Photoselection of Luminescent Molecules in Anisotropic Media in the Case of Two-Photon Excitation. Part I. Theoretical Considerations

1994 ◽  
Vol 49 (10) ◽  
pp. 936-938
Author(s):  
A. Kawski ◽  
G. Piszczek

AbstractPhotoselection of elongated luminescent molecules oriented in a stretched polymer film is considered theoretically for the case of two- and three-photon excitation, having in mind the employment of this phenomenon for determining the angle between the absorption and emission transition moments. Two-photon photoselection provides information on electronic excited states which are not detectable by conventional one-photon spectroscopy due to selection principles.

2018 ◽  
Vol 20 (30) ◽  
pp. 19922-19931 ◽  
Author(s):  
M. E. Sasin ◽  
A. G. Smolin ◽  
K.-H. Gericke ◽  
E. Tokunaga ◽  
O. S. Vasyutinskii

This paper presents the detailed study of two-photon excited fluorescence in indole dissolved in propylene glycol produced by two-photon absorption from the molecular ground state to several high lying excited states.


1997 ◽  
Vol 36 (24) ◽  
pp. 5548-5551 ◽  
Author(s):  
Felix N. Castellano ◽  
Henryk Malak ◽  
Ignacy Gryczynski ◽  
Joseph R. Lakowicz

1994 ◽  
Vol 374 ◽  
Author(s):  
Kenneth J. McEwan ◽  
Richard C. Hollins

AbstractIn this paper we describe a technique by which the broadband excited state absorption/emission and dynamics can be measured for materials with either linear or two photon absorption. The technique is applied to two different dyes in solution and to a cyano-biphenyl organic liquid. The ratio of σex/σgr for HITCI in methanol is greater than 1 from 400 to 570nm and at 532nn is determined to be 25; the excited state lifetime is 800ps. For CAP in methanol σex/σgr is greater than 1 from 400–650nm and is 14 at 532nm. Dimer absorption and emission are found to contribute to the excited state response in this material. In the organic liquid broadband (400–570nm) excited state absorption is measured following two photon excitation at 588nm.


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