scholarly journals Noncovalent Attachment of PbS Quantum Dots to Single- and Multiwalled Carbon Nanotubes

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Anirban Das ◽  
Eric Hall ◽  
Chien M. Wai

Attachment of PbS quantum dots (QD) to single-walled carbon nanotubes (SWNT) and multiwalled carbon nanotubes (MWCNT) is described; wherein commercially obtained PbS-QD of size 2.7 nm, stabilized by oleic acid, are added to a suspension of single- or multiwalled carbon nanotubes (CNT) prefunctionalized noncovalently with 1,2-benzenedimethanethiol (1,2-BDMT) in ethanol. The aromatic part of 1,2-BDMT attaches to the CNT byπ-πstacking interactions, noncovalently functionalizing the CNT. The thiol part of the 1,2-BDMT on the functionalized CNT replaces oleic acid on the surface of the QD facilitating the noncovalent attachment of the QD to the CNT. The composites were characterized by TEM and FTIR spectroscopy. Quenching of NIR fluorescence of the PbS-QD on attachment to the carbon nanotubes (CNT) was observed, indicating FRET from the QD to the CNT.

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Yuan-Xiang Yao ◽  
He-Bing Li ◽  
Jin-Yun Liu ◽  
Xin-Liang Tan ◽  
Jin-Gang Yu ◽  
...  

In an attempt to explore the possibility of using carbon nanotubes (CNTs) as efficient adsorbents for removal of pollutants from the contaminated water, the adsorption ofp-nitrophenol (PNP) on raw multiwalled carbon nanotubes (r.MWNTs) with different outer diameters, various functionalized multiwalled carbon nanotubes (f-MWNTs), raw single-walled carbon nanotubes (r.SWNTs) and oxidized single-walled carbon nanotubes (ox-SWNTs) has been investigated. The ox-SWNTs showed better adsorption ability for PNP with different concentrations, while lower uptake capacity was found for all of the r.MWNTs andf-MWNTs. The removal efficiency of PNP by ox-SWNTs was around 98%, indicating that ox-SWNTs possess a great potential application prospect for removing PNP from aqueous solutions.


2017 ◽  
Vol 2017 ◽  
pp. 1-12 ◽  
Author(s):  
Heeyoung Lee ◽  
Donghoon Kang ◽  
Young Min Song ◽  
Wonseok Chung

Carbon nanotubes (CNTs) are a primary nanomaterial that have outstanding physical and mechanical characteristics, and CNTs can be combined with cement-based materials to alter their heating characteristics. In this study, the types of CNTs used were multiwalled carbon nanotubes (MWCNTs) and single-walled carbon nanotubes (SWCNTs). Experiments were performed to determine the altered heating characteristics of the CNT cement mortars. The parameters of the experiment were CNT type, CNT content, curing age, and applied voltage. The results for the different CNT cement mortars indicate that mixing SWCNTs with water to produce CNT cement mortars was more effective for modifying the heating characteristics compared to mixing MWCNTs with water. In addition, field emission scanning electron microscope (FE-SEM) images supported the results found in the heating experiments.


2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Ana Cláudia C. de Paula ◽  
Gustavo A. M. Sáfar ◽  
Alfredo M. Góes ◽  
Marcelo P. Bemquerer ◽  
Marcos A. Ribeiro ◽  
...  

Human adipose-derived stem cells (hASCs) are an attractive cell source for therapeutic applicability in diverse fields for the repair and regeneration of damaged or malfunctioning tissues and organs. There is a growing number of cell therapies using stem cells due to their characteristics of modulation of immune system and reduction of acute rejection. So a challenge in stem cells therapy is the delivery of cells to the organ of interest, a specific site. The aim of this paper was to investigate the effects of a supramolecular assembly composed of single-walled carbon nanotubes (SWCNT), molecular magnets (lawsone-Co-phenanthroline), and a synthetic peptide (FWYANHYWFHNAFWYANHYWFHNA) in the hASCs cultures. The hASCs were isolated, characterized, expanded, and cultured with the SWCNT supramolecular assembly (SWCNT-MA). The assembly developed did not impair the cell characteristics, viability, or proliferation. During growth, the cells were strongly attached to the assembly and they could be dragged by an applied magnetic field of less than 0.3 T. These assemblies were narrower than their related allotropic forms, that is, multiwalled carbon nanotubes, and they could therefore be used to guide cells through thin blood capillaries within the human body. This strategy seems to be useful as noninvasive and nontoxic stem cells delivery/guidance and tracking during cell therapy.


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