Untersuchungen der elektrischen Leitfähigkeit homologer 4,4′-Di-n-alkyloxy-azoxybenzole im nematischen Phasenbereich / Investigation of the Electric Conductivity of Homologous 4,4′-Di-n-alkoxyazoxybenzenes in their Nematic Phase
1975 ◽
Vol 30
(3)
◽
pp. 316-322
◽
Keyword(s):
The effect of temperature and concentration of the added electrolyte tetrabutylammoniumpicrate on the electric conductivity of homologous 4,4′-di-n-alkoxyazoxybenzenes (C1 to C8) in their nematic phase is investigated. In general an increase of the alkyl chain length results in a decrease of the ratio of anisotropy x∥/x⊥. At the lowest temperature of the nematic phase values between 1,6 (C2) and 0,45 (C8) are obtained. This behaviour can be explained by the formation of cybotactic groups with a smectic structure. Increasing the electrolyte concentration reduces the ratio of anisotropy for short alkyl chains, whereas for long chains the ratio rapidly increases.
1976 ◽
Vol 31
(12)
◽
pp. 1700-1706
◽
2009 ◽
Vol 41
(6)
◽
pp. 790-798
◽
Keyword(s):
2020 ◽
Vol 302
◽
pp. 112507
◽
Keyword(s):
2016 ◽
Vol 222
◽
pp. 981-987
◽
Keyword(s):
2015 ◽
Vol 60
(7)
◽
pp. 1986-1996
◽
Keyword(s):
Keyword(s):
Keyword(s):
2006 ◽
Vol 61
(9-10)
◽
pp. 715-720
◽
2008 ◽
Vol 43
(3-4)
◽
pp. 225-235
◽
Keyword(s):