scholarly journals Cloud Point Extraction of Toxic Reactive Black 5 Dye from Water Samples Using Triton X-100 as Nonionic Surfactant

2011 ◽  
Vol 8 (4) ◽  
pp. 1606-1613 ◽  
Author(s):  
Raziyeh Mousavi ◽  
Farzin Nekouei
Keyword(s):  
Cloud Point ◽  
Salt Concentration ◽  
Water Samples ◽  
Cloud Point Extraction ◽  
Extraction Procedure ◽  
Ionic Surfactant ◽  
Reactive Black 5 ◽  
Optimum Conditions ◽  
Single Extraction ◽  
Triton X

A surfactant mediated cloud point extraction (CPE) procedure has been developed to remove color from wastewater containing reactive black 5, using triton x-100 (TX-100) as non-ionic surfactant. The effects of the concentration of the surfactant, pH, temperature and salt concentration on the different concentrations of dye have been studied and optimum conditions were obtained for the removal of reactive black 5 (RB 5). The concentration of RB 5 in the dilute phase was measured using UV-Vis spectrophotometer. It was found that the separation of phases was complete and the recovery of RB 5 was very effective in the presence of NaCl as an electrolyte. The results showed that up to 600 mg L-1of RB 5 can quantitatively be removed (>97%) by cloud point extraction procedure in a single extraction using optimum conditions.

scholarly journals Removal of Direct Yellow 12 from Water Samples by Cloud Point Extraction Using Triton X-100 as Nonionic Surfactant

2011 ◽  
Vol 8 (4) ◽  
pp. 1588-1595 ◽  
Author(s):  
Shahnaz Abedi ◽  
Farzin Nekouei
Keyword(s):  
Nonionic Surfactant ◽  
Cloud Point ◽  
Salt Concentration ◽  
Water Samples ◽  
Cloud Point Extraction ◽  
Extraction Procedure ◽  
Optimum Conditions ◽  
Single Extraction ◽  
Triton X

A surfactant mediated cloud point extraction (CPE) procedure has been developed to remove color from wastewater containing direct yellow 12 (Chrysophenine G), using triton x-100 (TX-100) as nonionic surfactant. The effects of the concentration of the surfactant, pH, temperature and salt concentration on the different concentration of dye have been studied and optimum conditions were obtained for the removal of direct yellow 12 (DY 12). The concentration of DY 12 in the dilute phase was measured using UV-Vis spectrophotometer. It was found that the separation of phases was complete and the recovery of DY 12 was very effective in the presence of NaCl as an electrolyte. The results showed that up to 600 mg L−1of DY 12 can quantitatively be removed (>96%) by Cloud point extraction procedure in a single extraction using optimum conditions.

A cloud point extraction procedure for gallium, indium and thallium determination in liquid crystal display and sediment samples

2015 ◽  
Vol 7 (5) ◽  
pp. 2114-2120 ◽  
Author(s):  
Wael I. Mortada ◽  
Ibrahim M. Kenawy ◽  
Mohamed M. Hassanien
Keyword(s):  
Liquid Crystal ◽  
Cloud Point ◽  
Cloud Point Extraction ◽  
Liquid Crystal Display ◽  
Extraction Procedure ◽  
Ionic Surfactant ◽  
Sediment Samples ◽  
Separation And Preconcentration ◽  
Thallium Determination ◽  
Triton X

A simple, sensitive and rapid cloud point extraction (CPE) methodology has been developed for the selective separation and preconcentration of gallium, indium and thallium, after complexation with gallic acid in the presence of Triton X-114 as a non-ionic surfactant.

Cloud Point Extraction of Direct Blue 71 Dye using Triton X-100 as Nonionic Surfactant

2021 ◽  
Vol 58 (1) ◽  
pp. 27-32
Author(s):  
Moussa Alibrahim
Keyword(s):  
Cloud Point ◽  
Salt Concentration ◽  
Dye Removal ◽  
Cloud Point Extraction ◽  
Blue Dye ◽  
Ionic Surfactant ◽  
Optimal Conditions ◽  
Direct Blue ◽  
Triton X ◽  
Direct Blue 71

Abstract A surfactant-mediated cloud point extraction (CPE) method using the non-ionic surfactant Triton X-100 (TX-100) has been developed to remove the dye Direct Blue 71 (DB71) from a waste water. Most of the dye molecules are solubilized in the coacervate phase so that the dilute phase remains free of the dye. The effects of surfactant concentration, temperature and salt concentration on the different dye concentrations were studied to determine the optimal conditions for removing DB71. The concentration of DB71 in the dilute phase was measured using UV-Vis spectrophotometer. It was found that the separation of phases was complete and the recovery of DB71 was very effective in the presence of NaCl as an electrolyte. The results showed that up to 25 ppm DB71, i.e. more than 95%, can be quantitatively removed by cloud point extraction procedures in a single extraction at optimal conditions. It was also observed that at a dye concentration of 1 ppm, 100% of the blue dye DB71 can be directly removed with a TX-100 concentration of 12% by weight. At higher dye concentrations of up to 30 ppm, 94.7%-100% dye can be removed. The TX-100 concentration was 12 wt%, the salt concentration (NaCl) 0.005 M and the temperature 75°C. It is concluded that the surfactant mediated cloud point extraction method for dye removal can be an alternative to current dye removal methods.

scholarly journals Development of a Cloud-Point Extraction Method for Cobalt Determination in Natural Water Samples

