scholarly journals Photoconversion Efficiency in Atomically thin TMDC-based heterostructures

2021 ◽  
Author(s):  
Kimiya Setayeshmehr ◽  
Mahdieh Hashemi ◽  
Narges Ansari

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2955
Author(s):  
Aleksandra Bartkowiak ◽  
Oleksandr Korolevych ◽  
Gian Luca Chiarello ◽  
Malgorzata Makowska-Janusik ◽  
Maciej Zalas

A series of pure and doped TiO2 nanomaterials with different Zr4+ ions content have been synthesized by the simple sol-gel method. Both types of materials (nanopowders and nanofilms scratched off of the working electrode’s surface) have been characterized in detail by XRD, TEM, and Raman techniques. Inserting dopant ions into the TiO2 structure has resulted in inhibition of crystal growth and prevention of phase transformation. The role of Zr4+ ions in this process was explained by performing computer simulations. The three structures such as pure anatase, Zr-doped TiO2, and tetragonal ZrO2 have been investigated using density functional theory extended by Hubbard correction. The computational calculations correlate well with experimental results. Formation of defects and broadening of energy bandgap in defected Zr-doped materials have been confirmed. It turned out that the oxygen vacancies with substituting Zr4+ ions in TiO2 structure have a positive influence on the performance of dye-sensitized solar cells. The overall photoconversion efficiency enhancement up to 8.63% by introducing 3.7% Zr4+ ions into the TiO2 has been confirmed by I-V curves, EIS, and IPCE measurements. Such efficiency of DSSC utilizing the working electrode made by Zr4+ ions substituted into TiO2 material lattice has been for the first time reported.





2016 ◽  
Vol 4 (2) ◽  
pp. 272-285 ◽  
Author(s):  
Pousali Chal ◽  
Arnab Shit ◽  
Arun K. Nandi

Nanotubular polyaniline/N,N-di((S)-1-carboxylethyl)-3,4 : 9,10 perylenetetracarboxyldiimide hybrids with characteristics of H-type aggregates and secondary de-doping yield photocurrent with photoconversion efficiency of 2.88%.



Nature Energy ◽  
2018 ◽  
Vol 3 (6) ◽  
pp. 529-529 ◽  
Author(s):  
Romain Cariou ◽  
Jan Benick ◽  
Frank Feldmann ◽  
Oliver Höhn ◽  
Hubert Hauser ◽  
...  


2021 ◽  
Author(s):  
Anatoliy Sachenko ◽  
Vitaliy Kostylyov ◽  
Viktor Vlasiuk ◽  
Igor Sokolovskyi ◽  
Mykhaylo Evstigneev


2020 ◽  
Vol 49 (18) ◽  
pp. 6592-6604 ◽  
Author(s):  
Xingchen Jiao ◽  
Kai Zheng ◽  
Liang Liang ◽  
Xiaodong Li ◽  
Yongfu Sun ◽  
...  

Ultrathin 2D materials serve as ideal models for tailoring three crucial parameters that determine CO2 photoconversion efficiency and product selectivity.



2020 ◽  
Vol 8 (8) ◽  
pp. 4396-4406 ◽  
Author(s):  
Fengzhu Li ◽  
Yan Wang ◽  
Kai Xia ◽  
Robert L. Z. Hoye ◽  
Vincenzo Pecunia

The microstructural enhancement of Rb3Sb2I9 compact films leads to a photoconversion efficiency boost up to 65.4%.



2018 ◽  
Vol 44 (10) ◽  
pp. 873-876 ◽  
Author(s):  
A. V. Sachenko ◽  
V. P. Kostylyov ◽  
A. V. Bobyl ◽  
V. N. Vlasyuk ◽  
I. O. Sokolovskyi ◽  
...  


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Wipula Priya Rasika Liyanage ◽  
Manashi Nath

AbstractHighly uniform and vertically aligned p-type CuInSe2 (CISe) nanotube arrays were fabricated through a unique protocol, incorporating confined electrodeposition on lithographically patterned nanoelectrodes. This protocol can be readily adapted to fabricate nanotube arrays of other photoabsorber and functional materials with precisely controllable design parameters. Ternary CISe nanotube arrays were electrodeposited congruently from a single electrolytic bath and the resulting nanotube arrays were studied through powder X-ray diffraction as well as elemental analysis which revealed compositional purity. Detailed photoelectrochemical (PEC) characterizations in a liquid junction cell were also carried out to investigate the photoconversion efficiency. It was observed that the tubular geometry had a strong influence on the photocurrent response and a 29.9% improvement of the photoconversion efficiency was observed with the nanotube array compared to a thin film geometry fabricated by the same process. More interestingly such enhancement in photoconversion efficiency was obtained when the electrode coverage with the nanotube arrays as photoactive material was only a fraction (~10%) of that for the thin film device. Apart from enhancement in photoconversion efficiency, this versatile technique provides ample opportunities to study novel photovoltaic materials and device design architectures where structural parameters play a key role such as resonant light trapping.



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