scholarly journals 3D Self-Supported Nanoarchitectured Arrays Electrodes for Lithium-Ion Batteries

2012 ◽  
Vol 2012 ◽  
pp. 1-19 ◽  
Author(s):  
Xin Chen ◽  
Ying Du ◽  
Nai Qing Zhang ◽  
Ke Ning Sun
Keyword(s):  
Lithium Ion Batteries ◽  
Large Scale ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Current Collector ◽  
High Energy ◽  
Kinetic Properties ◽  
Future Design ◽  
Conductive Substrates ◽  
Consumer Devices

Three-dimensional self-supported nanoarchitectured arrays electrodes (3DSNAEs) consisting of a direct growth of nanoarchitectured arrays on the conductive current collector, including homogeneous and heterogeneous nanoarchitectured arrays structures, have been currently studied as the most promising electrodes owing to their synergies resulting from the multistructure hybrid and integrating heterocomponents to address the requirements (high energy and power density) of superperformance lithium ion batteries (LIBs) applied in portable electronic consumer devices, electric vehicles, large-scale electricity storage, and so on. In the paper, recent advances in the strategies for the fabrication, selection of the different current collector substrates, and structural configuration of 3DSNAEs with different cathode and anode materials are investigated in detail. The intrinsic relationship of the unique structural characters, the conductive substrates, and electrochemical kinetic properties of 3DSNAEs is minutely analyzed. Finally, the future design trends and directions of 3DSNAEs are highlighted, which may open a new avenue of developing ideal multifunctional 3DSNAEs for further advanced LIBs.

Manganese phosphoxide/Ni5P4 hybrids as an anode material for high energy density and rate potassium-ion storage

2021 ◽  
Author(s):  
Sen Yang ◽  
Ting Li ◽  
Yiwei Tan
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Large Scale ◽  
Low Cost ◽  
Lithium Ion ◽  
High Energy ◽  
Potassium Ion ◽  
High Energy Density ◽  
Active Materials ◽  
Ion Storage

Potassium-ion batteries (PIBs) that serve as low-cost and large-scale secondary batteries are regarded as promising alternatives and supplement to lithium-ion batteries. Hybrid active materials can be featured with the synergistic...

scholarly journals High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure

Energies ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1602 ◽  
Author(s):  
Jun-Ping Hu ◽  
Hang Sheng ◽  
Qi Deng ◽  
Qiang Ma ◽  
Jun Liu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Three Dimensional ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Energy ◽  
High Rate ◽  
High Energy Density ◽  
High Rate Capability ◽  
Closed Structure ◽  
Short Lifecycle

LiNixCoyMnzO2 (LNCM)-layered materials are considered the most promising cathode for high-energy lithium ion batteries, but suffer from poor rate capability and short lifecycle. In addition, the LiNi1/3Co1/3Mn1/3O2 (NCM 111) is considered one of the most widely used LNCM cathodes because of its high energy density and good safety. Herein, a kind of NCM 111 with semi-closed structure was designed by controlling the amount of urea, which possesses high rate capability and long lifespan, exhibiting 140.9 mAh·g−1 at 0.85 A·g−1 and 114.3 mAh·g−1 at 1.70 A·g−1, respectively. The semi-closed structure is conducive to the infiltration of electrolytes and fast lithium ion-transfer inside the electrode material, thus improving the rate performance of the battery. Our work may provide an effective strategy for designing layered-cathode materials with high rate capability.

Freestanding highly defect nitrogen-enriched carbon nanofibers for lithium ion battery thin-film anodes

2017 ◽  
Vol 5 (11) ◽  
pp. 5532-5540 ◽  
Author(s):  
Guoqiang Tan ◽  
Wurigumula Bao ◽  
Yifei Yuan ◽  
Zhun Liu ◽  
Reza Shahbazian-Yassar ◽  
...  
Keyword(s):  
Thin Film ◽  
Energy Storage ◽  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Large Scale ◽  
Lithium Ion ◽  
High Energy ◽  
Storage Technologies ◽  
Power Densities ◽  
Cycling Life

To transform lithium ion batteries into large-scale energy storage technologies, high energy/power densities and long cycling life of carbon-based anodes must be achieved.