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Mohammad Reza Jamali ◽  
Mohammad Gholinezhad ◽  
Saiedeh Balarostaghi ◽  
Reyhaneh Rahnama ◽  
Seyed Hojjat Allah Rahimi
Keyword(s):  
Cloud Point ◽  
Water Samples ◽  
Cloud Point Extraction ◽  
Limit Of Detection ◽  
Cobalt Content ◽  
Cobalt Ions ◽  
Flame Atomic Absorption ◽  
Relative Standard ◽  
Separation And Preconcentration ◽  
Triton X

A new, simple, and versatile cloud-point extraction (CPE) methodology has been developed for the separation and preconcentration of cobalt. The cobalt ions in the initial aqueous solution were complexed with 4-Benzylpiperidinedithiocarbamate, and Triton X-114 was added as surfactant. Dilution of the surfactant-rich phase with acidified ethanol was performed after phase separation, and the cobalt content was measured by flame atomic absorption spectrometry. The main factors affecting CPE procedure, such as pH, concentration of ligand, amount of Triton X-114, equilibrium temperature, and incubation time were investigated and optimized. Under the optimal conditions, the limit of detection (LOD) for cobalt was 0.5 μg L-1, with sensitivity enhancement factor (EF) of 67. Calibration curve was linear in the range of 2–150 μg L-1, and relative standard deviation was 3.2% (c=100 μg L-1;n=10). The proposed method was applied to the determination of trace cobalt in real water samples with satisfactory analytical results.

Analysis of Six Organophosphorus Pesticide Residues in Apples and Pears Using Cloud-point Extraction Coupled with HPLC-UV

2014 ◽  
Vol 97 (4) ◽  
pp. 1202-1205 ◽  
Author(s):  
Lijin Zhang ◽  
Fang Chen ◽  
Wenhuan Zhang ◽  
Canping Pan
Keyword(s):  
Cloud Point ◽  
Extraction Method ◽  
Cloud Point Extraction ◽  
Organophosphorus Pesticides ◽  
Extraction Procedure ◽  
Organophosphorus Pesticide ◽  
Equilibrium Temperature ◽  
Equilibrium Time ◽  
Temperature Equilibrium ◽  
Triton X

Abstract A cloud-point extraction (CPE) method with Triton X-114 has been developed for analysis of six organophosphorus pesticides (OPPs) in apples and pears. In this CPE procedure, the effects of the surfactant volume, mass of sodium chloride, equilibrium temperature, equilibrium time, and pH on the extraction procedure were investigated. Under the optimal CPE conditions, the analytes were enriched 20-fold and the LODs dropped to 0.44–5.20 μg/kg. Furthermore, the proposed extraction method was validated by the correlation coefficient (R2) of the calibration curve, repeatability (RSD, n = 6), and fortified recoveries, which were 0.9967–0.9993, 2.7–6.5, and 74.7–104.5%, respectively. Based on these results, it could be concluded that the proposed CPE method with Triton X-114 was suitable for the effective extraction and enrichment of OPP residues in the apple and pear samples.

Cloud Point Extraction-Fluorimetric Combined Methodology for the Determination of Magnolol

2013 ◽  
Vol 699 ◽  
pp. 34-39
Author(s):  
Li Liu ◽  
Xia Shi Zhu
Keyword(s):  
Standard Deviation ◽  
Detection Limit ◽  
Cloud Point ◽  
Relative Standard Deviation ◽  
Cloud Point Extraction ◽  
Calibration Graph ◽  
Optimum Conditions ◽  
Relative Standard ◽  
Triton X

A new Triton X-114 cloud point extraction combined with fluorometry method for analysis of magnolol in drug samples was developed. Under the optimum conditions, the calibration graph was linear in the range of 2.0-150.0ng/mL of magnolol in the initial solution with r = 0.9998. Detection limit (DL) was 0.03ng/mL (S/N=3) and the relative standard deviation (RSD) for 20.0ng/mL of magnolol was 2.79%(n=11). The method was successfully applied for the determination of magnolol in drug samples with satisfactory results.

Cloud Point Extraction and Flame Atomic Absorption Spectrometry Determination of Lead (II) in Environmental and Food Samples

2012 ◽  
Vol 95 (6) ◽  
pp. 1797-1802 ◽  
Author(s):  
Mustafa Soylak ◽  
Erkan Yilmaz ◽  
Mehrorang Ghaedi ◽  
Mortaza Montazerozohori ◽  
Marjan Sheibani
Keyword(s):  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Cloud Point ◽  
Flame Atomic Absorption Spectrometry ◽  
Cloud Point Extraction ◽  
Extraction Procedure ◽  
Absorption Spectrometry ◽  
Bath Temperature ◽  
Flame Atomic Absorption ◽  
Triton X

Abstract A cloud point extraction procedure for the preconcentration of Pb2+ in various samples following complexation with 2,2-(1E,1′E)-1,1′-(2,2′-azanediylbis(ethane-2,1-diyl)bis(azan-1-yl-1-ylidene)) bis(ethan-1-yl-1-ylidene)diphenol in Triton X-114 after centrifugation is reported. A 0.5 mL portion of methanol acidified with 1.0 M HNO3 was added to the surfactant-rich phase prior to analysis by flame atomic absorption spectrometry. The influence of analytical parameters—including pH, concentrations of ligand, Triton X-114, and HNO3, bath temperature, heating time, and centrifugation rate and time—were optimized, and the effect of the matrix ions on the recovery of Pb2+ was investigated. An LOD of 1.9 ng/mL along with a preconcentration factor of 50 with RSD of 1.0% for Pb2+ were achieved. The proposed procedure was applied to the analysis of various real samples.

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