Zur Kenntnis des ersten Alkalimetall-Cadmium-Halogeno-Oxovanadats: K4CdV5O15Cl / On the First Alkaline-Cadmium-Vanadium Oxide Halide: K4CdV5O15Cl
1996 ◽
Vol 51
(4)
◽
pp. 493-497
◽
Keyword(s):
Type V
◽
Abstract Single crystals of K4CdV5O15Cl have been prepared by crystallization from melts. The yellow crystals show tetragonal symmetry, space group C14-P4, a = 9.097(1), c = 5.331(2) Å, Z = 1. K4CdV5O15Cl belongs to the K4CuV5O3Cl type. V (l) forms V2O7 double tetrahedra connected by square V(2)O5 pyramids and CdO4Cl2 octahedra. The crystal structure is discussed with respect to the isotypic compound K4CuV5O15Cl considering a short V(2)-O distance indicative of a vanadinyl group.
1994 ◽
Vol 49
(11)
◽
pp. 1459-1462
◽
1997 ◽
Vol 52
(4)
◽
pp. 457-461
◽
Keyword(s):
2002 ◽
Vol 57
(12)
◽
pp. 1454-1460
◽