Complex Formation in Molten Salts Studied by Distribution Methods

1963 ◽  
Vol 18 (7) ◽  
pp. 840-842 ◽  
Author(s):  
J. O. Liljenzin ◽  
H. Reinhardt ◽  
H. Wirries ◽  
R. Lindner
Keyword(s):  
Complex Formation ◽  
Stability Constants ◽  
Molten Salts ◽  
Chloro Complexes ◽  
Complex Constant ◽  
The Stability

With a distribution technique described earlier the stability constants of cadmium-chloro complexes were evaluated. The values obtained are practically identical with those obtained by other authors with polarographic methods with the exception of the first complex constant which was found to be considerably higher (832) than that described in the literature (200).

Equilibrium Studies of Alkyltin(IV) Complexes with D-Glucosamine

1997 ◽  
Vol 62 (7) ◽  
pp. 1023-1028 ◽  
Author(s):  
Mohamed M. Shoukry ◽  
Samir M. El-Medani
Keyword(s):  
Complex Formation ◽  
Stability Constants ◽  
Acid Base ◽  
Complex Formation Equilibria ◽  
Equilibrium Studies ◽  
Formation Equilibria ◽  
Effects Of Temperature ◽  
The Stability

The acid-base and complex-formation equilibria involving glucosamine and its complexes with alkyltin(IV) chlorides have been studied by potentiometric technique. The results prove to a formation of 1 : 1 complex with trialkyltin(IV) and both 1 : 1 and 1 : 2 complexes with dialkyltin(IV) species. The stability constants in water were determined, the effects of temperature (from 15 to 35 °C) and ethanol (up to 88 vol.%) was studied and the speciation of the complexes was resolved.

The affinity of aldehydic compounds to complex formation. Nickel(II) and cobalt(II) complexes with 2-pyridinecarboxaldehyde

1977 ◽  
Vol 55 (14) ◽  
pp. 2613-2619 ◽  
Author(s):  
M. S. El-Ezaby ◽  
M. A. El-Dessouky ◽  
N. M. Shuaib
Keyword(s):  
Complex Formation ◽  
Aqueous Solutions ◽  
Stability Constants ◽  
Metal Ion ◽  
Experimental Conditions ◽  
Complex Species ◽  
Spectrophotometric Methods ◽  
Complex Equilibria ◽  
The Stability ◽  
Hydroxy Groups

The interactions of Ni(II) and Co(II) with 2-pyridinecarboxaldehyde have been investigated in aqueous solutions at μ = 0.10 M (KNO3) at 30 °C. The stability constants of different complex equilibria have been determined using potentiometric methods. Spectrophotometric methods were also used in the case of the nickel(II) – 2-pyridinecarboxaldehyde system. It was concluded that nickel(II) and cobalt(II), analogous to copper(II), enhance hyrdation of 2-pyridinecarboxaldehyde prior to deprotonation of one of the geminal hydroxy groups. Complex species of 1:1 as well as 1:2 metal ion to ligand composition exist under the experimental conditions used.

Die Komplexbildung von Tris(dihydroxy-phosphonylmethyl)phosphinoxid* mit einigen zweiwertigen Kationen / Complex Formation of Some Divalent Cations with Tris(dihydroxy-phosphonylmethyl)phosphine Oxide

1977 ◽  
Vol 32 (5) ◽  
pp. 547-550 ◽  
Author(s):  
G. Anderegg
Keyword(s):  
Complex Formation ◽  
Stability Constants ◽  
Phosphine Oxide ◽  
Divalent Cations ◽  
Ph Measurements ◽  
The Stability

The formation of the 1:1 complexes of Mg2+, Ca2+, Ni2+, Cu2+ and Zn2+ with tris-(dihydroxy-phosphonylmethyl)phosphine oxide has been studied by pH measurements. The values of the stability constants and their trend is similar to that found for the complexes of tripolyphosphate.

Study of nitrate complex formation with trivalent Pm, Eu, Am and Cm using a solvent extraction technique

2004 ◽  
Vol 92 (12) ◽  
Author(s):  
Sofie Andersson ◽  
C. Ekberg ◽  
J-O. Liljenzin ◽  
M. Nilsson ◽  
G. Skarnemark
Keyword(s):  
Solvent Extraction ◽  
Complex Formation ◽  
Nuclear Fuel ◽  
Stability Constants ◽  
Spent Nuclear Fuel ◽  
Aqueous Media ◽  
Separation Process ◽  
Nitrate Complex ◽  
The Stability ◽  
Solvent Extraction Technique

SummaryThe separation of actinides and lanthanides is an important question in the treatment of spent nuclear fuel in the transmutation concept. To find an efficient and well functioning separation process it is necessary to study the chemistry of the elements in the two groups in different aqueous media. The stability constants of the nitrate complex formation with Pm, Eu, Am and Cm were determined using solvent extraction. The extraction was studied using the synergistic system of 2,6-bis-(benzoxazolyl)-4-dodecyloxylpyridine and 2-bromodecanoic acid in

A spectrophotometric study of the complex formation between cobalt(III) and trans-1,2-cyclohexanedinitrilotetraacetic acid (CyDTA)

1979 ◽  
Vol 57 (17) ◽  
pp. 2292-2296 ◽  
Author(s):  
Rita K. Hessley ◽  
Shoba Waykole ◽  
Robert L. Sublett
Keyword(s):  
Complex Formation ◽  
Stability Constants ◽  
Spectrophotometric Study ◽  
Higher Order ◽  
Order Complex ◽  
Spectrophotometric Methods ◽  
Investigation Result ◽  
Unique System ◽  
The Stability

An intriguing and unique system has been observed during the otherwise routine study of the cobalt(III) complex of trans-1,2-cyclohexanedinitrilotetraacetic acid (CyDTA). Using classical spectrophotometric methods to determine the stoichiometry and the stability of a complex, significant deviations from the predicted 1:1 complex were observed in a system buffered at pH = 4.6. It is postulated that in addition to the usual 1:1 complex, the propensity of the reactants to form complexes and the strong oxidizing conditions used in this investigation result in the formation of a second, higher order complex between Co(III) and CyDTA. When the concentration of CyDTA exceeds that of Co(III), the metal:ligand ratio for this complex is 1:2. A structure is proposed, and approximate stability constants of both complexes are discussed.

scholarly journals Study of Complex Formation Between Iodoquinol (IQ) and Co2+, Mn2+, Cd2+, Pb2+and Zn2+Cations in Binary Aqueous / Non-aqueous Solvent Using Spectrophotometry

2007 ◽  
Vol 4 (4) ◽  
pp. 581-586 ◽  
Author(s):  
A. Nezhadali ◽  
H. A. Hosseini ◽  
P. Langara
Keyword(s):  
Ionic Strength ◽  
Complex Formation ◽  
Stability Constants ◽  
Spectrophotometric Method ◽  
Formation Constants ◽  
The Other ◽  
Aqueous Solvent ◽  
The Stability ◽  
Complexation Reactions

The complexation reactions between iodoquinol and Co2+, Mn2+, Cd2+, Pb2+and Zn2+cations were studied in different DMF/H2O binary mixtures at the ionic strength of 0.1(using NaNO3).The spectrophotometric method was used for the determination of formation constants and the stoichiometries. The stoichiometry of the complexes is established 1:1 by Job's and mole ratio methods. It was found that the stability constants of the complex formed between the ligand (IQ) and the cations in the all cases increase with increasing of the non-aqueous solvent. In the most cases the maximum formation constants between Zn2+ion and IQ were obtained respect to the other cations.

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