Simulation Techniques for the Characterization of Structural and Transport Properties of Catalyst Pellets

2020 ◽  
pp. 89-136
Author(s):  
Sebastian C. Reyes ◽  
Enrique Iglesia
2010 ◽  
Vol 146-147 ◽  
pp. 491-494
Author(s):  
Ning Bo Liao ◽  
Miao Zhang ◽  
Rui Jiang

For nanoscale devices and structures, interface phenomena often dominate their overall thermal behavior. The feature scale of material interfaces usually originate from nanometer length and present a hierarchical nature. Considering to the limitations of the continuum mechanics on the characterization of nano-scale, the multiscale model featuring the interface could be very important in materials design. The purpose of this review is to discuss the applications of multiscale modeling and simulation techniques to study the mechanical properties at materials interface. It is concluded that a multi-scale scheme is needed for this study due to the hierarchical characteristics of interface.


Author(s):  
Riccardo Da Soghe ◽  
Cosimo Bianchini ◽  
Jacopo D’Errico

This paper deals with a numerical study aimed at the validation of a computational procedure for the aerothermal characterization of pre-swirl systems employed in axial gas turbines. The numerical campaign focused on an experimental facility which models the flow field inside a direct-flow pre-swirl system. Steady and unsteady simulation techniques were adopted in conjunction with both a standard two-equations RANS/URANS modelling and more advanced approaches such as the Scale-Adaptive-Simulation principle, the SBES and LES. The comparisons between CFD and experiments were done in terms of swirl number development, static and total pressure distributions, receiving holes discharge coefficient and heat transfer on the rotor disc surface. Several operating conditions were accounted for, spanning 0.78·106<Reφ<1.21·106 and 0.123<λt<0.376. Overall the steady-state CFD predictions are in good agreement with the experimental evidences even though it is not able to confidently mimic the experimental swirl and pressure behaviour in some regions. Although the use of unsteady sliding mesh and direct turbulence modelling, would in principle increase the insight in the physical phenomenon, from a design perspective the tradeoff between accuracy and computational costs is not always favourable.


2019 ◽  
Vol 23 ◽  
pp. 201-212
Author(s):  
Shivkumari Panda ◽  
Dibakar Behera ◽  
Tapan Kumar Bastia

This chapter presents the preparation and characterization of some unique properties of nanocomposites by dispersing graphite flakes in commercial unsaturated polyester (UPE) matrix. The composite was prepared by a novel method with the use of solvent swelling technique. Three different specimens of UPE/graphite nanocomposites were fabricated with addition of 1, 2 and 3 wt% of graphite flakes. Except mechanical, viscoelastic and thermo gravimetric properties, transport properties like electrical conductivity, thermal conductivity and water transport properties were studied for the first time. Graphite flakes propose enhanced properties to the composites suggesting homogeneous distribution of the nanofiller in the matrix and strong interaction with the matrix. 2wt% nanofiller loading showed superior essential characteristics and after that the properties reduced may be due to the nucleating tendency of the nanofiller particles. The XRD pattern showed the compatibility of the graphite flakes by introducing a peak around 26.550 in the nanocomposites. SEM Properties are also in agreement with the compatibility. Nanocomposite with 2wt% graphite also showed remarkable enhancement in transport, mechanical, viscoelastic and thermo gravimetric properties. So by introduction of a small quantity of graphite endow the new class of multiphase nanocomposites with inimitable structure and tremendous application.


2007 ◽  
Vol 1035 ◽  
Author(s):  
Celine Tavares Chevalier ◽  
J. Rothman ◽  
G. Feuillet

AbstractThe characterization of transport properties in Zn0 is known to be challenging, particularly due to surface (in the case of bulk) or interface (in the case of heteroepitaxial layers) conduction channels, which puts severe limitations on the interpretation of Hall Effect measurements. In this communication, we report on the study of transport properties of n-type ZnO bulk material using Hall mobility spectrum analysis estimated through the algorithm known as full Maximum Entropy Mobility Spectrum Analysis, f-MEMSA. The electrical properties of bulk Zn0 are measured using a Hall setup for applied magnetic fields µ0H in the range 0T-9T and for temperatures between 50K and 400K. The f-MEMSA analysis highlights the existence of two types of conduction channels in the considered ZnO substrate. We also show that surface conductive channel can be suppressed using appropriate annealing conditions.


2013 ◽  
Author(s):  
Anton Vladyka ◽  
Viktor Sydoruk ◽  
Svetlana Vitusevich ◽  
Mykhailo Petrychuk ◽  
Dong Xiang ◽  
...  

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