scholarly journals Correction to: Visualizing and measuring gold leaf in fourteenth- and fifteenth-century Italian gold ground paintings using scanning macro X-ray fluorescence spectroscopy: a new tool for advancing art historical research

2019 ◽  
Vol 7 (1) ◽  
Author(s):  
Douglas MacLennan ◽  
Laura Llewellyn ◽  
John K. Delaney ◽  
Kathryn A. Dooley ◽  
Catherine Schmidt Patterson ◽  
...  
1992 ◽  
Vol 267 ◽  
Author(s):  
Barbara H. Berrie

ABSTRACTPigment identification and technical analysis of works of art provide the historian and conservator with information that allows a new view of an object. The methods the analyst chooses depends on the nature of the sample and the materials and method expected for the age of the object being examined. Several analytical methods are used frequently in the museum field with great success; these include x-ray fluorescence spectroscopy, x-ray powder diffraction methods and optical microscopy. Results from the analysis of pigments in paintings by Derain, Beckmann, El Greco, G. David, and Gentileschi are given. The results include discovery of an unpublished formulation of cobalt violet, example of the use of particle size to change the appearance of color, and the use of x-ray fluorescence to determine artists' palettes without removing samples from the works of art. The study of the El Greco and the Gentileschi show how technical investigations can complement art historical research.


Heritage ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 1165-1181
Author(s):  
Flavia Fiorillo ◽  
Lucia Burgio ◽  
Christine Slottved Kimbriel ◽  
Paola Ricciardi

This study presents the results of the technical investigation carried out on several English portrait miniatures painted in the 16th and 17th century by Nicholas Hilliard and Isaac Oliver, two of the most famous limners working at the Tudor and Stuart courts. The 23 objects chosen for the analysis, spanning almost the entire career of the two artists, belong to the collections of the Victoria and Albert Museum (London) and the Fitzwilliam Museum (Cambridge). A non-invasive scientific methodology, comprising of stereo and optical microscopies, Raman microscopy, and X-ray fluorescence spectroscopy, was required for the investigation of these small-scale and fragile objects. The palettes and working techniques of the two artists were characterised, focusing in particular on the examination of flesh tones, mouths, and eyes. These findings were also compared to the information written in the treatises on miniature painting circulating during the artists’ lifetime. By identifying the materials and techniques most widely employed by the two artists, this study provides information about similarities and differences in their working methods, which can help to understand their artistic practice as well as contribute to matters of attribution.


Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 33
Author(s):  
Valérie Laperche ◽  
Bruno Lemière

Portable X-ray fluorescence spectroscopy is now widely used in almost any field of geoscience. Handheld XRF analysers are easy to use, and results are available in almost real time anywhere. However, the results do not always match laboratory analyses, and this may deter users. Rather than analytical issues, the bias often results from sample preparation differences. Instrument setup and analysis conditions need to be fully understood to avoid reporting erroneous results. The technique’s limitations must be kept in mind. We describe a number of issues and potential pitfalls observed from our experience and described in the literature. This includes the analytical mode and parameters; protective films; sample geometry and density, especially for light elements; analytical interferences between elements; physical effects of the matrix and sample condition, and more. Nevertheless, portable X-ray fluorescence spectroscopy (pXRF) results gathered with sufficient care by experienced users are both precise and reliable, if not fully accurate, and they can constitute robust data sets. Rather than being a substitute for laboratory analyses, pXRF measurements are a valuable complement to those. pXRF improves the quality and relevance of laboratory data sets.


2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Qing Wu ◽  
Max Döbeli ◽  
Tiziana Lombardo ◽  
Katharina Schmidt-Ott ◽  
Benjamin Watts ◽  
...  

AbstractIn the previous paper (Part I), the colorimetry and interferometric microscopy measurements on modern gold leaf models have revealed that the visual appearance of a gilded surface, both burnished and unburnished, depends strongly on the substrate type, surface roughness and texture, but not on the colour of the substrate. In this second part, we investigate the materials compositions and technical specifications of medieval gold leaf through combining literature sources and materials analysis such as scanning electron microscopy coupled with energy dispersive X-ray analysis (SEM–EDX) on samples taken from gilded wooden sculptures. Our study shows that the late medieval gold leaf has a high purity of about 23.7 carat and has an average thickness of 160 nm (with a peak value of 138 nm), purer and thicker than the modern gold leaves studies in Part I. Supportive Rutherford backscattering spectrometry (RBS) measurements on gilded models confirms the accuracy and reliability of the SEM–EDX observations on the medieval gold leaf samples. We additionally present observations of a rarely recorded special variant of medieval gold leaf—“fine reinforced gold leaf”. Combined with the findings from Part I, we conclude that light penetrating the medieval gold leaf and reflected from the gilding substrate could not be a significant, or even perceptible contribution to the visual appearance of the gilding. We argue that the misconception surrounding the correlation between the substrate colour and the gilded surface appearance can be attributed to the historical development of gilding and polychromy technologies.


2019 ◽  
Vol 34 (5) ◽  
pp. 854-859 ◽  
Author(s):  
Sofia Pessanha ◽  
Sara Silva ◽  
Luís Martins ◽  
José Paulo Santos ◽  
João M. Silveira

In this work, we established a methodology for the analysis and characterization of hydroxyapatite-based materials using X-ray fluorescence.


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