Cd0,73Cu0,27V2O6: Eine Verbindung mit Branneritstruktur / Cd0 ,73Cu0,27V2O6: A Compound with Brannerite Structure
1994 ◽
Vol 49
(7)
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pp. 927-930
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Keyword(s):
X Ray
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Abstract Single crystals of Cd0.73Cu0.27V2O6 were prepared by solid state reactions. X-ray investigations lead to monoclinic symmetry, space group C32h-C2/m , a = 9.339, b = 3.5604, c = 6.893 Å, β = 111.85°, Z = 2. It belongs to the Brannerite structure, showing a statistical distribution of Cd2+ and Cu2+ on one point position. The crystal structure of Brannerites is discussed with respect to the distorted O2- octahedra around V5+ and the influence of the Jahn-Teller active Cu2+ ion to the shortened M2+O6 octahedra.
1996 ◽
Vol 51
(2)
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pp. 229-232
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Keyword(s):
1997 ◽
Vol 52
(4)
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pp. 457-461
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Keyword(s):
1996 ◽
Vol 51
(4)
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pp. 489-492
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1998 ◽
Vol 53
(2)
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pp. 149-152
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