Synthesis and Crystal Structure of a Novel Neutral Polymeric Lead(II)-thiosemicarbazonato Complex
1998 ◽
Vol 53
(1)
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pp. 81-86
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Keyword(s):
The reaction between lead(II) acetate and 2-acetylpyridine 4N-methylthiosemicarbazone (H4ML) produced a complex of the formula [Pb(4ML)(OOCMe)] with an unusual polymeric structure in which the lead atom is hepta-coordinate, the deprotonated thiosemicarbazone is a tetradentate bridge, and the acetate group both chelates and bridges. The complex crystallizes in the triclinic space group P1̄ with a = 8.860(2), b = 9.394(2), c = 9.783(3) A, α = 108.93(4), β = 98.67(3), γ = 107.87(5)°, V = 704.1(3) Å3 , Z = 2.
1985 ◽
Vol 40
(6)
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pp. 736-739
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1995 ◽
Vol 50
(8)
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pp. 1175-1180
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Keyword(s):
1996 ◽
Vol 51
(10)
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pp. 1464-1468
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1998 ◽
Vol 63
(11)
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pp. 1884-1892
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Keyword(s):
2020 ◽
Vol 75
(5)
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pp. 497-501
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1992 ◽
Vol 47
(1)
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pp. 1-4
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1992 ◽
Vol 47
(4)
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pp. 460-464
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Keyword(s):
2001 ◽
Vol 56
(6)
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pp. 517-520
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1995 ◽
Vol 50
(2)
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pp. 223-228
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1990 ◽
Vol 45
(4)
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pp. 413-416
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