Notizen:Mischungsenthalpien beim flüssigen System Wasser + Essigsäure / Heats of Mixing for the Liquid System Water + Acetic Acid
1972 ◽
Vol 27
(10)
◽
pp. 1527-1529
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Keyword(s):
C 30
◽
Calorimetric measurements of the heats of mixing for the liquid system water+acetic acid at 17 °C, 20 °C, 25 °C, 30 °C, 40 °C, and 50 °C show that there is a change of sign in the function H̅E(x), where H̅E denotes the molar heat of mixing and x the mole fraction of acetic acid. The process of mixing the pure liquid components is weakly exothermic for low acid concentrations, but strongly endothermic for high acid concentrations. The function H̅E can be approximately represented by the usual power series with respect to x, five free parameters at each temperature being necessary.