Real-Time Continuous Rapid Colorimetric Sensor for Gaseous Formaldehyde Determination by Increasing Gas-Liquid Reaction Rate

Author(s):  
Yan Chen ◽  
Siting Liu ◽  
Honglan Jiang ◽  
Jiejian Zhang ◽  
Zhaohui Zhang ◽  
...  
Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 3141 ◽  
Author(s):  
Xiao-Liang Guo ◽  
Yan Chen ◽  
Hong-Lan Jiang ◽  
Xian-Bo Qiu ◽  
Du-Li Yu

Formaldehyde is one of the most dangerous air pollutants, which can cause sick building syndrome. Thus, it is very crucial to precisely determine formaldehyde with a low cost and simple operation. In this paper, a smartphone-based microfluidic colorimetric sensor is devised for gaseous formaldehyde determination with high sensitivity and selectivity. Specifically, a novel microfluidic chip is proposed based on the 4-aminohydrazine-5-mercapto-1,2,4-triazole (AHMT) method to determine formaldehyde; the chip consists of two reagent reservoirs, one reaction reservoir and a mixing column. In this design to prevent the fluid from flowing out while letting the gas molecule in, a hydrophobic porous poly tetra fluoroethylene (PTFE) membrane is put on the top of the reaction reservoir. Using the microfluidic chip sensor, a smartphone-based formaldehyde determination system is developed, which makes the measuring process automated and simple. As per the experiment results, the limit-of-detection (LOD) of the system is as low as 0.01 ppm, which is much lower than the maximum exposure concentration (0.08 ppm) recommended by the World Health Organization (WHO). Moreover, the sensor is hardly affected by acetaldehyde, volatile organic compounds (VOCs) or acidic-alkaline, which shows great selectivity. Finally, the performance of the proposed sensor is verified by using it for the determination of formaldehyde in a newly decorated house.


2012 ◽  
Vol 35 ◽  
pp. 741-751 ◽  
Author(s):  
Özlem Cizer ◽  
Koen Van Balen ◽  
Jan Elsen ◽  
Dionys Van Gemert

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1256
Author(s):  
Fernando J. Beltrán ◽  
Manuel Checa ◽  
Javier Rivas ◽  
Juan F. García-Araya

In a water ozonation process, dissolved organics undergo two reactions at least: direct ozone attack and oxidation with hydroxyl radicals generated from the ozone decomposition. In the particular case of urban wastewater contaminated with pharmaceuticals, competition between these two reactions can be studied through application of gas–liquid reaction kinetics. However, there is a lack in literature about kinetic modeling of ozone processes in water specially in photocatalytic ozonation. In this work, lumped reactions of ozone and hydroxyl radicals with total organic carbon have been proposed. Urban wastewater containing a mixture of eight pharmaceutical compounds has been used to establish the kinetic model that simulates the mineralization process. The kinetic model is based on a mechanism of free radical and molecular reactions and the knowledge of mass transfer, chemical reaction rate constants, and radiation transfer data. According to the model, both single ozonation and photocatalytic ozonation present two distinct reaction periods characterized by the absence and presence of dissolved ozone. In the first period (less than 10 min), pharmaceuticals mainly disappear by direct ozone reactions and TOC variation due to these compounds has been modeled according to gas–liquid reaction kinetics through a lumped ozone-pharmaceutical TOC fast second order reaction. The corresponding rate constant of this reaction was found to change with time from 3 × 105 to 200 M−1 s−1 with Hatta values higher than 0.3. In the second period (nearly 5 h), competition between direct and hydroxyl radical reactions takes place and a kinetic model based on a direct and free radical reaction mechanism is proposed. Main influencing parameters to be known were: Direct ozone reaction rate constant, catalyst quantum yield, and hydroxyl radical scavengers. The first two take values of 0.5 M−1 s−1 and 5 × 10−4 mol·photon−1, respectively, while a fraction of TOC between 10% and 90% that changes with time was found to possess hydroxyl radical scavenger nature.


2017 ◽  
Vol 72 ◽  
pp. 583-589 ◽  
Author(s):  
Sanduru Thamarai Krishnan ◽  
Kuk Hui Son ◽  
Namhyoung Kim ◽  
Buddolla Viswanath ◽  
Sanghyo Kim ◽  
...  

APL Photonics ◽  
2020 ◽  
Vol 5 (1) ◽  
pp. 016105 ◽  
Author(s):  
Ruisi Wang ◽  
Junxiao Zhou ◽  
Kuiming Zeng ◽  
Shizhen Chen ◽  
Xiaohui Ling ◽  
...  

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