scholarly journals Octafluorobiphenyl-4,4′-dicarboxylate as a ligand for metal-organic frameworks: progress and perspectives

2020 ◽  
Vol 92 (7) ◽  
pp. 1081-1092
Author(s):  
Anastasia M. Cheplakova ◽  
Denis G. Samsonenko ◽  
Vladimir P. Fedin
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Functional Properties ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Porous Coordination Polymers ◽  
Aromatic Carboxylates ◽  
Metal Organic

AbstractWhile metal-organic frameworks based on aromatic carboxylates are very numerous and well investigated, the chemistry of their fully fluorinated analogues is at the very beginning. This minireview aims at summarizing all metal complexes with octafluorobiphenyl-4,4′-dicarboxylate (oFBPDC2−) anion and in particular, porous coordination polymers, their syntheses, crystal structures and functional properties highlighting the importance of further investigation of such systems.

Selective gas adsorption in microporous metal–organic frameworks incorporating urotropine basic sites: an experimental and theoretical study

2015 ◽  
Vol 51 (73) ◽  
pp. 13918-13921 ◽  
Author(s):  
S. A. Sapchenko ◽  
D. N. Dybtsev ◽  
D. G. Samsonenko ◽  
R. V. Belosludov ◽  
V. R. Belosludov ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Ab Initio ◽  
Coordination Polymers ◽  
Theoretical Study ◽  
Gas Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Frameworks ◽  
Porous Coordination Polymers ◽  
Basic Sites ◽  
Metal Organic

Urotropine-based porous coordination polymers with free N-donors demonstrate selective adsorption towards acidic gas substrates (C2H2 or CO2) as confirmed by isotherm measurements and ab initio DFT calculations.

Selective carbon dioxide adsorption by mixed-ligand porous coordination polymers

CrystEngComm ◽  
2015 ◽  
Vol 17 (44) ◽  
pp. 8388-8413 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debajyoti Ghoshal
Keyword(s):  
Carbon Dioxide ◽  
Solid State ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Mixed Ligand ◽  
Carbon Dioxide Adsorption ◽  
Porous Coordination Polymers ◽  
Metal Organic ◽  
Proper Design

Mixed ligand metal–organic frameworks (MOFs) have resolutely established themselves as a class of excellent solid state sorbents for carbon dioxide (CO2) and a proper design of such MOF can potentially improve not only the amount of CO2 adsorption, but also the selectivity of CO2 uptake over other gases and volatiles.

scholarly journals Antifungal activity of water-stable copper-containing metal-organic frameworks

2017 ◽  
Vol 4 (10) ◽  
pp. 170654 ◽  
Author(s):  
Supaporn Bouson ◽  
Atiweena Krittayavathananon ◽  
Nutthaphon Phattharasupakun ◽  
Patcharaporn Siwayaprahm ◽  
Montree Sawangphruk
Keyword(s):  
Growth Rate ◽  
Candida Albicans ◽  
Antifungal Activity ◽  
Aspergillus Niger ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Antimicrobial Activities ◽  
Porous Coordination Polymers ◽  
Metal Organic ◽  
Agricultural Industries

Although metal-organic frameworks (MOFs) or porous coordination polymers have been widely studied, their antimicrobial activities have not yet been fully investigated. In this work, antifungal activity of copper-based benzene-tricarboxylate MOF (Cu-BTC MOF), which is water stable and industrially interesting, is investigated against Candida albicans , Aspergillus niger , Aspergillus oryzae and Fusarium oxysporum . The Cu-BTC MOF can effectively inhibit the growth rate of C. albicans and remarkably inhibit the spore growth of A. niger , A. oryzae and F. oxysporum . This finding shows the potential of using Cu-BTC MOF as a strong biocidal material against representative yeasts and moulds that are commonly found in the food and agricultural industries.

Four cobalt(ii) coordination polymers with diverse topologies derived from flexible bis(benzimidazole) and aromatic dicarboxylic acids: syntheses, crystal structures and catalytic properties

RSC Advances ◽  
2014 ◽  
Vol 4 (106) ◽  
pp. 61281-61289 ◽  
Author(s):  
Xiao Xiao Wang ◽  
Baoyi Yu ◽  
Kristof Van Hecke ◽  
Guang Hua Cui
Keyword(s):  
Dicarboxylic Acid ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Catalytic Properties ◽  
Hydrothermal Reaction ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Metal Organic ◽  
Aromatic Dicarboxylic Acids

Four metal–organic frameworks (MOFs) were obtained from the hydrothermal reaction of Co(ii) and with dicarboxylic acid and flexible bis(5,6-dimethylbenzimidazole) and characterized. The four MOFs exhibit distinct 2D or 3D structural frameworks.

Syntheses, crystal structures and UV-visible absorption properties of five metal–organic frameworks constructed from terphenyl-2,5,2′,5′-tetracarboxylic acid and bis(imidazole) bridging ligands

2014 ◽  
Vol 43 (18) ◽  
pp. 6701-6710 ◽  
Author(s):  
Liming Fan ◽  
Xiutang Zhang ◽  
Wei Zhang ◽  
Yuanshuai Ding ◽  
Weiliu Fan ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Tetracarboxylic Acid ◽  
Absorption Properties ◽  
Visible Absorption ◽  
Bridging Ligands ◽  
Metal Organic ◽  
Uv Visible

Five novel coordination polymers based on terphenyl-2,5,2′,5′-tetracarboxylic acid and bis(imidazole) bridging ligands.

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