scholarly journals Adsorpsi Alkil Benzena Sulfonat Menggunakan Zeolit Termodifikasi Cetyltrimethylammonium

2017 ◽  
Vol 20 (1) ◽  
pp. 13-18 ◽  
Author(s):  
Anis Komariah ◽  
Sriatun Sriatun ◽  
Pardoyo Pardoyo

Dalam penelitian ini dilakukan modifikasi zeolit alam teraktivasi NH4Cl (H-Zeolit) dengan surfaktan CTAB (Cetyltrimethylammonium Bromide) berbagai konsentrasi yaitu sebesar 0,25 mM (ZMS-1), 1 mM (ZMS-2), dan 100 mM (ZMS-3) sebagai adsorben senyawa ABS (Alkil Benzena Sulfonat). Karakterisasi dilakukan terhadap H-Zeolit dan ZMS menggunakan spektrofotometer FTIR. Parameter utama dalam penelitian ini adalah variasi konsentrasi ABS (50, 75, dan 100 ppm) dan waktu kontak (15, 30, 45, 60, 75, dan 90 menit). Konsentrasi ABS yang teradsorpsi dianalisis dengan spektrofotometer UV-Vis menggunakan metode MBAS (Methylene Blue Active Substance). Hasil spektra FTIR zeolit alam termodifikasi surfaktan (ZMS) menunjukkan puncak pada bilangan gelombang 2931,80 cm-1; 2854,65 cm-1 dan 1404,18 cm-1  yang mengindikasikan keberadaan gugus CTAB pada zeolit. Konsentrasi maksimum dan waktu optimum ABS yang dapat dijerap oleh per 0,1 gram ZMS adalah 50 ppm dalam 25 mL pada waktu 60 menit dengan persen adsorpsi sebesar 84,04% untuk H-Zeolit ; 96,42% untuk ZMS-1; 96,48% untuk ZMS-2; dan 97,29% untuk ZMS-3. Performa ZMS cenderung meningkat dengan konsentrasi CTAB pada zeolit.

2006 ◽  
Vol 510-511 ◽  
pp. 798-801
Author(s):  
Hyung Suk So ◽  
Hyun Chul Shin ◽  
Beom Suk Kim ◽  
Yeong Seok Yoo

The purpose of this study is to develop a new system to control effective discharge of active substances such as agricultural chemicals. To synthesize a naturally dissolvable polymer; ε-caprolactone and diglycolide were copolymerized with ethylene glycol as an initiator to produce macrodiol. As macrodiol has hydroxyl groups in both ends, they are modified with methacryloyl chloride for photochemical networking. After standard macromonomer produced by this procedure was physically mixed with methylene blue, it was networked with ultra-violet rays to be filmed. This film is naturally dissolvable and hydrolytic. As a result of hydrolytic test with a crosslinked structure of 10 % methylene blue, it decreased by 9 % for seven weeks in 37 °C phosphate buffer solution (pH = 7). Thus, we verified that active substance can be discharged from a crosslinked structure for a long time at a constant rate under room temperature.


2020 ◽  
pp. 24-33
Author(s):  
Natalya Sedyakina ◽  
Nataliya Feldman ◽  
Sergey Lutsenko

The aim of the work is to develop composition of reverse microemulsion stabilized by the surfactant from a number of polyglycerol polyricinoleates for encapsulating water-soluble biologically active substance (BAS) and studying the kinetics of its release into the medium simulating the medium of the small intestine. Materials and methods. Possible stable (equilibrium) phases of the reverse microemulsion in the pseudoternary system water–PG-3-PR/Tween 80–paraffin oil were determined by titration of surfactant/co-surfactant mixtures–oil in water with hydrophilic-lipophilic balance (HLB) values of the surfactant mixture ranging from 4.0 to 7.0. Stability of a number of compositions during storage at 20 °C for 6 months was studied. Based on the obtained data, a composition was selected for encapsulating methylene blue (MS) dye as a model of a water-soluble biologically active substance. Microemulsion was obtained by mixing paraffin oil and surfactants with selected mass ratio followed by the addition of an aqueous phase. Reverse microemulsion morphology was evaluated with transmission electron microscopy (TEM). To evaluate the in vitro drug release rate, aliquots of an aqueous dye solution (control sample) and MB-containing microemulsions were placed in dialysis bags and immersed in 0.01 M phosphate-buffered saline (PBS) (pH 7.4) in a thermostatic shaking incubator at 180 rpm and 37 °C. Aliquots of the release medium were selected at predetermined time intervals and the concentration of MB dye was determined using a UV spectrophotometer at 660 nm. Results. Composition containing 13.5 wt% paraffin oil, 76.5 wt% mixture of PG3-PR/Tween 80 (HLB 5.5) and 10 wt% water was chosen to encapsulate the biologically active agents. Number average droplet diameter in the dispersed phase of the obtained microemulsion was 55 nm. Dye-loaded microemulsion sample showed a prolonged release of biologically active substances within 48 hours of the experiment (15.2%) and low initial release rate. Conclusion. Possible stable phases of reverse microemulsion in the pseudoternary system water–PG-3-PR/Twin 80–paraffin oil were determined in the course of the work and optimal microemulsion composition for encapsulating medicinal substances was found. It was shown that the resulting microemulsion system provides a sustained release of methylene blue as a model of a water-soluble biologically active substance in a medium simulating medium of the small intestine. The obtained data allow to consider this composition as a potential nanoscale system for the sustained delivery of water-soluble drugs.


