scholarly journals Thermoacoustic Properties of Binary Liquid Mixtures of Sulfolane with Aniline, N,N-Dimethylaniline and N,N-Diethylaniline at Different Temperatures and Atmospheric Pressure

2021 ◽  
Vol 33 (11) ◽  
pp. 2796-2802
Author(s):  
Mohammad Aftabuzzaman ◽  
Mohammad Monirul Islam ◽  
Nasiruddin ◽  
Farhana Rahman Rima ◽  
Mohammad Nazrul Islam ◽  
...  

Densities and sound velocities of the binary liquid mixtures of sulfolane + aniline, sulfolane + N,N-dimethylaniline, sulfolane + N,N-diethylaniline over the whole range of composition and their pure component were measured at temperatures (T = 303.15, 308.15, 313.15 K) and atmospheric pressure. A high precision vibrating-tube densitometer was used for the measurements. From the measured values, excess adiabatic compressibility (βs E), excess sound velocity (uE), excess internal pressure (Pi E) and deviation of surface tension (Δγ) were calculated for each of the systems. The excess properties and surface tension deviation were fitted to the Redlich-Kister equation. All these properties have been discussed in terms of molecular interactions.

2020 ◽  
Vol 27 ◽  
pp. 1324-1330
Author(s):  
S.K. Fakruddin Babavali ◽  
Timmeswara Sarma Nori ◽  
P. Naresh ◽  
Ch. Srinivasu ◽  
P. Srinivasa Sastry

2018 ◽  
Vol 4 (1) ◽  
pp. 0085-0091
Author(s):  
Heloisa Emi Hoga ◽  
Ricardo Belchior Torres

No presente estudo, dados experimentais de volume molar excesso ( ) de soluções líquidas binárias de metil terc butl éter (MTBE) + metanol, ou + etanol, ou + 1-propanol, ou + 2-propanol, ou + 1-butanol, ou + 1-pentanol, ou + 1-hexanol foram usados para testar a aplicabilidade da Teoria Prigogine-Flory-Patterson (PFP Theory), como função da composição a diferentes temperaturas e pressão atmosférica. De acordo com o modelo, a contribuição interacional é a mais importante para descrever o comportamento do  . Foi observado que a Teoria PFP reproduz os dados experimentais usando apenas um parâmetro ajustável. Para todos os sistemas estudados foi obtida uma boa concordância entre os resultados experimentais e a Teoria.


2013 ◽  
Vol 91 (3) ◽  
pp. 211-220 ◽  
Author(s):  
R.K. Shukla ◽  
Atul Kumar ◽  
Urvashi Srivastava ◽  
Naveen Awasthi ◽  
J.D. Pandey

Densities and surface tensions were measured for the binary liquid mixtures formed by formamide, N-methylacetamide, di-methylformamide, and di-methylacetamide with acetonitrile at 293.15, 298.15, 303.15, and 313.15 K and atmospheric pressure over the whole concentration range. The Prigogine–Flory–Patterson model, the Ramaswamy and Anbananthan model, the model devised by Glinski, the Sanchez equation, the Goldsack relation, and the Eberhart model were used to predict the associational behaviour of weakly interacting liquids. The measured properties were fitted to the Redlich–Kister polynomial relation to estimate the binary coefficients and standard errors. Furthermore, the McAllister multibody interaction model was used to correlate the binary properties. These nonassociated and associated models were compared and tested for different systems showing that the associated processes yield fair agreement between theory and experiment compared with nonassociated processes.


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