Comparison of dual frequency comb absorption spectra of air-broadened water vapor up to 1300K with HITRAN Online and HITEMP2010 models

Abstract. We present the first quantitative intercomparison between two open-path dual comb spectroscopy (DCS) instruments which were operated across adjacent 2-km open-air paths over a two-week period. We used DCS to measure the atmospheric absorption spectrum in the near infrared from 6021 to 6388 cm−1 (1565 to 1661 nm), corresponding to a 367 cm−1 bandwidth, at 0.0067 cm−1 sample spacing. The measured absorption spectra agree with each other to within 5 × 10−4 without any external calibration of either instrument. The absorption spectra are fit to retrieve concentrations for carbon dioxide (CO2), methane (CH4), water (H2O), and deuterated water (HDO). The retrieved dry mole fractions agree to 0.14 % (0.57 ppm) for CO2, 0.35 % (7 ppb) for CH4, and 0.40 % (36 ppm) for H2O over the two-week measurement campaign, which included 23 °C outdoor temperature variations and periods of strong atmospheric turbulence. This agreement is at least an order of magnitude better than conventional active-source open-path instrument intercomparisons and is particularly relevant to future regional flux measurements as it allows accurate comparisons of open-path DCS data across locations and time. We additionally compare the open-path DCS retrievals to a WMO-calibrated cavity ringdown point sensor located along the path with good agreement. Short-term and long-term differences between the two systems are attributed, respectively, to spatial sampling discrepancies and to inaccuracies in the current spectral database used to fit the DCS data. Finally, the two-week measurement campaign yields diurnal cycles of CO2 and CH4 that are consistent with the presence of local sources of CO2 and absence of local sources of CH4.

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Intercomparison of open-path trace gas measurements with two dual-frequency-comb spectrometers

Atmospheric Measurement Techniques ◽

10.5194/amt-10-3295-2017 ◽

2017 ◽

Vol 10 (9) ◽

pp. 3295-3311 ◽

Cited By ~ 26

Author(s):

Eleanor M. Waxman ◽

Kevin C. Cossel ◽

Gar-Wing Truong ◽

Fabrizio R. Giorgetta ◽

William C. Swann ◽

...

Keyword(s):

Absorption Spectra ◽

Near Infrared ◽

Frequency Comb ◽

Integration Time ◽

Deuterated Water ◽

Dual Frequency ◽

Measurement Campaign ◽

Diurnal Cycles ◽

Open Path ◽

Local Sources

Abstract. We present the first quantitative intercomparison between two open-path dual-comb spectroscopy (DCS) instruments which were operated across adjacent 2 km open-air paths over a 2-week period. We used DCS to measure the atmospheric absorption spectrum in the near infrared from 6023 to 6376 cm−1 (1568 to 1660 nm), corresponding to a 355 cm−1 bandwidth, at 0.0067 cm−1 sample spacing. The measured absorption spectra agree with each other to within 5 × 10−4 in absorbance without any external calibration of either instrument. The absorption spectra are fit to retrieve path-integrated concentrations for carbon dioxide (CO2), methane (CH4), water (H2O), and deuterated water (HDO). The retrieved dry mole fractions agree to 0.14 % (0.57 ppm) for CO2, 0.35 % (7 ppb) for CH4, and 0.40 % (36 ppm) for H2O at ∼  30 s integration time over the 2-week measurement campaign, which included 24 °C outdoor temperature variations and periods of strong atmospheric turbulence. This agreement is at least an order of magnitude better than conventional active-source open-path instrument intercomparisons and is particularly relevant to future regional flux measurements as it allows accurate comparisons of open-path DCS data across locations and time. We additionally compare the open-path DCS retrievals to a World Meteorological Organization (WMO)-calibrated cavity ring-down point sensor located along the path with good agreement. Short-term and long-term differences between the open-path DCS and point sensor are attributed, respectively, to spatial sampling discrepancies and to inaccuracies in the current spectral database used to fit the DCS data. Finally, the 2-week measurement campaign yields diurnal cycles of CO2 and CH4 that are consistent with the presence of local sources of CO2 and absence of local sources of CH4.

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A PORTABLE DUAL FREQUENCY COMB SPECTROMETER FOR ATMOSPHERIC APPLICATIONS

Proceedings of the 71st International Symposium on Molecular Spectroscopy ◽

10.15278/isms.2016.tb03 ◽

2016 ◽

Author(s):

Kevin Cossel ◽

Nathan Newbury ◽

Ian Coddington ◽

Greg Rieker ◽

Robert Wright ◽

...

Keyword(s):

Frequency Comb ◽

Dual Frequency

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Real-time and near real-time ZTD from a local network of low-cost dual-frequency GNSS receivers.

10.5194/egusphere-egu21-5465 ◽

2021 ◽

Author(s):

Tomasz Hadas ◽

Grzegorz Marut ◽

Jan Kapłon ◽

Witold Rohm

Keyword(s):

Water Vapor ◽

Real Time ◽

Low Cost ◽

Weather Prediction ◽

Local Network ◽

System Component ◽

Dual Frequency ◽

Lower Accuracy ◽

Gnss Receivers ◽

The Impact

The dynamics of water vapor distribution in the troposphere, measured with Global Navigation Satellite Systems (GNSS), is a subject of weather research and climate studies. With GNSS, remote sensing of the troposphere in Europe is performed continuously and operationally under the E-GVAP (http://egvap.dmi.dk/) program with more than 2000 permanent stations. These data are one of the assimilation system component of mesoscale weather prediction models (10 km scale) for many nations across Europe. However, advancing precise local forecasts for severe weather requires high resolution models and observing system.&#160; &#160;Further densification of the tracking network, e.g. in urban or mountain areas, will be costly when considering geodetic-grade equipment. However, the rapid development of GNSS-based applications results in a dynamic release of mass-market GNSS receivers. It has been demonstrated that post-processing of GPS-data from a dual-frequency low-cost receiver allows retrieving ZTD with high accuracy. Although low-cost receivers are a promising solution to the problem of densifying GNSS networks for water vapor monitoring, there are still some technological limitations and they require further development and calibration.We have developed a low-cost GNSS station, dedicated to real-time GNSS meteorology, which provides GPS, GLONASS and Galileo dual-frequency observations either in RINEX v3.04 format or via RTCM v3.3 stream, with either Ethernet or GSM data transmission. The first two units are deployed in a close vicinity of permanent station WROC, which belongs to the International GNSS Service (IGS) network. Therefore, we compare results from real-time and near real-time processing of GNSS observations from a low-cost unit with IGS Final products. We also investigate the impact of replacing a standard patch antenna with an inexpensive survey-grade antenna. Finally, we deploy a local network of low-cost receivers in and around the city of Wroclaw, Poland, in order to analyze the dynamics of troposphere delay at a very high spatial resolution.As a measure of accuracy, we use the standard deviation of ZTD differences between estimated ZTD and IGS Final product. For the near real-time mode, that accuracy is 5&#160;mm and 6 mm, for single- (L1) and dual-frequency (L1/L5,E5b) solution, respectively. Lower accuracy of the dual-frequency relative solution we justify by the missing antenna phase center correction model for L5 and E5b frequencies. With the real-time Precise Point Positioning technique, we estimate ZTD with the accuracy of 7.5 &#8211; 8.6 mm. After antenna replacement, the accuracy is improved almost by a factor of 2 (to 4.1 mm), which is close to the 3.1&#160;mm accuracy which we obtain in real-time using data from the WROC station.

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