Near-Infrared Optical Properties and Charge Transport in Expanded Porphyrins

2021 ◽  
Vol MA2021-01 (16) ◽  
pp. 761-761
Author(s):  
Gloria Cardenas-Jiron ◽  
Merlys Borges-Martinez ◽  
Nicolas Montenegro-Pohlhammer ◽  
Yoh Yamamoto ◽  
Tunna Baruah ◽  
...  
2000 ◽  
Vol 72 (3) ◽  
pp. 383-391 ◽  
Author(s):  
Rinaldo Cubeddu ◽  
Cosimo D'Andrea ◽  
Antonio Pifferi ◽  
Paola Taroni ◽  
Alessandro Torricelli ◽  
...  

Author(s):  
Jin-Dou Huang ◽  
Jinfeng Zhao ◽  
Kun Yu ◽  
Xiaohua Huang ◽  
Shi-Bo Cheng ◽  
...  

The conducting and optical properties of a series of indeno[1,2-b]fluorene-6,12-dione (IFD)-based molecules have been systematically studied and the influences of butyl, butylthio and dibutylamino substituents on the reorganization energies, intermolecular electronic couplings and charge-injection barriers of IFD have been discussed. The quantum-chemical calculations combined with electron-transfer theory reveal that the incorporation of sulfur-linked side chains decreases reorganization energy associated with hole transfer and optimizes intermolecular π–π stacking, which results in excellent ambipolar charge-transport properties (μh = 1.15 cm2 V−1 s−1 and μe = 0.08 cm2 V−1 s−1); in comparison, addition of dibutylamino side chains increases intermolecular steric interactions and hinders perfect intermolecular π–π stacking, which results in the weak electronic couplings and finally causes the low intrinsic hole mobility (μh = 0.01 cm2 V−1 s−1). Furthermore, electronic spectra of butyl-IFD, butylthio-IFD and dibutylamino-IFD were simulated and compared with the reported experimental data. Calculations demonstrate that IFD-based molecules possess potential for developing novel infrared and near-infrared probe materials via suitable chemical modifications.


1992 ◽  
Vol 72 (9) ◽  
pp. 4295-4299 ◽  
Author(s):  
I. Sagnes ◽  
G. Vincent ◽  
P. A. Badoz

2019 ◽  
Vol 115 (16) ◽  
pp. 161902 ◽  
Author(s):  
Akshay Singh ◽  
Yifei Li ◽  
Balint Fodor ◽  
Laszlo Makai ◽  
Jian Zhou ◽  
...  

2020 ◽  
Vol 826 ◽  
pp. 153946 ◽  
Author(s):  
Xiaolong Qing ◽  
Le Yuan ◽  
Can Wang ◽  
Mei Bi ◽  
Yaqin Wang ◽  
...  

1990 ◽  
Vol 68 (5) ◽  
pp. 2346-2350 ◽  
Author(s):  
J. Y. Duboz ◽  
P. A. Badoz ◽  
J. Henz ◽  
H. von Känel

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