scholarly journals Study on the unsaturated hydrogen bond behavior of bio-based polyamide 56

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 23-31
Author(s):  
Shouyun Zhang ◽  
Jinghong Ma
Keyword(s):  
Hydrogen Bond ◽  
Infrared Spectroscopy ◽  
Hydrogen Bonds ◽  
Metal Oxides ◽  
Significant Influence ◽  
Polymer Chains ◽  
Experimental Results ◽  
Bond Behavior ◽  
Unit Structure

AbstractIn this paper, the unsaturated hydrogen bonds (H-bonds) of the bio-based polyamide 56 (PA56) with an odd-even unit structure were analyzed by infrared spectroscopy. It was proved that the bio-based PA56 had less saturated H-bonds, which became attenuated and blue-shifted at the temperature exceeding 260°C. Besides, as H-bond was decayed and broken, new unsaturated H-bonds readily formed. Moreover, the experimental results obtained strongly indicate that the unsaturated H-bonds of bio-based polyamide 56 could react with polar metal oxides. Besides, the intercalation of montmorillonite was found to have a significant influence on the hydrogen bond between polymer chains.

scholarly journals The role of hydrogen bonds in diluted ethanol solutions of cyclohexane and dimethylformamide

2021 ◽  
pp. 44-47
Keyword(s):  
Hydrogen Bond ◽  
Refractive Index ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Hydrogen Bonds ◽  
Ethanol Solution ◽  
Pure Ethanol ◽  
First Time ◽  
Formed Hydrogen

The aim of this work is to determine molecular association in solutions of cyclohexane-ethanol and dimethylformamide-ethanol. The refractometric method and Fourier transform infrared spectroscopy used to determine the optical features of the concentration characteristics of diluted ethanol solutions of cyclohexane and dimethylformamide. It was found for the first time that at some concentrations the hydrogen bond is stronger than for a pure ethanol solution. The first maximum of the excess refractive index of solutions is formed at a concentration of 0.02 mole fraction of cyclohexane and dimethylformamide, which is in good correlation with IR spectroscopy, indicating the largest number of formed hydrogen bonds.

scholarly journals Hydrogen Bond Arrangement Is Shown to Differ in Coexisting Phases of Aqueous Two-Phase Systems

Biomolecules ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1787
Author(s):  
Pedro P. Madeira ◽  
Amber R. Titus ◽  
Luisa A. Ferreira ◽  
Alexander I. Belgovskiy ◽  
Elizabeth K. Mann ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Hydrogen Bonds ◽  
Total Reflection ◽  
Attenuated Total Reflection ◽  
Two Phase ◽  
Coexisting Phases ◽  
Aqueous Two Phase Systems ◽  
Phase Systems

Analysis by attenuated total reflection–Fourier transform infrared spectroscopy shows that each coexisting phase in aqueous two-phase systems has a different arrangement of hydrogen bonds. Specific arrangements vary for systems formed by different solutes. The hydrogen bond arrangement is shown to correlate with differences in hydrophobic and electrostatic properties of the different phases of five specific systems, four formed by two polymers and one by a single polymer and salt. The results presented here suggest that the arrangement of hydrogen bonds may be an important factor in phase separation.

scholarly journals Femtosecond Mid-Infrared Spectroscopy of Hydrogen-Bonded Liquids

1999 ◽  
Vol 19 (1-4) ◽  
pp. 83-90 ◽  
Author(s):  
S. Woutersen ◽  
U. Emmerichs ◽  
H. J. Bakker
Keyword(s):  
Hydrogen Bond ◽  
Infrared Spectroscopy ◽  
Hydrogen Bonds ◽  
Pump Probe ◽  
Mid Infrared ◽  
Hydrogen Bond Strength ◽  
Stretching Vibration ◽  
Probe Spectroscopy ◽  
Femtosecond Time Scale ◽  
Hydrogen Bonded

We perform femtosecond mid-infrared pump-probe spectroscopy on hydrogen-bonded ethanol dissolved in CCl4. We find that upon excitation of the OH-stretching vibration the hydrogen bonds are predissociated on a femtosecond time scale, and that the predissociation time constant depends strongly on the hydrogen-bond strength.

Hydrogen bonds in N-(3-chloro-2-benzo[b]thienocarbonyl)- and N-(2-benzo[b]thienocarbonyl)-N'-monosubstituted thioureas

1987 ◽  
Vol 52 (11) ◽  
pp. 2673-2679 ◽  
Author(s):  
Oľga Hritzová ◽  
Peter Kutschy ◽  
Ján Imrich ◽  
Thomas Schöffmann
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Strong Hydrogen Bond ◽  
Cyclic Form ◽  
Thiourea Derivatives

N-(3-Chloro-2-benzo[b]thienocarbonyl)-N'-monosubstituted thiourea derivatives undergo photocyclizations with lower yields than those obtained from analogous N',N'-disubstituted derivatives. This decreased reactivity is caused by the existence of a six-membered cyclic form with the very strong hydrogen bond NH···O=C. The possibility of formation of various conformers has been found with N-(2-benzo[b]thienocarbonyl)-N'-monosubstituted thiourea derivatives as a consequence of the rotation around the C(2)-C(O) connecting line.

