ICP Rotational Spectroscopic Temperature Determination Using N2 and N2+

1987 ◽  
Vol 41 (4) ◽  
pp. 658-660 ◽  
Author(s):  
C. J. Seliskar ◽  
D. C. Miller ◽  
P. A. Fleitz

The rotational structure in the origin bands of the Second Positive System of N2 and the First Negative System of N2+ have been used to demonstrate that these bands can be employed to determine a consistent spectroscopic temperature in an ICP. The experimental spectra have been modeled by the use of a computer program which calculates these bands for both species.

1968 ◽  
Vol 16 (9) ◽  
pp. 1115-1130 ◽  
Author(s):  
Donald E. Shemansky ◽  
A.Vallance Jones

Pramana ◽  
1994 ◽  
Vol 42 (3) ◽  
pp. 231-237 ◽  
Author(s):  
P R Sasikumar ◽  
S S Harilal ◽  
V P N Nampoori ◽  
C P G Vallabhan

The greenish-yellow afterglow of active nitrogen was first described, by Lewis. Two decades have passed since Fowler and Strutt showed that this afterglow was due to a selective excitation of a few green, yellow and red bands belonging to the first positive system of the nitrogen molecule (N 2 ). Recent work on active nitrogen indicates that the selective excitation is due to metastable nitrogen atoms giving up their energy to metastable nitrogen molecules in state A, the final state of the first positive bands, thus leading to the selective excitation of certain specific vibrational levels in state B, the initial state of the first positive bands. The molecule then returns to state A, at the same time emitting the bands which constitute the afterglow. From the rotational analysis of the second positive nitrogen bands by Lindau, and Hulthèn and Johansson, it is known that state B corresponds to a 3 II state, the second positive bands having their final state in common with the initial state of the first positive bands. No definite information has been found concerning the electronic configuration of the nitrogen molecule which gives rise to state A. This can be obtained by making a detailed analysis of the rotational structure of the first positive nitrogen bands.


1972 ◽  
Vol 27 (1) ◽  
pp. 65-67 ◽  
Author(s):  
K. Altmann ◽  
G. Strey

Abstract A computer program for simulation of the rotational structure of Raman bands is described. The program is used for an analysis of the Raman spectra of gaseous chlorine.


1978 ◽  
Vol 48 ◽  
pp. 287-293 ◽  
Author(s):  
Chr. de Vegt ◽  
E. Ebner ◽  
K. von der Heide

In contrast to the adjustment of single plates a block adjustment is a simultaneous determination of all unknowns associated with many overlapping plates (star positions and plate constants etc. ) by one large adjustment. This plate overlap technique was introduced by Eichhorn and reviewed by Googe et. al. The author now has developed a set of computer programmes which allows the adjustment of any set of contemporaneous overlapping plates. There is in principle no limit for the number of plates, the number of stars, the number of individual plate constants for each plate, and for the overlapping factor.


Author(s):  
Makoto Shiojiri ◽  
Toshiyuki Isshiki ◽  
Tetsuya Fudaba ◽  
Yoshihiro Hirota

In hexagonal Se crystal each atom is covalently bound to two others to form an endless spiral chain, and in Sb crystal each atom to three others to form an extended puckered sheet. Such chains and sheets may be regarded as one- and two- dimensional molecules, respectively. In this paper we investigate the structures in amorphous state of these elements and the crystallization.HRTEM and ED images of vacuum-deposited amorphous Se and Sb films were taken with a JEM-200CX electron microscope (Cs=1.2 mm). The structure models of amorphous films were constructed on a computer by Monte Carlo method. Generated atoms were subsequently deposited on a space of 2 nm×2 nm as they fulfiled the binding condition, to form a film 5 nm thick (Fig. 1a-1c). An improvement on a previous computer program has been made as to realize the actual film formation. Radial distribution fuction (RDF) curves, ED intensities and HRTEM images for the constructed structure models were calculated, and compared with the observed ones.


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