Metall-Komplexe mit S4N4 -Liganden: Die Strukturen von zwei Komplexen der Zusammensetzung [TiCl4(S4N4)]2 / Metal Complexes with S4N4 Ligands: The Structures of Two Complexes of Composition [TiCl4(S4N4)]2
1988 ◽
Vol 43
(4)
◽
pp. 467-471
◽
Keyword(s):
AbstractSlow reaction of TiCl4 with S4N4 in CH2Cl2/CCl4 produces a mixture of two crystalline dinuclear complexes of composition [TiCl4(S4N4)]2. Crystal data for the orange-yellow α-isomer: monoclinic, space group P21/n with a = 11.608(3) Å. b = 8.304(3) Å, c = 10.938(5) Å, β = 101.06(4)° and Z = 2. Crystal data for the red-brown β-isomer: monoclinic, space group P21/c with a = 11.220(2) Å, b = 13.868(2) Å, c = 14.839(4) Å, β = 106.18(2)° and Z = 4. Crystal structure analyses reveal that the S4N4 molecules in the α-form act as 1,3-N,N′-bonded bridging ligands and in the β-form as N-bonded monodentate ligands.
1981 ◽
Vol 36
(10)
◽
pp. 1208-1210
◽
1998 ◽
Vol 53
(7)
◽
pp. 641-652
◽
1989 ◽
Vol 44
(7)
◽
pp. 778-785
◽
Keyword(s):
1989 ◽
Vol 44
(8)
◽
pp. 903-910
◽