Isolierte MnCl6-Oktaeder im Oxohalogeno-Vanadat Ba5(Mg0,4Mn0,6)(V2O7)2MnCl6 / Isolated MnCl6 Octahedra in the Oxohalogeno Vanadate Ba5(Mg0,4Mn0,6)(V2O7)2MnCl6
1997 ◽
Vol 52
(4)
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pp. 457-461
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Keyword(s):
Single crystals of Ba5(Mg0,4Mn0,6)(V207)2MnCl6 have been prepared by solid state reactions of MgCO3, Mn2O3, V2O5 and BaCl2·2H2O below the melting point of BaCl2. The new vanadium oxide chloride crystallizeswith monoclinic symmetry, space group C42h-P2/c, a = 13.345(4), b = 5.711(2), c = 15.859(4) Å, β = 113.69(2)°, Z = 2. Special features of the crystal structure are isolated MnCl6 octahedra and layers created by divanadat groups and (Mg,Mn)O6 octahedra. The 2∞ [(Mg,Mn)V2O7] nets of Ba3(Mg0,4Mn0,6)(V2O7)2MnCl6 are discussed with respect to other oxohalogeno vanadates Containing divanadate groups.
1996 ◽
Vol 51
(2)
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pp. 229-232
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Keyword(s):
Über das erste Oxopalladat-Arsenat: KMg3Pd(AsO4)3 / On the First Oxopalladat-Arsenate: KMg3Pd(AsO4)3
1995 ◽
Vol 50
(6)
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pp. 867-870
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1994 ◽
Vol 49
(11)
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pp. 1463-1466
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1996 ◽
Vol 51
(4)
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pp. 489-492
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1995 ◽
Vol 50
(1)
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pp. 51-55
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Keyword(s):
1997 ◽
Vol 52
(8)
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pp. 989-993
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