Electrochemical Performances of Zinc Oxide Electrodes Coated with Layered Double Hydroxides in Alkaline Solutions

2015 ◽  
Vol 44 (10) ◽  
pp. 1359-1361 ◽  
Author(s):  
You-Shin Lee ◽  
Kohei Miyazaki ◽  
Tomokazu Fukutsuka ◽  
Takeshi Abe
Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 747 ◽  
Author(s):  
Ai-Lan Yan ◽  
Xin-Chang Wang ◽  
Ji-Peng Cheng

The research on supercapacitors has been attractive due to their large power density, fast charge/discharge speed and long lifespan. The electrode materials for supercapacitors are thus intensively investigated to improve the electrochemical performances. Various transition metal layered double hydroxides (LDHs) with a hydrotalcite-like structure have been developed to be promising electrode materials. Earth-abundant metal hydroxides are very suitable electrode materials due to the low cost and high specific capacity. This is a review paper on NiMn LDHs for supercapacitor application. We focus particularly on the recent published papers using NiMn LDHs as electrode materials for supercapacitors. The preparation methods for NiMn LDHs are introduced first. Then, the structural design and chemical modification of NiMn LDH materials, as well as the composites and films derived from NiMn LDHs are discussed. These approaches are proven to be effective to enhance the performance of supercapacitor. Finally, the reports related to NiMn LDH-based asymmetric supercapacitors are summarized. A brief discussion of the future development of NiMn LDHs is also provided.


2019 ◽  
Vol 48 (3) ◽  
pp. 1084-1094 ◽  
Author(s):  
Xiaolong Deng ◽  
Jinzhao Huang ◽  
Fashen Chen ◽  
Hao Wan ◽  
Yifan Lin ◽  
...  

Metallic Ag0 intercalated CoAl LDHs synthesized via a facile redox process exhibited excellent ORR activity through a four-electron reduction process.


2019 ◽  
Vol 7 (29) ◽  
pp. 17637-17647 ◽  
Author(s):  
Gyeongseop Lee ◽  
Wonjoo Na ◽  
Jungwon Kim ◽  
Seungae Lee ◽  
Jyongsik Jang

A novel hollow-in-hollow structure is fabricated by distributing ZIF-67-derived hollow Ni–Co layered double hydroxides on hollow carbon sphere shells.


Author(s):  
Tuğba Türk ◽  
Taha Boyraz ◽  
İbrahim Alp

Abstract Since the presence of arsenic in the waters of the world causes serious health effects on people, it is very important to remove it. Layered double hydroxides have a high surface area and high anion exchange capacity, and because of this feature, it is a potential adsorbent to remove arsenic. For regeneration and reuse of adsorbents, researchers in some limited studies have used agents such as acids and alkalis. Media replacement accounts for approximately 80% of the total operational and maintenance costs. In this paper, an adsorption/desorption/regeneration study was carried out with MgFeHT to determine the desorption properties of the adsorbent and to examine its reusability. The best alkaline desorption solution was determined from two different alkaline solutions: NaOH and KH2PO4. As(V) adsorption capacity of the MgFeHT at different pH (3–12) using the arsenic aqueous solution (with 2,000 μg As(V)/L) was evaluated. For the adsorption process, the experimental data are fitted well with the pseudo-second-order kinetic model and the Langmuir model. Moreover, the concentration of 2,000 μg/L arsenic was reduced to below the legal limit determined by the WHO (<10 μg/L). The regeneration studies were conducted on the adsorptive media used in the arsenic removal system. The regeneration efficiency of As(V) was maintained 98.5% for four regeneration cycles using 0.5 M NaOH. MgFeHT was successfully regenerated with an aqueous solution of NaOH and was reused with a small loss of sorption efficiency.


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