Stability of Catholytes in Vanadium Redox Flow Batteries and the Kinetics of Precipitation of VV

2016 ◽  
Batteries ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 56 ◽  
Author(s):  
Vida Krikstolaityte ◽  
Oh Joshua ◽  
Andrei Veksha ◽  
Nyunt Wai ◽  
Grzegorz Lisak ◽  
...  

This study presents the application of pyrolyzed spent coffee beans as a potential electrode material to replace commercial bipolar graphite plate in vanadium redox flow batteries (VRB). The results indicate that the biochar obtained from spent coffee beans shows relatively good electrochemical charge transfer kinetics of vanadium redox reactions as well as generates higher energy and voltage efficiency in a static cell test when compared to TF6 bipolar graphite plate. Additionally, the biochar was activated via steam at various activation times to increase its surface area, and their effect on the kinetics of the electrochemical reactions was investigated. The activated carbon did not exhibit any improvement neither in electron transfer kinetics nor in the battery efficiency, despite their increased surface area. The performed studies demonstrate that the biochar obtained from spent coffee beans can be a low-cost electrode material for VRB with improved performance characteristics.


2020 ◽  
Vol 7 (4) ◽  
pp. 1023-1028 ◽  
Author(s):  
Lei Zhang ◽  
Qiang Ma ◽  
Jun‐Ping Hu ◽  
Jun Liu ◽  
Qi Deng ◽  
...  

Carbon ◽  
2013 ◽  
Vol 60 ◽  
pp. 280-288 ◽  
Author(s):  
Cristina Flox ◽  
Javier Rubio-García ◽  
Marcel Skoumal ◽  
Teresa Andreu ◽  
Juan Ramón Morante

Author(s):  
Han-Wen Chou ◽  
Feng-Zhi Chang ◽  
Hwa-Jou Wei ◽  
Bhupendra Singh ◽  
Amornchai Arpornwichanop ◽  
...  

Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 176
Author(s):  
Iñigo Aramendia ◽  
Unai Fernandez-Gamiz ◽  
Adrian Martinez-San-Vicente ◽  
Ekaitz Zulueta ◽  
Jose Manuel Lopez-Guede

Large-scale energy storage systems (ESS) are nowadays growing in popularity due to the increase in the energy production by renewable energy sources, which in general have a random intermittent nature. Currently, several redox flow batteries have been presented as an alternative of the classical ESS; the scalability, design flexibility and long life cycle of the vanadium redox flow battery (VRFB) have made it to stand out. In a VRFB cell, which consists of two electrodes and an ion exchange membrane, the electrolyte flows through the electrodes where the electrochemical reactions take place. Computational Fluid Dynamics (CFD) simulations are a very powerful tool to develop feasible numerical models to enhance the performance and lifetime of VRFBs. This review aims to present and discuss the numerical models developed in this field and, particularly, to analyze different types of flow fields and patterns that can be found in the literature. The numerical studies presented in this review are a helpful tool to evaluate several key parameters important to optimize the energy systems based on redox flow technologies.


2021 ◽  
Vol 289 ◽  
pp. 116690
Author(s):  
Z.H. Zhang ◽  
L. Wei ◽  
M.C. Wu ◽  
B.F. Bai ◽  
T.S. Zhao

2021 ◽  
Vol 39 ◽  
pp. 166-175
Author(s):  
Zeyu Xu ◽  
Mingdong Zhu ◽  
Kaiyue Zhang ◽  
Xihao Zhang ◽  
Lixin Xu ◽  
...  

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