Bulk Synthesis of Poly(tert-butyl methacrylate) Long Macromonomer with Narrow Distribution by Atom Transfer Radical Polymerization and Nucleophilic Substitution

2006 ◽  
Vol 35 (2) ◽  
pp. 222-223 ◽  
Author(s):  
Wei Yang ◽  
Tatsuo Kaneko ◽  
Xiao-Ya Liu ◽  
Ming-Qing Chen ◽  
Mitsuru Akashi
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Nucleophilic Substitution ◽  
Radical Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Tert Butyl

Atom Transfer Radical Polymerization of iso-Butyl Methacrylate in Microemulsion with Cationic and Non-Ionic Emulsifiers

2008 ◽  
Vol 29 (3) ◽  
pp. 264-264
Author(s):  
Yasuyuki Kagawa ◽  
Masahiro Kawasaki ◽  
Per B. Zetterlund ◽  
Hideto Minami ◽  
Masayoshi Okubo
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer

scholarly journals Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis

Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 458 ◽  
Author(s):  
Federico Di Sacco ◽  
Andrea Pucci ◽  
Patrizio Raffa
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Oil Recovery ◽  
Water Solution ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Resistance Variation ◽  
Volatile Organic ◽  
Functionalization Of Carbon Nanotubes ◽  
Volatile Organic Compound Sensors

Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials capable of interacting with different Volatile Organic Compounds (VOCs) by electrical resistance variation upon exposure. Moreover, facile hydrolysis of the tBMA group yields polyelectrolytic macrosurfactants with remarkable thickening properties for promising applications in water solution, such as Enhanced Oil Recovery (EOR).

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