Systems with a Variable Number of Particles: The Chemical Potential

2018 ◽  
pp. 157-180
1999 ◽  
Vol 13 (12n13) ◽  
pp. 411-415 ◽  
Author(s):  
M. CORGINI ◽  
D. P. SANKOVICH

A quantum system of nonlinear oscillators is considered. Within the framework of Berezin's functional integral we prove the gaussian domination at finite temperature for some values of the chemical potential. Upper and lower bounds for the average number of particles with momentum p are derived.


1991 ◽  
Vol 05 (01n02) ◽  
pp. 113-118
Author(s):  
A. Moreo

We study the behavior of the mean number of particles <n> as a function of the chemical potential μ in the two dimensional Hubbard model with both attractive and repulsive interaction, using a quantum Monte Carlo method. Working at U/t=10, 4 and −4 on lattices with 4×4, 6×6 and 8×8 sites, we do not find evidence of phase separation.


Author(s):  
Nils Dalarsson ◽  
Mariana Dalarsson ◽  
Leonardo Golubović

1964 ◽  
Vol 12 (2) ◽  
pp. 139-141 ◽  
Author(s):  
A.A. Logunov ◽  
Nguyen Van Hieu ◽  
L.T. Todorov

2016 ◽  
Vol 94 (1) ◽  
pp. 47-57 ◽  
Author(s):  
H.A. Al-Khzon ◽  
H.B. Ghassib ◽  
Mohamed K. Al-Sugheir

A system of a finite number of harmonically trapped fermions in one dimension, in the presence of a static magnetic field, is studied within the framework of the static fluctuation approximation, for different repulsive and attractive potential strengths. Specifically, the thermodynamic properties of the system (the chemical potential, total energy, heat capacity, and entropy), as well as its magnetic properties (the magnetization and susceptibility), are calculated. It is observed that the system remains in an ordered phase for a small number of particles N, even at high temperatures T. Disorder sets in for large N, even at low T. The effect of the potential strength on the heat capacity is particularly tangible in the region bordering the quantum and classical regimes. The effect of the temperature (representing disorder) is directly opposite to that of the magnetic field (representing order), as expected on basic physical grounds. These features are consistent with experimental results.


Author(s):  
M.T. Thomaz

We approach the question of the movement of a particle with variable mass observed from an inertial frame. We consider two different situations: (i) a particle whose intrinsic mass value varies over time; (ii) the center of mass (CM) of a set of particles with constant mass but with a variable number of particles belonging to it. We show that Newton’s Second Law distinguishes the case in which the intrinsic mass of the particle varies over time from systems composed of particles, with constant mass, whose total mass varies over time. In the first case, we study the consequences of the equation of motion of a particle with variable mass is not covariant in inertial references under Galilean transformations. We also show that the equation that drives the dynamics of the CM of a system with variable number of particles preserves the equivalence of all inertial frames under the Galilean transformations. We verify the non-conservation of the linear momentum vector of the CM of a set of free particles during the time that one particle leaves or comes into the system.


2007 ◽  
Vol 21 (06) ◽  
pp. 829-855
Author(s):  
TOMAS B. MATERDEY

Kohn proved in 1961 that interactions between electrons did not change the de Haas–van Alphen (dHvA) oscillation frequency for single electrons in the nondegenerate ground-state [Phys. Rev.123(4), 1242 (1961)]. It was proved recently that the pure-state Wigner function for an electron in a magnetic field carries this quantum and physical oscillation, and a quantum dielectric function, so the conductance can be calculated from the Wigner function [Int. J. Mod. Phys. B17(25), 4555 (2003)], [Int. j. Mod. Phys. B17(26), 4683 (2003)]. We present the first complete proof that at a finite temperature, the mixed-state Wigner function also shows dHvA oscillations with the same frequency. The Wigner function is a fundamental quantity, the fact that it carries observable physical information shows a great potential in the design of new quantum materials at the nanoscale. The definition of the mixed-state Wigner function involves a grand canonical partition function (GCPF). Although dHvA is a well-known phenomenon, we present the first complete proof of it happening in degenerate mixed-states, based on a GCPF, which requires reconciliation between the dHvA experimental condition of a fixed number of particles and the GCPF's sum over number of particles. The GCPF is applied to one of the two spin species, while both the spin and spin-magnetic moment interaction are considered. We show that the contour integration in ω(ε) leads to a non-oscillatory term that is much larger than an oscillatory term, in the dHvA experimental conditions of high fields and low temperatures. This dominance of the non-oscillatory term explains the constancy of the chemical potential, allowing it to reduce to the Fermi energy in the limit of zero temperature. The obtained mixed-state Wigner function shows a fundamental period of oscillation with respect to B-1 that reduces to the Onsager's period for dHvA oscillations. This indicates that in mixed-states, dHvA oscillations depend on electrons of one spin species, this means the population of electrons of each spin species oscillates with the magnetic field. The temperature dependence in the Wigner function will allow a combination of phase-space and thermodynamics information for mesoscopic structures, and the study of phase-space density holes such as BGK modes in the quantum domain.


Author(s):  
Daniel V. Schroeder

Although the law of entropy increase governs the direction in which things change, we don’t observe entropy directly. Instead we observe three quantities—temperature, pressure, and chemical potential—that tell us how the entropy of a system changes as it interacts in three different ways with its surroundings. This chapter shows how these three quantities are mathematically related to a system’s entropy, energy, volume, and number of particles. These relations complete the foundation of macroscopic thermodynamics. Moreover, for the three model systems whose entropies are calculated explicitly in the previous chapter, these relations lead to detailed testable predictions of thermal behavior.


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