Using Orthogonal Ploughing/Extrusion to Fabricate Three-Dimensional On-Chip-Structured Current Collector for Lithium-Ion Batteries

2019 ◽  
Vol 7 (15) ◽  
pp. 12910-12919 ◽  
Author(s):  
Wei Yuan ◽  
Baoyou Pan ◽  
Zhiqiang Qiu ◽  
Ziming Peng ◽  
Yintong Ye ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Current Collector ◽  
On Chip

Large-scale synthesis of Si@C three-dimensional porous structures as high-performance anode materials for lithium-ion batteries

2014 ◽  
Vol 2 (48) ◽  
pp. 20494-20499 ◽  
Author(s):  
Chengmao Xiao ◽  
Ning Du ◽  
Xianxing Shi ◽  
Hui Zhang ◽  
Deren Yang
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Large Scale ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Magnesium Silicide ◽  
Porous Structures ◽  
Acid Pickling ◽  
Large Scale Synthesis

We demonstrate the synthesis of Si@C three-dimensional porous structures derived from commercial magnesium silicide (Mg2Si) powder via simple annealing and acid pickling processes.

Amorphous and Crystalline Vanadium Oxides as High-Energy and High-Power Cathodes for Three-Dimensional Thin-Film Lithium Ion Batteries

2017 ◽  
Vol 9 (15) ◽  
pp. 13121-13131 ◽  
Author(s):  
Felix Mattelaer ◽  
Kobe Geryl ◽  
Geert Rampelberg ◽  
Jolien Dendooven ◽  
Christophe Detavernier
Keyword(s):  
Thin Film ◽  
Lithium Ion Batteries ◽  
High Power ◽  
Three Dimensional ◽  
Lithium Ion ◽  
High Energy ◽  
Vanadium Oxides

Oriented single-crystalline TiO2 nanowires on titanium foil for lithium ion batteries

2010 ◽  
Vol 25 (8) ◽  
pp. 1588-1594 ◽  
Author(s):  
Bin Liu ◽  
Da Deng ◽  
Jim Yang Lee ◽  
Eray S. Aydil
Keyword(s):  
Lithium Ion Batteries ◽  
Large Scale ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Titanium Foil ◽  
Nanowire Arrays ◽  
Tio2 Nanowires ◽  
Single Crystalline ◽  
Discharge Rates ◽  
Charge Discharge

A simple and environmentally benign three-step hydrothermal method was developed for growing oriented single-crystalline TiO2-B and/or anatase TiO2 nanowire arrays on titanium foil over large areas. These nanowire arrays are suitable for use as the anode in lithium ion batteries; they exhibit specific capacities ranging from 200–250 mAh/g at charge-discharge rates of 0.3 C where 1 C is based on the theoretical capacity of 168 mAh/g. Batteries retain this capacity over as many as 200 charge-discharge cycles. Even at high charge-discharge rates of 0.9 C and 1.8 C, the specific capacities were 150 mAh/g and 120 mAh/g, respectively. These promising properties are attributed to both the nanometer size of the nanowires and their oriented alignment. The comparable electrochemical performance to existing technology, improved safety, and the ability to roll titanium foils into compact three-dimensional structures without additional substrates, binders, or additives suggest that these TiO2 nanowires on titanium foil are promising anode materials for large-scale energy storage.

Tris (2, 2, 2-Trifluoroethyl) Phosphate (TFP) as Flame-Retarded Additives for Li-Ion Batteries

2013 ◽  
Vol 787 ◽  
pp. 40-45 ◽  
Author(s):  
Wei Wang ◽  
Shi Xiong Wang ◽  
Yun Bo He ◽  
Xiang Jun Yang ◽  
Hong Guo
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Batteries ◽  
Large Scale ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Li Ion Batteries ◽  
Long Cycle Life ◽  
Flame Retarded ◽  
Li Ion

With high energy density, long cycle life and high voltage Lithium-ion batteries are one of very promising pollution-free power supply. The electrolytes for these batteries consist of flammable organic solvents which are serious hazard under abusive conditions especially for large-scale lithium batteries. To reduce flammability of electrolyte of lithium-ion batteries and resolve safety problem, Tris (2, 2, 2-trifluoroethyl) phosphate (TFP) was synthesized and added into electrolytes as additive. It was found that the SET decreased significantly with the increase of the concentration of TFP. When the concentration is over 20% (vol.) electrolytes are nonflammable. At the same time, with the concentration increasing, the ion-conductivity decreased and the discharge capacity also came down slowly. The electrochemistry stability of LiCoO2 cathode was improved. According to our study, it is possible to find a cosolvent or additive that makes nonflammable lithium-ion electrolyte be put into practice.

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