Author(s):  
B. J. Panessa ◽  
J. F. Gennaro

Tissue from the hood and sarcophagus regions were fixed in 6% glutaraldehyde in 1 M.cacodylate buffer and washed in buffer. Tissue for SEM was partially dried, attached to aluminium targets with silver conducting paint, carbon-gold coated(100-500Å), and examined in a Kent Cambridge Stereoscan S4. Tissue for the light microscope was post fixed in 1% aqueous OsO4, dehydrated in acetone (4°C), embedded in Epon 812 and sectioned at ½u on a Sorvall MT 2 ultramicrotome. Cross and longitudinal sections were cut and stained with PAS, 0.5% toluidine blue and 1% azure II-methylene blue. Measurements were made from both SEM and Light micrographs.The tissue had two structurally distinct surfaces, an outer surface with small (225-500 µ) pubescent hairs (12/mm2), numerous stoma (77/mm2), and nectar glands(8/mm2); and an inner surface with large (784-1000 µ)stiff hairs(4/mm2), fewer stoma (46/mm2) and larger, more complex glands(16/mm2), presumably of a digestive nature.


2012 ◽  
Vol 60 (S 01) ◽  
Author(s):  
H Weiler ◽  
O Moeller ◽  
M Wohlhoefer ◽  
LO Conzelmann ◽  
J Albers ◽  
...  

2014 ◽  
Vol 62 (S 01) ◽  
Author(s):  
I. Kanzler ◽  
F. Guo ◽  
N. Bogert ◽  
A. Moritz ◽  
A. Beiras-Fernandez

2019 ◽  
Author(s):  
A Repici ◽  
C Hassan ◽  
R Bisschops ◽  
P Bhandari ◽  
E Dekker ◽  
...  

2020 ◽  
pp. 181-191
Author(s):  
M. Tkachenko ◽  
N. Borys ◽  
Ye. Kovalenko

The research aims to establish the eff ectiveness of granular chalk use produced by «Slavuta-Calcium» Ltd. under growing Poliska–90 winter wheat variety, changing the physicochemical properties of grey forest soil and the wheat productivity. It also aims to establish optimal dosis of «Slavuta-Calcium» granular chalk as the meliorant and mineral fertilizer for grey forest soil in the system of winter wheat fertilization. In the temporary fi eld studies, various doses of nutrients N60–90–120P30–45–60K60–90–120 combined with «Slavuta–Calcium» granular chalk in a dose of Ca230–460–690 kg/ha of the active substance were studied against the background of secondary plowing of rotation products – soybean biomass that averaged 2.34 t/ha. Granular chalk is a modern complex highly eff ective meliorant with the content of Ca – 37.7 and Mg – 0.2 %, the mass fraction of carbonates (CaCO3 + MgCO3) makes at least 95 %. It is characterized by a high level of solubility when interacting with moisture in soil. It has a form of white granules, the mass fraction of 4.0–6.0 mm in size granules makes not less than 90 % and the one of 1.0 mm in size makes less than 5 %. Reactivity – 97 %. The granular chalk is advisable to apply on acidic soils, as a highly concentrated calcium-magnesium fertilizer, with the former as the dominant fertilizer, to optimize the physicochemical properties of the soil, as well as the plant nutrition system, in particular, increasing the availability of an element for assimilation by plants and as long-term ameliorants. The eff ectiveness of the use of mineral fertilizers, in particular acidic nitrogen on highly and medium acidic soils, after chemical reclamation is increased by 30–50 %, and slightly acidic by 15–20 %. The increase in productivity of crops from the combined eff ects of nutrients and chalk granulated is usually higher than when separately applied. The eff ectiveness of the integrated action of these elements is manifested in the growth of plant productivity and the quality of the resulting products, as well as the optimization of physical chemical properties and soil buff ering in the long term. In order to optimize the physicochemical properties of the arable layer of gray forest soil and the productive nutrition of agricultural crops, winter wheat, in particular, biogenic elements should be used in doses N60-90-120P30-45- 60K60-90-120 with granulated chalk «Slavuta-Calcium» in doses of Ca230-460-690 kg/ha of active substance. Granulated chalk obtained as a result of industrial grinding of solid sedimentary carbonate rocks of natural origin, subsequently under the infl uence of the granulation process of the starting material contains Ca and Mg carbonates of at least 95 %, dense granules which facilitates convenient mechanized application, as well as chalk suitable for accurate metered application on the quest map. Key words: granular chalk, gray forest soil, chemical reclamation, crop productivity.


Sign in / Sign up

Export Citation Format

Share Document