The Mechanism of Electrochemical Oxidation of Sulphite on Gold Nanoparticles

2018 ◽  
Vol 16 (1) ◽  
pp. 8-12 ◽  
Author(s):  
Muhammad Saqaf Jagirani ◽  
Sarfaraz Ahmed Mahesar ◽  
Sirajuddin ◽  
Syed Tufail Hussain Sherazi ◽  
Munawar Saeed Qureshi ◽  
...  

2014 ◽  
Vol 1040 ◽  
pp. 297-302 ◽  
Author(s):  
D.O. Perevezentseva ◽  
E.V. Gorchakov

The electrochemical activity of gold nanoparticles at graphite electrodes by the method of cyclic voltammetry is studied. In this article the nature of the supporting electrolyte, modification time of graphite electrode by gold nanoparticles and the potential range on the value of the “inverse” cathodic peak are investigated. The “inverse” cathodic peak of gold nanoparticles formed in the reaction mixture HAuCl4:Na3C6H5O7:NaBH4=1:1:4 is observed on the cathodic branch of cyclic voltamperegram at Ec = 0.05 V at graphite electrode. The mechanism of stepwise electrochemical oxidation and reduction of the phase structure of gold on the surface of the graphite electrode in 0.1 M NaOH is offered. The “inverse” cathodic peak of gold nanoparticles on the cathodic branch of cyclic voltammogram at graphite electrode is caused by oxidation of Au2O to Au2O3.<br /><br />


2015 ◽  
Vol 53 ◽  
pp. 11-14 ◽  
Author(s):  
Donghyeop Han ◽  
Sung-Soo Kim ◽  
Yang-Rae Kim ◽  
Byeong-Hyeok Sohn ◽  
Taek Dong Chung

2016 ◽  
Vol 4 (9) ◽  
pp. 3278-3286 ◽  
Author(s):  
C. Engelbrekt ◽  
N. Šešelj ◽  
R. Poreddy ◽  
A. Riisager ◽  
J. Ulstrup ◽  
...  

Atomically thin platinum shells on gold nanoparticles (NPs) are synthesized in one pot under mild conditions. The core-shell NPs exhibit excellent catalysis for energy related processes such as electrochemical oxidation of biofuels, aromatic ring hydrogenation, and γ-valerolactone production.


RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 49798-49805 ◽  
Author(s):  
Mohsen Irandoust ◽  
Maryam Haghighi

A novel sensitive voltammetric method is described for the determination of dinitramine based on its electrochemical oxidation on gold electrodes modified with Fe3O4@SiO2–Si–(CH2)3–SH core shell (Au/Au–NPs–S–(CH2)3–Si–SiO2@Fe3O4).


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