Facile Synthesis and Crystal Structure of [(PhSO2 N)2 WVI Cl2 (CH3CN)2] - the Oxidative Imination of W(CO)6 by N,N-Dichlorophenylsulphonamide
1985 ◽
Vol 40
(6)
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pp. 736-739
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Keyword(s):
AbstractThe reaction of N,N-dichlorophenylsulphonamide with tungsten hexacarbonyl in refluxing CCl4 leads in good yield to the yellow polymeric complex [(PhSO2N)2WCl2]x, which may be converted to the octahedral nitrene complex [(PhSO2N)2WCl2(CH3CN)2] by recrystallisation from acetonitrile. Crystals of the acetonitrile complex are triclinic, space group P 1̅, a = 820.7(2), b = 1128.8(3), c = 1286.9(3) pm, α = 89.25(3), β = 89.54(3). γ = 72.67(2)°, Z = 2, R = 0.027 for 2527 unique observed reflections.
1995 ◽
Vol 50
(8)
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pp. 1175-1180
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Keyword(s):
1996 ◽
Vol 51
(10)
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pp. 1464-1468
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1998 ◽
Vol 63
(11)
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pp. 1884-1892
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Keyword(s):
2020 ◽
Vol 75
(5)
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pp. 497-501
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2015 ◽
Vol 70
(7)
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pp. 455-459
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1992 ◽
Vol 47
(1)
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pp. 1-4
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1992 ◽
Vol 47
(4)
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pp. 460-464
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Keyword(s):
1998 ◽
Vol 53
(1)
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pp. 81-86
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1995 ◽
Vol 50
(2)
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pp. 223-228
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1990 ◽
Vol 45
(4)
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pp. 413-416
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