scholarly journals Vibrational predissociation of rare-gas van der waals complexes of 9-methoxyanthracene.

1989 ◽  
pp. 1217-1224
Author(s):  
Satoshi HIRAYAMA ◽  
Fujio TANAKA ◽  
Kosuke SHOBATAKE
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Rare Gas ◽  
Vibrational Predissociation

Vibrational predissociation versus intramolecular vibrational energy redistribution (IVR) in rare gas∙∙∙dihalogen complexes: IVR identified in Ar∙∙∙I2(B,ν′) using velocity-map imaging

2021 ◽  
Author(s):  
Camille Makarem ◽  
Jie Wei ◽  
Richard A Loomis ◽  
Joshua P Darr
Keyword(s):  
Vibrational Energy ◽  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Rare Gas ◽  
Velocity Map Imaging ◽  
Energy Redistribution ◽  
Vibrational Predissociation ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Excited Molecules

The competition between multiple pathways sampled during the energetic relaxation of excited molecules can be difficult to experimentally decipher. The rare gas···dihalogen van der Waals complexes have remained key systems...

scholarly journals Consecutive Vibrational Redistribution and Predissociation Processes in s-Tetrazine–Argon Van Der Waals Complexes

1983 ◽  
Vol 2 (3-4) ◽  
pp. 125-135 ◽  
Author(s):  
J. J. F. Ramaekers ◽  
L. B. Krijnen ◽  
H. J. Lips ◽  
J. Langelaar ◽  
R. P. H. Rettschnick
Keyword(s):  
Decay Time ◽  
Van Der Waals ◽  
Stagnation Pressure ◽  
Van Der Waals Complexes ◽  
Supersonic Expansion ◽  
Vibrational Predissociation ◽  
Out Of Plane ◽  
Spectrally Resolved ◽  
Plane Mode

s-Tetrazine argon complexes T−Arn (n = 1, 2) are formed in a supersonic expansion of argon seeded with s-tetrazine. The expansion was conducted through a nozzle of 50 or 100 μm with an argon stagnation pressure between 1 and 1.5 bar. From spectrally resolved measurements it is clear that vibrational redistribution processes as well as vibrational predissociation processes take place after SVL excitation within the complex.From rise and decay time experiments it can be concluded, that after excitation of the 6a1 complex level, the above mentioned processes are consecutive and not parallel. It appears that the out of plane mode 16a couples with the Van der Waals stretching mode. The predissociation rate of the 16a2 complex is observed to be 2.3 × 109 s−1.

High-resolution spectroscopy of 4-fluorostyrene-rare gas van der Waals complexes: Results and comparison with theoretical calculations

1998 ◽  
Vol 108 (5) ◽  
pp. 1836-1850 ◽  
Author(s):  
N. M. Lakin ◽  
G. Pietraperzia ◽  
M. Becucci ◽  
E. Castellucci ◽  
M. Coreno ◽  
...  
Keyword(s):  
High Resolution ◽  
Theoretical Calculations ◽  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
High Resolution Spectroscopy ◽  
Rare Gas

Resonant two‐photon ionization of fluorene rare‐gas van der Waals complexes

1983 ◽  
Vol 79 (12) ◽  
pp. 5769-5779 ◽  
Author(s):  
Samuel Leutwyler ◽  
Uzi Even ◽  
Joshua Jortner
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Rare Gas ◽  
Two Photon ◽  
Photon Ionization
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