Crystal Structure of 3Ni(N03)2.16C6 H5NH2
Keyword(s):
X Ray
◽
Abstract The Compound 3Ni(NO3)2 -16C6H5NH2 was obtained by crystallization from solutions of Ni(NO3)2 • 6C6H5NH2 -2H2O in aniline. Its crystal structure was determined by single crystal X-ray diffraction. The crystals are triclinic, space group P1 with lattice constants a = 985.2 pm, ft = 1004.5 pm and c = 2514.3 pm, a = 96.34°, ß = 92.63° and y = 89.82°. The structure shows units of four aniline molecules and two slightly distorted nitrate ions in the coordination sphere of each nickel ion. These units are similar to contact ion pairs in concentrated ionic solutions.
1994 ◽
Vol 49
(12)
◽
pp. 1654-1658
◽
1994 ◽
Vol 49
(12)
◽
pp. 1809-1812
◽
Keyword(s):
2007 ◽
Vol 62
(1)
◽
pp. 1-4
◽
1992 ◽
Vol 47
(4)
◽
pp. 460-464
◽
Keyword(s):