3. Multiscale modeling predictions of age hardening curves in Al-Cu alloys

2016 ◽  
pp. 37-72
Author(s):  
J. E. O'Neal ◽  
K. K. Sankaran

Al-Li-Cu alloys combine high specific strength and high specific modulus and are potential candidates for aircraft structural applications. As part of an effort to optimize Al-Li-Cu alloys for specific applications, precipitation in these alloys was studied for a range of compositions, and the mechanical behavior was correlated with the microstructures.Alloys with nominal compositions of Al-4Cu-2Li-0.2Zr, Al-2.5Cu-2.5Li-0.2Zr, and Al-l.5Cu-2.5Li-0.5Mn were argon-atomized into powder at solidification rates ≈ 103°C/s. Powders were consolidated into bar stock by vacuum pressing and extruding at 400°C. Alloy specimens were solution annealed at 530°C and aged at temperatures up to 250°C, and the resultant precipitation was studied by transmission electron microscopy (TEM).The low-temperature (≲100°C) precipitation behavior of the Al-4Cu-2Li-0.2Zr alloy is a combination of the separate precipitation behaviors of Al-Cu and Al-Li alloys. The age-hardening behavior at these temperatures is characteristic of Guinier-Preston (GP) zone formation, with additional strengthening resulting from the coherent precipitation of δ’ (Al3Li, Ll2 structure), the presence of which is revealed by the selected-area diffraction pattern (SADP) shown in Figure la.


2006 ◽  
Vol 519-521 ◽  
pp. 555-560 ◽  
Author(s):  
Peter V. Liddicoat ◽  
Tomoyuki Honma ◽  
L.T. Stephenson ◽  
Simon P. Ringer

During age-hardening of certain Al-Zn-Mg-Cu alloys, a 90% hardness increase can occur with 75 seconds. The clustering and precipitation of solute element species during this early rapid hardening (RH) period has been investigated through atom probe tomography, transmission electron microscopy, and Vickers hardness measurements. This study has focussed on the effect of copper by analysing three alloys; Al-2.0Zn-1.8Mg-0.7Cu, Al-2.0Zn-1.7Mg-0.2Cu and Al-1.9Zn-1.7Mg (at.%). The early RH reaction in these alloys accounts for up to 70% of the total hardening (peak hardness minus as-quenched hardness) and takes place during the first 60 seconds of ageing. We report preferred solute-solute interactions in the as-quenched materials. This quenched-in nanostructure acts as a template for subsequent solute clustering, the nature of which we have correlated with ageing.


2019 ◽  
Vol 754 ◽  
pp. 265-268 ◽  
Author(s):  
Qianqian Zhu ◽  
Lingfei Cao ◽  
Xiaodong Wu ◽  
Yan Zou ◽  
Malcolm J. Couper
Keyword(s):  

1970 ◽  
Vol 20 (1) ◽  
pp. 36-42
Author(s):  
Ryo TAMAMURA ◽  
Kazuhiko ASANO ◽  
Kenichi HIRANO ◽  
Yoshitsugu MISHIMA
Keyword(s):  

2012 ◽  
pp. 939-944
Author(s):  
Hiroaki Motoshima ◽  
Shoichi Hirosawa ◽  
Seungwon Lee ◽  
Zenji Horita ◽  
Kenji Matsuda ◽  
...  

In 1932, Mehl, Barrett and Rhines published data on the nature of the precipitates in aluminium alloys containing copper and magnesium silicide respectively. They found in the first case that the precipitation of CuAl 2 from solid solution took the form of plates parallel to the (100) plane in the solid solution lattice. These investigators remarked: “The etching reaction of the particles found was so indefinite, because of the minuteness of the particles, that it' could not be used to identify the phase. Since, however, Schmid and Wassermann have found CuAl 2 in over-aged alloys with 4.5 % Cu, and since in the present work diffraction lines correspond in position to those from CuAl 2 , we may consider the precipitate observed to have been CuAl 2 .. . . These photographs show the precipitate to be chiefly in the form of plates....Furthermore, these plates are well defined in low copper concentrations but poorly defined in high....In figs. 2 and 3 (1 % Cu alloys aged 5 days at 350 and 360° C respectively) there is shown one family of plates lying nearly in the plane of polish, and two others, the edges of which form approximately a right angle, the plates in the plane of polish are especially evident in fig. 3.”


JOM ◽  
1957 ◽  
Vol 9 (10) ◽  
pp. 1182-1189 ◽  
Author(s):  
Ervin E. Underwood
Keyword(s):  

Author(s):  
Hiroaki Motoshima ◽  
Shoichi Hirosawa ◽  
Seungwon Lee ◽  
Zenji Horita ◽  
Kenji Matsuda ◽  
...  

2018 ◽  
Vol 142 ◽  
pp. 259-267 ◽  
Author(s):  
Yong Zhang ◽  
Daniele Pelliccia ◽  
Benjamin Milkereit ◽  
Nigel Kirby ◽  
Marco J. Starink ◽  
...  

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