Preparation and characterization of styrene-methyl methacrylate In deproteinized natural rubber latex (SMMADPNR)

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
Siti Hajjar Che Man ◽  
Azanam S. Hashim ◽  
Hazizan Md. Akil

AbstractThe graft polymerization of Styrene and Methyl methacrylate (MMA) onto deproteinized natural rubber latex (DPNR) was carried out using ammonium peroxy disulfate (N2H8O8S2) as an initiator. The suitable reaction conditions based on the higher monomer conversion was determined. The degree of grafting and the copolymers composition of the resultant SMMA-DPNR were obtained using 1H NMR Spectroscopy. As expected, composition of styrene in DPNR was higher than that of MMA due to the higher reactivity ratio of styrene monomer as compared to MMA monomer and the structure of the NR backbone. The mechanism of seeded emulsion polymerization leading to graft copolymer of styrene and MMA onto NR was studied and elucidated.

2018 ◽  
Vol 42 (17) ◽  
pp. 14179-14187
Author(s):  
Janisha Jayadevan ◽  
G. Unnikrishnan

Novel blend membranes from physico-chemically modified deproteinized natural rubber latex for drug release applications.


2012 ◽  
Vol 51 (6) ◽  
pp. 605-611 ◽  
Author(s):  
Indrajith Rathnayake ◽  
Hanafi Ismail ◽  
Baharin Azahari ◽  
Nalin Dammika Darsanasiri ◽  
Sanath Rajapakse

Polímeros ◽  
2014 ◽  
Vol 24 (3) ◽  
pp. 283-290 ◽  
Author(s):  
Feiyun Wei ◽  
Heping Yu ◽  
Zongqiang Zeng ◽  
Hongchao Liu ◽  
Qifang Wang ◽  
...  

2014 ◽  
Vol 11 (2) ◽  
pp. 109-115 ◽  
Author(s):  
Sweeta Akbari ◽  
Arun Gupta ◽  
Tanveer Ahmed Khan ◽  
Saidatul Shima Jamari ◽  
Norlirabiatuladawiyah Binti Che Ani ◽  
...  

2012 ◽  
Vol 31 (5) ◽  
pp. 586-592 ◽  
Author(s):  
W.G.I.U. Rathnayake ◽  
H. Ismail ◽  
A. Baharin ◽  
A.G.N.D. Darsanasiri ◽  
Sanath Rajapakse

2008 ◽  
Vol 286 (8-9) ◽  
pp. 1049-1059 ◽  
Author(s):  
A. Bogner ◽  
A. Guimarães ◽  
R. C. O. Guimarães ◽  
A. M. Santos ◽  
G. Thollet ◽  
...  

2013 ◽  
Vol 712-715 ◽  
pp. 111-114 ◽  
Author(s):  
Tian Ming Gao ◽  
Mao Fang Huang ◽  
Rui Hong Xie ◽  
Hong Lian Chen

Surface modified nanocrystalline cellulose (NCC) was prepared by silicon-69, and then blended into natural rubber latex to prepare nanocomposites. The nanocomposites properties of tensile properties, tear strength, morphology and thermal dynamic mechanical properties were measured by mechanical property testing, scanning electron microscopy (SEM), and dynamic mechanical analysis (DMA), respectively. The results showed that modified NCC is homogeneously distributed throughout NR matrix, which leads to the enhancement on mechanical properties. Moreover, the storage modulus (E) of modified nanocellulose filled NR is higher than unmodified nanocellulose filled NR, and the tanδ is reversed.


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