Kinetics of Triplet Sublevel Selective Photochemical Reactions in the Solid State
Keyword(s):
Abstract A detailed description of the overall kinetics of photochemical reactions has to deal with photo-physical activation and de-activation rates as well as with true photochemical rates. Based on the hypothesis that for photoreactions involving the lowest excited triplet state the chemical reaction rates of the individual triplet zero-field levels have different values, a method is presented for the evaluation of these rates from bulk measurements under steady state illumination conditions. The complications arising from the detection of solid state reactions are discussed, and a simple solution is given, illustrated by a numerical example.
1989 ◽
Vol 54
(5)
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pp. 1311-1317
Keyword(s):
2002 ◽
Vol 34
(3)
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pp. 193-208
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2018 ◽
Vol 12
(5)
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pp. 940-941
Keyword(s):
1967 ◽
Vol 63
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pp. 1023
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