temperature from the sensor in the tag. The system reports any temperature violations immediately via e-mail or text message, and/or posts the alarm on a secure website. The system can monitor thousands of packages and record individual temperature histories in a database. The first type of packaging that will benefit from the RFID technology is Model 9977, which has been certified by the U.S. Department of Energy (DOE) to ship and store fissile materials such as plutonium and uranium. The recorded data can be correlated to the temperature of the containment O-ring seals, based on the decay heat load of the contents. Accelerated aging studies of the Viton® GLT O-rings have shown that temperature is one of the key parameters governing the life of the O-ring seals, which maintain the integrity of the containment boundary of the package. Use of the RFID temperature-monitoring system to verify that the surface temperature remains below a certain threshold will make it possible to extend the leak-test period of the package from one year to up to five years. The longer leak-rate testing interval will yield a cost savings of up to $10,000 per package over five years. This work was conducted by Argonne National Laboratory in support of the DOE Packaging Certification Program, Office of Environmental Management, Office of Packaging and Transportation (EM-63).


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