Crystal structure of tofacitinib dihydrogen citrate (Xeljanz®), (C16H21N6O)(H2C6H5O7)

2021 ◽  
pp. 1-8
Author(s):  
James A. Kaduk ◽  
Amy M. Gindhart ◽  
Thomas N. Blanton
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Carboxylic Acid ◽  
Hydrogen Bonds ◽  
Powder Diffraction ◽  
Density Functional ◽  
Acid Group ◽  
Dimensional Network ◽  
Van Der Waals Contacts ◽  
Citrate Anion

The crystal structure of tofacitinib dihydrogen citrate (tofacitinib citrate) has been solved and refined using synchrotron X-ray powder diffraction data, and optimized using density functional techniques. Tofacitinib dihydrogen citrate crystallizes in space group P212121 (#19) with a = 5.91113(1), b = 12.93131(3), c = 30.43499(7) Å, V = 2326.411(6) Å3, and Z = 4. The crystal structure consists of corrugated layers perpendicular to the c-axis. Within the layers, cation⋯anion and anion⋯anion hydrogen bonds link the fragments into a two-dimensional network parallel to the ab-plane. Between the layers, there are only van der Waals contacts. A terminal carboxylic acid group in the citrate anion forms a strong charge-assisted hydrogen bond to the ionized central carboxylate group. The other carboxylic acid acts as a donor to the carbonyl group of the cation. The citrate hydroxy group forms an intramolecular charge-assisted hydrogen bond to the ionized central carboxylate. Two protonated nitrogen atoms in the cation act as donors to the ionized central carboxylate of the anion. These hydrogen bonds form a ring with the graph set symbol R2,2(8). The powder pattern has been submitted to ICDD® for inclusion in the Powder Diffraction File™ (PDF®).

Experimental Study on the Optimal Thickness of Infiltration Media of the CRI System

2011 ◽  
Vol 415-417 ◽  
pp. 1703-1707
Author(s):  
Jun Min Chen ◽  
Xiao Lin Yao
Keyword(s):  
Experimental Study ◽  
Removal Efficiency ◽  
Significant Influence ◽  
Soil Column ◽  
Experimental Results ◽  
Artificial Soil ◽  
Optimal Thickness ◽  
Effluent Quality ◽  
Anaerobic Zone

Abstract. In order to investigate the optimal thickness of infiltration media in the Constructed Rapid Infiltration System, the artificial soil column is used to simulate the Constructed Rapid Infiltration System, and the CODCr, NH3-N and TN concentrations of the effluent from all the sampling sites are monitored. The experimental results and analysis show that the thickness of infiltration media exerts a significant influence on the CODCr, NH3-N and TN concentration and removal efficiency of the effluent; the CODCr, NH3-N and TN are mainly removed in the 0-1800mm zone of the artificial soil column; the total CODCr removal efficiency increases, as the thickness of infiltration media increases, but the CODCr removal efficiency in the 1800-2200mm zone is very low; the NH3-N and TN removal efficiency reaches the maximum where the thickness of infiltration media is 1800mm; the NH3-N and TN concentration of the effluent from 1800-2200mm zone dose not decrease, but increase 5-8%, due to the assimilation denitrification and amemoniation reaction on the end of the anaerobic zone; in consideration of the effluent quality, efficient biodegradation zone, construction investment, etc. the optimal thickness of infiltration media in CRI system should be 1800mm.

Effect of Zeolite Addition on the Properties of Bioplastic Composites of Carboxymethyl Cellulose-Urea

2019 ◽  
Vol 948 ◽  
pp. 175-180 ◽  
Author(s):  
Indriana Kartini ◽  
Kukuh Handaru Iskandar ◽  
Chotimah ◽  
Eko Sri Kunarti ◽  
Rochmadi
Keyword(s):  
Tensile Strength ◽  
Hydrogen Bonds ◽  
Strong Interaction ◽  
Carboxymethyl Cellulose ◽  
Slow Release ◽  
Polymer Chains ◽  
Solvent Casting ◽  
Ammonium Ions ◽  
Petri Dishes ◽  
Urea Inclusion

Bioplastic composites based on carboxymethyl cellulose (CMC) and urea have been successfully synthesised at various amount of zeolites. Urea inclusion into the bioplastics was supposed to result in nitrogen slow-release composites. The bioplastic composites were prepared by solvent casting the precursor gel containing 0.5 % (w/w) urea in CMC in the petri dishes. The zeolites content was varied at 0.1, 0.5, 1.0, 2.0, and 3.0 % (w/w to CMC). It showed that the addition of zeolites to the bioplastic composites up to 0.5% increased their tensile strength. More addition of zeolites decreased the strain of the bioplastic composite. It could be due to the formation of hydrogen bonds between CMC and zeolites. The amount of urea absorbed in the bioplastics increased as the amount of zeolites increases. It is possibly to be due to the strong interaction between urea and zeolites. The ammonium ions may interact with interchangeable cations in the zeolite. This interaction will also extend the time for the bioplastics to biodegrade. The presence of zeolites in the CMC polymer chains is useful to give nitrogen slow-release composites.

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