Geochemistry tools, statistical geochemistry, equilibrium thermodynamics: phase diagrams, nonequilibrium thermodynamics, thermodynamic principles of evolution, laws of self-development

2018 ◽  
pp. 1-6
Author(s):  
Aleksey B. Ptitsyn

The microstructure and morphology of a mixture of polymeric materials depends on factors in both the thermal and rheological history of a sample as well as on its equilibrium thermodynamics. Concentrating largely on systems which are partly miscible we explore the effects of molecular, rheological and thermodynamic parameters on phase diagrams of binary polymer blends and show how these interact with sample preparation in determining the final sample morphology.


2020 ◽  
Vol 29 (15) ◽  
pp. 2030010
Author(s):  
J. Felix Salazar ◽  
Thomas Zannias

The recent monumental detection of gravitational waves by LIGO, the subsequent detection by the LIGO/VIRGO observatories of a binary neutron star merger seen in the gravitational wave signal [Formula: see text], the first photo of the event horizon of the supermassive black hole at the center of Andromeda galaxy released by the EHT telescope and the ongoing experiments on Relativistic Heavy Ion Collisions at the BNL and at the CERN, demonstrate that we are witnessing the second golden era of observational relativistic gravity. These new observational breakthroughs, although in the long run would influence our views regarding this Kosmos, in the short run, they suggest that relativistic dissipative fluids (or magnetofluids) and relativistic continuous media play an important role in astrophysical-and also subnuclear-scales. This realization brings into the frontiers of current research theories of irreversible thermodynamics of relativistic continuous media. Motivated by these considerations, we summarize the progress that has been made in the last few decades in the field of nonequilibrium thermodynamics of relativistic continuous media. For coherence and completeness purposes, we begin with a brief description of the balance laws for classical (Newtonian) continuous media and introduce the classical irreversible thermodynamics (CIT) and point out the role of the local-equilibrium postulate within this theory. Tangentially, we touch the program of rational thermodynamics (RT), the Clausius–Duhem inequality, the theory of constitutive relations and the emergence of the entropy principle in the description of continuous media. We discuss at some length, theories of non equilibrium thermodynamics that sprang out of a fundamental paper written by Müller in 1967, with emphasis on the principles of extended irreversible thermodynamics (EIT) and the rational extended irreversible thermodynamics (REIT). Subsequently, after a brief introduction to the equilibrium thermodynamics of relativistic fluids, we discuss the Israel–Stewart transient (or causal) thermodynamics and its main features. Moreover, we introduce the Liu–Müller–Ruggeri theory describing relativistic fluids. We analyze the structure and compare this theory to the class of dissipative relativistic fluid theories of divergent type developed in the late 1990 by Pennisi, Geroch and Lindblom. As far as theories of nonequilibrium thermodynamics of classical media are concerned, it is fair to state that substantial progress has been made and many predictions of the extended theories have been placed under experimental scrutiny. However, at the relativistic level, the situation is different. Although the efforts aiming to the development of a sensible theory (or theories) of nonequilibrium thermodynamics of relativistic fluids (or continuous media) spans less than a half-century, and even though enormous steps in the right direction have been taken, nevertheless as we shall see in this review, still a successful theory of relativistic dissipation is lacking.


Author(s):  
A. Zangvil ◽  
L.J. Gauckler ◽  
G. Schneider ◽  
M. Rühle

The use of high temperature special ceramics which are usually complex materials based on oxides, nitrides, carbides and borides of silicon and aluminum, is critically dependent on their thermomechanical and other physical properties. The investigations of the phase diagrams, crystal structures and microstructural features are essential for better understanding of the macro-properties. Phase diagrams and crystal structures have been studied mainly by X-ray diffraction (XRD). Transmission electron microscopy (TEM) has contributed to this field to a very limited extent; it has been used more extensively in the study of microstructure, phase transformations and lattice defects. Often only TEM can give solutions to numerous problems in the above fields, since the various phases exist in extremely fine grains and subgrain structures; single crystals of appreciable size are often not available. Examples with some of our experimental results from two multicomponent systems are presented here. The standard ion thinning technique was used for the preparation of thin foil samples, which were then investigated with JEOL 200A and Siemens ELMISKOP 102 (for the lattice resolution work) electron microscopes.


1984 ◽  
Vol 29 (3) ◽  
pp. 261-261
Author(s):  
Paul Pedersen
Keyword(s):  

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