Surfactant Interactions with Skin

1999 ◽  
pp. 433-468 ◽  
Author(s):  
Thomas Polefka
Keyword(s):  
Surfactant Interactions

scholarly journals Membrane-surfactant interactions. The role of surfactant in mitochondrial complex III-phospholipid-Triton X-100 mixed micelles.

1986 ◽  
Vol 261 (14) ◽  
pp. 6578-6584
Author(s):  
J M Valpuesta ◽  
J L Arrondo ◽  
M C Barbero ◽  
M Pons ◽  
F M Goñi
Keyword(s):  
Mixed Micelles ◽  
Complex Iii ◽  
Mitochondrial Complex ◽  
Surfactant Interactions ◽  
Triton X

Thermodynamics and acoustic effects of quercetin on micellization and interaction behaviour of CTAB in different hydroethanol solvent systems

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Vikrant Abbot ◽  
Poonam Sharma
Keyword(s):  
Pharmaceutical Industry ◽  
Hydrophobic Interactions ◽  
Chemical Properties ◽  
Formulation Development ◽  
Surfactant Interactions ◽  
Physico Chemical ◽  
Ultrasonic Sound ◽  
Apparent Molar Compressibility ◽  
Solvent Systems ◽  
Thermoacoustic Properties

AbstractFlavonoids amongst the class of secondary metabolites possess numerous health benefits, are known for its use in pharmaceutical industry. Quercetin, a flavonoid has more prominent medical advantages however its utilization is constrained because of various instability and insolubility issues and therefore, taken into consideration for studying its physico-chemical properties. In view of that, the thermodynamic and thermoacoustic properties of quercetin were examined in presence of cationic surfactant cetyltrimethylammonium bromide (CTAB) at different hydroethanolic concentrations and temperatures. The conductivity studies were used to calculate change in enthalpy (∆Hom), change in entropy (∆Som) and change in Gibbs free Energy (∆Gom) of micellization. The interactions between quercetin and CTAB were found to be endothermic, entropically controlled and spontaneous. Further, ultrasonic sound velocity and density studies were carried out and utilized for the calculation of thermoacoustic parameters i.e. apparent molar volume and apparent molar compressibility. Thermoacoustic properties revealed that at higher surfactant concentration, hydrophobic interactions are dominant. The results suggested that the flavonoid-surfactant interactions in hydroethanolic solutions is more favourable as compared with aqueous solution. Overall, the data is favourable for the framework to be used for detailing advancement, drug development, drug industry, pharmaceutical industry, medical administration and formulation development studies.

Raman studies of cation-surfactant interactions in alkylpolyoxyethylene surfactant aqueous solutions

1991 ◽  
Vol 22 (3) ◽  
pp. 183-186 ◽  
Author(s):  
Diana C. W. Siew ◽  
Ralph P. Cooney ◽  
Michael J. Taylor
Keyword(s):  
Aqueous Solutions ◽  
Surfactant Interactions

Heat capacities and volumes in aqueous polymer and polymer–surfactant solutions

1987 ◽  
Vol 65 (5) ◽  
pp. 990-995 ◽  
Author(s):  
Gérald Perron ◽  
Josée Francoeur ◽  
Jacques E. Desnoyers ◽  
Jan C. T. Kwak
Keyword(s):  
Thermodynamic Properties ◽  
Chain Length ◽  
Polymer Concentration ◽  
Heat Capacities ◽  
Aqueous Mixtures ◽  
Alkyltrimethylammonium Bromides ◽  
Aqueous Polymer ◽  
Surfactant Interactions ◽  
Polymer Surfactant ◽  
Polymer Interaction

The apparent molar volumes and heat capacities of aqueous mixtures of neutral polymers and ionic surfactants were measured at 25 °C. The polymers chosen were poly(vinylpyrrolidone) (PVP) and poly(ethyleneoxide) (PEO) and the surfactants were the C8, C10, and C12 homologs of sodium alkylsulfates and the C10, C12, and C16 homologs of alkyltrimethylammonium bromides. The polymer–surfactant interactions depend on the nature of both components and on the chain length of the surfactant. The thermodynamic properties of the cationic surfactants are essentially the same in the absence and presence of polymer indicating little surfactant–polymer interaction. On the other hand, the thermodynamic properties of anionic surfactants are shifted, upon the addition of polymers, in the direction of enhanced hydrophobic association. The effect increases with the surfactant chain length and with the polymer concentration. The effect is larger with PVP than with PEO.

Experimental techniques to study protein–surfactant interactions: New insights into competitive adsorptions via drop subphase and Interface exchange

2022 ◽  
pp. 102601
Author(s):  
Aliyar Javadi ◽  
Saeid Dowlati ◽  
Sara Shourni ◽  
Reinhard Miller ◽  
Matthias Kraume ◽  
...  
Keyword(s):  
Experimental Techniques ◽  
Surfactant Interactions

Raman Spectroscopic Study of Ba2+-Surfactant Interactions in Aqueous Monodisperse Alkylpolyoxyethylene Surfactant Solutions

1993 ◽  
Vol 47 (11) ◽  
pp. 1784-1787
Author(s):  
Diana C. W. Siew ◽  
Ralph P. Cooney ◽  
Michael J. Taylor
Keyword(s):  
Conformational Changes ◽  
Influencing Factor ◽  
Difference Spectroscopy ◽  
Raman Spectroscopic ◽  
Chain Component ◽  
Raman Spectroscopic Study ◽  
Surfactant Solutions ◽  
Surfactant Complex ◽  
Surfactant Interactions ◽  
The Stability

Aqueous monodisperse alkylpolyoxyethylene surfactant-Ba2+ systems were investigated to clarify the coordination effects between the polyether chain and the cation which have been previously identified in polydisperse alkylphenoxy- and alkypolyoxyethylene surfactant systems. The coordination effects are simplified in the present study due to the presence of only a single polyether chain component. Formation of the surfactant complex resulted in conformational changes of the polyether chain which were monitored by Raman difference spectroscopy and curve fitting. The present studies confirm that surfactant-complex formation is dependent upon the polyether chain adopting the TGT-TĜT conformation and that the stability of the complex increases with the number of filled chain sites. The length of the polyether chain is also an influencing factor.

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