Molekül-und Elektronenstruktur des Thioheteroanions [S2 WS2CoS2WS2]2- / Molecular and Electronic Structure of the Thiohetero Anion [S2WS2CoS2WS2]2-
1978 ◽
Vol 33
(9)
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pp. 978-982
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Keyword(s):
X Ray
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Abstract The crystal and molecular structure of [(C6H5)4P]2[Co(WS4)2] was determined from single crystal X-ray diffraction data (space group P21/c with a = 18.542(4), b = 15.443(2), c= 18.713(2) Å, β= 108.73(1)°, Z = 4). In the complex anion Co is coordinated by two bidentate chelating WS42- anions, with a nearly tetrahedral surrounding of Co. The bond lengths in the planar metal sulfur ring CoS2W are Co-S = 2.26 Å and W-S = 2.22 Å, while the terminal W-S bonds are 2.14 Å.
2018 ◽
Vol 6
(2)
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pp. 132-136
1987 ◽
Vol 42
(4)
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pp. 395-409
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1973 ◽
Vol 137
(2-3)
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Keyword(s):
1968 ◽
Vol 302
(1469)
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pp. 225-236
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1980 ◽
Vol 35
(10)
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pp. 1203-1206
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Keyword(s):
1982 ◽
Vol 37
(10)
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pp. 1230-1233
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