Simulation of an Acid Gas Removal Unit Using a DGA and MDEA Blend Instead of a Single Amine

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Umer Zahid

AbstractMost of the industrial acid gas removal (AGR) units employ chemical absorption process for the removal of acid gases from the natural gas. In this study, two gas processing plants operational in Saudi Arabia have been selected where two different amines n1amely, diglycolamine (DGA) and monoethanol amine (MDEA) are used to achieve the sweet gas purity with less than 4 ppm of H2S. This study performed a feasibility simulation of AGR unit by utilizing the amine blend (DGA+MDEA) for both plants instead of a single amine. The study used a commercial process simulator to analyze the impact of process variables such as amine circulation rate, amine strength, lean amine temperature, regenerator inlet temperature, and absorber and regenerator pressure on the process performance. The results reveal that when the MDEA (0–15 wt. %) is added to DGA, marginal energy savings can be achieved. However, significant operational energy savings can be made when the DGA (0–15 wt. %) is blended with MDEA being the main amine.

Author(s):  
Prem Krish ◽  
Andrea Gains-Germain ◽  
Joseph Thorp ◽  
Jeremy Martin ◽  
Max Shirazi

Acid gas removal is a critical process step in natural gas processing and syngas production for ammonia and other uses. Application of a liquid phase turbocharger to the acid gas removal unit (AGRU) results in significant energy savings and improvement to reliability, availability and maintainability (RAM) of the plant. This paper describes conventional configurations with high pressure pumps and new configurations utilizing liquid phase turbochargers. Design of the equipment, process operations and controls and reliability analysis are included. The results of a RAM study comparing conventional configurations to those incorporating liquid phase turbochargers in multiple cases are also presented. From the RAM study, it can be concluded that flow sheet configurations that include a liquid phase turbocharger consistently provide lower plant downtime and maintenance costs as compared with conventional flow sheet configurations. This is in addition to the energy savings that result from energy recovery with the application of the liquid phase turbocharger to the AGRU. For the reference plant used in the study, the maintenance cost savings are as great as $2.5M over the 20 year lifetime of the plant and average annual downtime reduction is as much as 19.8 hours.


2015 ◽  
Vol 4 (4) ◽  
pp. 1-7
Author(s):  
Yansen Hartanto ◽  
Tri Partono Adhi ◽  
Antonius Indarto

Acid gas removal to remove carbon dioxide (CO2) in natural gas is one of the most important processes. The common removal process of CO2 from natural gas by using alkanolamine solution This process was adopted as basic module in commercial process simulation tools with various equilibrium models. Thus, this study was focused to evaluate the validity in certain operating condition and equilibrium model that produced by commercial simulation tools. The model in this study included coefficient activity model based on Kent-Eisenberg, Li-Mather, and Electrolyte Non Random Two Liquid (NRTL). The evaluation was conducted by doing analysis from simulation result and experiment data that have been used as reference. Furthermore, validation test in absorption process simulation was done to compare column temperature profile. The overall conclusions show that electrolyte NRTL gives the most accurate result.


2016 ◽  
Vol 2 (2) ◽  
pp. 1
Author(s):  
Rosanne Walker ◽  
Sara Pavía

ResumenMejorar el rendimiento térmico de los edificios mediante la adaptación del aislamiento puede reducir la pérdida innecesaria de calor y energía minimizando el impacto ambiental. El aislamiento térmico interior es a menudo el elegido en los edificios históricos para preservar sus características. Sin embargo, el aislamiento interior puede aumentar la acumulación de humedad en paredes que socavan su durabilidad. Hay una falta de conocimiento sobre la eficacia de sólidos muros históricos y el impacto del aislamiento interno en su comportamiento higrotérmico. Este artículo investiga las propiedades térmicas e hídricas de siete opciones de aislamiento internos, incluyendo la pintura térmica, aerogel (AG), corcho-cal (CL), cal-cáñamo (HL), silicato de calcio bordo (CSB), tablero de fibra de madera (TFB) y placa de polisocianurato (PIR). Sus propiedades se comparan con un enlucido de cal tradicional. El PIR y el aerogel AG muestran extraordinarias propiedades térmicas que contribuyen a la comodidad y ahorro de energía, y la CL y HL son permeables al vapor y a la capilaridad. Estos tienen aproximadamente el doble de la masa térmica de los otros aislantes. Además, la CL tiene una buena inercia térmica (segunda difusividad más baja) y, a pesar de su contenido orgánico, una adsorción de baja a alta RH.AbstractImproving the thermal performance of buildings by retrofitting insulation can reduce unnecessary heat loss and building operational energy minimising environmental impact. Internal thermal insulation is often favoured for historic buildings to preserve their features. However, internal insulation may increase moisture accumulation in walls undermining their durability. There is a lack of knowledge on the performance of historic solid walls and the impact of internal insulation in their hygrothermal behaviour. This paper investigates the thermal and hygric properties of seven internal insulation options including thermal paint, aerogel (AG), cork lime (CL), hemp lime (HL), calcium silicate board (CSB), timber fibre board (TFB) and polyisocyanurate (PIR) board. Their properties are compared with a traditional lime plaster. The PIR and aerogel AG show outstanding thermal properties that contribute towards indoor thermal comfort and energy savings and the CL and HL are vapour permeable and capillary active. They have approximately double the thermal mass of the other insulations. In addition, the CL has a good thermal inertia (2nd lowest diffusivity) and, in spite of its organic content, a low adsorption at high RH.


2017 ◽  
Vol 2 (2) ◽  
pp. 111-133
Author(s):  
Qinghan Bian ◽  
Dennis Paradine ◽  
Katherine Wreford ◽  
Jennifer Eby ◽  
Yori Jamin ◽  
...  

2015 ◽  
Vol 83 ◽  
pp. 97-109 ◽  
Author(s):  
Habin Cho ◽  
Michael Binns ◽  
Kwang-Joon Min ◽  
Jin-Kuk Kim

Author(s):  
O. Badr ◽  
R. Al-Kuwari ◽  
A. Abdel-Sattar

Abstract Qatar, one of the Arabian Gulf States, possesses one of the world’s largest non-associated gas fields. Most of the country’s development plans are based on the preparation of natural gas for export and local use. Under normal operation of gas processing plants, the residual, H2S-rich Acid Gas is treated in a sulfur recovery unit to produce pure sulfur. However, under abnormal situations, the acid gas is burned in incinerators or flares releasing SO2–rich combustion products. Under severe weather conditions, such a flare may get extinguished and the acid gas is released unignited into the atmosphere. This paper studies the environmental hazards due to the release of such dangerous gases. Dispersion models developed by the US EPA have been used to determine the size and map location of the dangerous zones. For ignited acid gas, the results indicated the possible formation of SO2-toxic clouds extending to 110 km from the flare location in the downwind direction and 210 m above ground level. For the less common case of releasing unignited acid gas, the H2S-toxic cloud may extend to 20 km and 110 m in the downwind and vertical directions, respectively. A parametric study has been conducted to consider the effects of some meteorological conditions (wind speed and atmospheric stability) as well as the number of operating trains in a typical gas processing plant.


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