Elucidating Effect of Transition Metal on Anionic Oxygen Activity in High-Energy Li-Rich Layered Oxides

Author(s):  
Yan-Hui Chen ◽  
Jing Zhang ◽  
Li Yi ◽  
Yongfan Zhang ◽  
Shuping Huang ◽  
...  

Ni-rich layered oxides, like LiNi0.8Co0.1Mn0.1O2 (NCM811), have been widely investigated as cathodes for high energy density. However, gradual structural transformation during cycling can lead to capacity degradation and potential decay...


2020 ◽  
Vol 13 (4) ◽  
pp. 1269-1278 ◽  
Author(s):  
Kyojin Ku ◽  
Byunghoon Kim ◽  
Sung-Kyun Jung ◽  
Yue Gong ◽  
Donggun Eum ◽  
...  

We propose a new lithium diffusion model involving coupled lithium and transition metal migration, peculiarly occurring in a lithium-rich layered oxide.


Author(s):  
Indeok Lee ◽  
Gwangeon Oh ◽  
Seulgi Lee ◽  
Tae-Yeon Yu ◽  
Muhammad Hilmy Alfaruqi ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qizhang Yan ◽  
Mingqian Li ◽  
Hongpeng Gao ◽  
Jianhua Tian ◽  
...  

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for the next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer...


2021 ◽  
Vol MA2021-02 (42) ◽  
pp. 1283-1283
Author(s):  
Guiliang Xu ◽  
Xiang LIU ◽  
Khalil Amine

2013 ◽  
Vol 06 (01) ◽  
pp. 1330001 ◽  
Author(s):  
JING XU ◽  
DAE HOE LEE ◽  
YING SHIRLEY MENG

Significant progress has been achieved in the research on sodium intercalation compounds as positive electrode materials for Na-ion batteries. This paper presents an overview of the breakthroughs in the past decade for developing high energy and high power cathode materials. Two major classes, layered oxides and polyanion compounds, are covered. Their electrochemical performance and the related crystal structure, solid state physics and chemistry are summarized and compared.


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